有机化学试题库三——完成反应式题及解答

1试题库三——完成反应式题及解答1．2．3．CH3CH2CH=CH2→CH3CH2CH2CH2OH4．CH3CH=CH25．(CH3)2C=CHCH2CH36．CH2=CHCH2OH→7．CH3CH2CH2C≡CH+HCl（过量）→8．CH3CH2C≡CH+HBr（过量）→9．CH3CH2C≡CCH3+KMnO410．CH3CH2C≡CCH3+H2O11．CH2=CHCH=CH2+CH2=CHCHO→12．13．14．15．16．17．18．19．20．(CH3)2C=CHCH3HBr①②O3Zn粉,H2OClCH2CHCH2OHOH△H+H2SO4HgSO4CH3+HBr+Cl2高温+Cl2CH2CH3Br2+CH(CH3)2Cl2+高温CH3①O3②H2O△CH3①②H2O△H2SO4B2H6①②H2O2①O3②H2O△CH=CH2CH3CH=CH2KMnO4CH3OCH=CH2+HBr221．22．23．24．25．26．27．28．29．30．31．32．33．34．35．36．CH2=CHCH2ClCH2=CHCH2CN37．(CH3)3CCl+NaOH38．(CH3)2CHCH2CH2OH+HBr39．40．41．+CH2Cl2AlCl3+CH3HNO3+KMnO4H+△+CH=CH2Cl2C6H5CH2ClMgCO2H+H2OCH2=CHCH2Br+NaOC2H5CH=CHBrCH2BrAgNO3室温乙醇++Br2KOH-乙醇△CH2=CHCHOCH2ClClH2ONaOH,△H2OClCH3OH-+SN2历程H2OCH3OH-+ClSN1历程BrKOH-乙醇H2OOH+HCl无水ZnCl2+HIOCH3CH2CH2OCH3（过量）FeBr2SO3HOHAlCl3CH3H2SO4SO3/CH3BrEtONa342．43．(CH3)2CHBr+NaOC2H544．45．CH3COOH+CH3CH2CHO46．CH3COCH2CH2CH2CHO47．48．49．CH3COCH2CH3+H2N-OH→50．Cl3CCHO+H2O→51．52．CH3CH2CHO53．C6H5COCH3+C6H5MgBr→54．55．56．(CH3)3CCHO57．58．59．60．61．62．CH2=CHCH2CH2COCH3+HCl→63．C6H5CHO+CH3COCH3→64．65．66．+HIOCH3（过量）CH3CH2CH2CH2CHCH3OHKMnO4OH-HIO4HIO4CH3OH+Br2CH3CH2CH2CHCH2CH3OH浓H2SO4△（分子内脱水）CHOH3C+KMnO4稀NaOHH2OH++OH2NNHC6H5NaOH浓O+(CH3)2C(CH2OH)2无水HCl+ONa2CrO7△H+KMnO4CHO室温CCH3OCl2H2OOH-,CCH3OCl2+H+H2OH+CH3COCHCO2C2H5CH3OH-,稀△①②,CH3COCHCO2CH3CH2CO2CH3△浓NaOHCH3CH2CHCOOHOH△+OH2NOH467．68．69．70．71．72．73．74．75．76．77．78．79．80．HOCH2CH2COOH81．NCCH2CH2CN+H2O82．83．CH3COCl+84．85．CH3CH2COOC2H5H+稀△CO2CH3COCH3△HO2CCH2COCCOOHCH3CH3H2ONaOH△CH3CH2CHCOOHCl-△CH3CHCH2COOHOHH2ONaOH△-OOH3C稀△CH3CH2CCOOHOHCH3H2SO4稀△CH3CH2COCO2HH2SO4CH3CHCOCO2HCH3△△COOHCOOHCOOHH+①②NaOH△OO,,△CH3CH2COOHCl2+P-Na2Cr2O7H2O(CH3)2CHOH+COClH3CLiAlH4NaOHH+CH2COOHCH2COOH△Ba(OH)2CH3无水AlCl3(CH3CO)2O+OHNaOEt586．CH3COOC2H5+CH3CH2CH2OH→87．CH3CH(COOH)288．89．90．91．92．93．94．(C2H5)3N+CH3CHBrCH3→95．[(CH3)3NCH2CH2CH2CH3]+Cl-+NaOH→96．CH3CH2COCl+97．98．99．100．101．102．103．104．105．106．△+COOHHCl+COOHHOCH2CH2OH2COOHLiAlH4+OHHCOOHCH2CH2COOC2H5CH2CH2COOC2H5NaOEtNCONH2OH-△H3CNHCH3N(C2H5)2+HNO2O？CHOH3C浓碱？CH3SCH3H2O230%HAc△？NKMnO4/H+NaOC2H5△？？CH2CH2COOC2H5CH2CH2COOC2H5CH3CH2Br？①NaOH/H2O②H+/H2O？△H+/H2O△？CH2CH2CH2CNOHH+CH3CH2CHOOH-△NaBH4OHCNH2OH+CHO+HS(CH2)3SHHClCH3CH2OH①NaBrH2SO4/②Mg乙醚/①CH3CHO②H2O???①Na2Cr2O7②HOCH2CH2OH6107．108．109．110．111．112．113．114．115．116．117．118．119．120．121．122．123．124．125．C6H5CHOCH3CH2CH2CHO+OH-△H2S+O1:1①OH2/Pd②Al2O3△?KMnO4OH-?CH3COCH3CH3CH2CH2CHOH2N+(CH3)2CHCH2COOHBr2△P+CCOOOH2OH+OCH3HNO3H2SO4NH2/PtO+HCNCH2CH2NCH2CH3Me2+△CH3CH2CH2CHO+NaHSO3??Na2CO3+COBrH2OCH2CONH2Cl2NaOH+OCH3H2SO4HNO3△CH3CHO+CH3CH2OHHCl无水(CH3CH2)3NCH2CH2COCH3OH+-△△NCOOHCOOHCO2-CHOBrZn-HgHCl△COOHCOOH△7126．127．128．129．130．131．132．133．134．135．136．137．138．139．140．141．142．(CH3CH2CO)2O+NH2CH3(CH2)4COClNaOHCl2C6H5COCH3H2NNHCONH2ClCH2CH2NMe2OHCH2CH3+-△NCOOHSOCl2CH3AlCl3CHCOOHCHCOOH△NHCH3H2SO4HNO3△ClCOClNH3NaOHBr23CHOCH2OHC6H5HNNH2C6H5CH2Cl干醚MgCO2H2O①②SOCl2???H3CNHCOCH3HNO3+HOAc(CH3)2CHCHCH3OHN(CH3)3+-△SCOCH3HNO3H2SO4△COOHCOOHCH3(CH2)4COClNH3△?NaOHCl2+?H2OCH2ClCCH2ClOHCN???NaCNH2O?NH2CH3SO2Cl+??NaOH8143．144．145．146．147．148．149．150．151．152．153．154．155．156．157．158．159．COOH?△H2SO4HNO3NH2OH+(CH3CO)2OOHCH2COOH△CH2COOHCH2COOH△?AlCl3?Zn-HgHCl??AlCl3SOCl2??NH2＜5℃HClNaNO2+OH-?OH[Ag(NH3)2]OH-CHOHO+COOHPCl5CHO+H2NNHCNH2HOAcOphCH2CH-NMe2CH3O+-△+CH2SHCHSHCH2SHHