电化学原理-第三版-李荻-课后答案

©right&[e-mail]12266KClKClHOHO0.001141.31.010142.31010001000cKKKKcm112EVFiiFEVii10288.0scmVH10050.0scmVK10051.0scmVCl3,62.550121,,,,2eqcmKCloHCloKOHoOHo2-14WOccc,cK1.008101.004HH2,811c5.510cm1000oHO41121,,Cl,tt1,t76.33mol(KCloKCloClcm121121121,K,Na,Cl73.49mol50.14mol76.31mol(NaClooocmcmcm2121Cl,Na,121Cl,K,mol45.126mol82.142cmcmooooKClNaClCl,o3vscmvscmuvscmuFuaoololoio/1020.5,/1062.7,/1091.7,/24N,24K,24C,C,,5Cu(OH)2==Cu2++2OH-,=y2CucOHc=2yKS=4y3u=ui=KH2O+10-3[yCu2++2yOH-]oy=1.3610-4mol/dm3Ks=4y3=1.00610-11(mol/dm3)36==+=y3AgIOAg3IOAgc3IOc=y=ySK2K=iK=+yOHK2310Ag+y3IO0=+yOHK23103AgIOy=43651074.1104.68101.11030.1Lmol/;=ySK2=3.038102)/(Lmol7HAco,=HClo,+NaAco,-NaClo,=390.7121eqcmHAco,=9.02121eqcm0/=0.023==1.69K_2)1/(V5108IR=iSKSl=Kil,K=1000c,IR=1000ilc=V79.05.01261010105339log=-0.5115||||ZZI25C1,/,/uvsmvs,Cl73.49mol50.14mol76.31mol(NaCl73.49mol50.14mol76.31mol(NaCl,Cl73.49mol50.14mol76.31mol(NaCl73.49mol50.14mol76.31mol(NaCl73.49mol50.14mol76.31mol(NaCl73.49mol50.14mol76.31mol(NaClNa,aooNa62.762.7K62.762.7OH=2y=2yKKo)Agcc©right&[e-mail]1=0.9740I=212iizm,I=212iicz=mmm12=0.91013=0.64874=0.811410=HaHmpH=-log=-log0.209Ha4.0=1.0812326623SbOHeSbHO236HH6e:2322323SbOHSbHO00GEnF83646F0.0143VE=+0E2.36RTF2232323logHSbOSbHOPaaa==0.0143V0E0602.32.3loglog6SbSbHHRTRTaaFF2.3logHRTaF000.0143SbEEV222442HOeHO224HH4e:22222HOHO2220022.3log4HOHOPPRTEEEFa0=1.229V0=0.000V001.229EV242SnSne:32222FeeFe23422SnFeSnFe223422022.3log2SnFeSnFeCCRTEEFCC=0.771-0.15+220.05910.001(0.01)log20.01(0.001)=0.6505V(0.1)AgAgme(1)AgmeAg(1)(0.1)AgmAgm(1)0(0.1)2.3logAgmAgmaRTEEFa0E1m3AgNO0.4V0.1m3AgNO0.72V2.310.4log0.0440.10.72RTEVF32222|(),()|(),ClHgHgClsKClmClPPt2222HgClHgCle222CleCl222HgClHgCl22H2224242424242242424=0.0143V=0.0143V0E2.32.3RT24HHHH24244240000EVEV0000EVEV0000EVEVEVEVEV32322222223222222232323232322222222223232©right&[e-mail]3222200002.3log2ClHgHgClPaRTEEEFaO1.35950.26811.0914(25C)EVEClaE00EClaE423,(1)|(1)()HPtHatmHClaAgNOmAg222HHe222AgeAgg2222HAgHAE02.3log()AgAgAgRTEmF223|(),()()HgHgClsKClAgNOmAg02.3log()AgAgAgRTEmF:23,(1)|(1)Pb()PbHPtHatmHClaNOm,22Pb2PbHH,220PbPbPb2.3log()2RTEmF:'232e,(1)|(1)FeCl(),FeCl()FHPtHatmHClamm,32+21FeFe2HH232302.3log()FeFeFeFeRTEaFa5424(),()ZnZnSOmHgSOsHg22402.3log()2SOZnRTEEaaF222(),()(),HPbPbClsHClmHPPt-20222.3log()2HHClRTEEaaPF6'2,(1)|(1)(0.1),()HPtHatmHClaKClmAgClsAgAgCleAgCl02.3logClRTaF0=0.2224V0.79V0.22240.0591log(0.790.1)0.2876EV7'2.312.31loglogaClClRTRTEFaFa'2.3logClClaRTFa=0.01m=0.1ma'a0.10.780.078,()Claaa0.010.9040.00904,()Claaa2.32log(bRTEtaaF)2.30.078(21)log()(20.3891)0.0591log0.01230.00904baRTEEtaaVF0.0591,0.046abEVEV0.01baEEV822,(1)|(1)|(),PtHatmHIaIsPt2,(1)|(1)FeCl(),FeCl()F,(1)|(1)FeCl(),FeCl()F2,(1)|(1)FeCl(),FeCl()F,(1)|(1)FeCl(),FeCl()F2EEaaPb2PbPb2PbPb2PbPb2PbPb2PbPb2PbPb2PbPb2PbPb2PbPb2PbPb2PbPb2PbPb2Pbee,(1)|(1)FeCl(),FeCl()F,(1)|(1)FeCl(),FeCl()F,(1)|(1)FeCl(),FeCl()F,02.32.3RTEEaaEEaa02.3EEaaEEaa2(),()(),(),()(),2PbPbClsHClmHPPtPbPbClsHClmHPPt(),()(),(),()(),EEaaP,(1)|(1)(0.1),(),(1)|(1)(0.1),(),(1)|(1)(0.1),()©right&[e-mail]4222222HHeIeII222HIH0202.3log()2HIRTEEaEF030.53460.1310(3525)0.5333EV0,E00ln2965000.5333102.9GnFERTKkJ0lnRTEKnF2965000.5333ln40.198.314298K172.8610KE00151.52GGkJ85.3510KK2222HgCleHgCl9:222HHe,,222222HHgClHgClH022.3log()22HClRTEEaaF,0.790.1Cla02.32.3loglogHClRTRTaEEaFFlolog6.9Haglog14HOHaa7.18107.9410OHa:00.0591logCla0.0591log0.0591HapHE6.90.0591EpH7.183107.9410()OHamoldm102222HgHge22242HgSOHgSO4242422HgSOHgSOe222202.3log2HgHgHgRTaF222402.32.3loglog22HgHgSORTRTKsaFF2224440,2.3log2HgHgSOSOSORTaF222442007,2.30.0591log0.7986log(6.510)0.63822HgHgSOSOHgHgRTKsVFAgClAgCle2212HgCleHgCl2212AgHgClAgClHg1965000.04554.391GnFEkJmol343911965002980.338105.329PEHGnFTkJmolT31965002980.3381032.617PESnFTJmolKT1222ZnZne22CueCu22ZnCuCuZn0.0591log0.05910.0591log0.0591HH0.0591log0.05910.0591log0.05910.0591log0.05910.0591log0.05910.0591log0.05910.0591log0.05910.0591log0.05910.0591log0.05910.0591log0.05910.0591log0.05910.0591log0.05910.0591log0.059188107.9410()107.9410()88moldmmoldm107.9410()107.9410()107.9410()107.9410()107.9410()107.9410()107.9410()107.9410()22HgSOHgSO22HgSOHgSO22222222224loglog22SOSO2222224aEEaaEEaFFFFaEEaaEEaaEEa88107.9410107.9410107.94100.0591log0.05910.0591log0.0591apap0.0591log0.05910.0591log0.0591HH33107.9410()107.9410()33moldmmoldm107.9410()107.9410()107.9410()242242HgSOHgSOHgSOHgSO242242242HgSOHgSO24224222242.32.32.32.3HgHgHgHg2222222222log22222222aa2222222222222222222.32.3log0.7986log(6.510)0.638log0.7986log(6.510)0.638RTRT222222log0.7986log(6.510)0.638©right&[e-mail]51.1031.1012965001.101296500293189.8298293PEQpHnFEnFTkJmolT1.1031.10129650077.2298293PESnFTJmolKTlnGnFERTK221ZnCuaa0021.101,log37.262.32.30.00581nFEEEKRTRT377.9510K22GGGFFCu22CueCu010.337VeCu020.520V00000031212300031220.33720.5200.154V00330.1549650014861GFJmol0lnRTKnF132KKK0002331212ln(lnln)()RTRTRTFFKKKFFFRTRT54422442OHeHO()001220.1V224HHe22222HOHOg1KKp22222lnln44HOHOpRTRTEKFFpp222228122247602.312.30.05910.0591loglogl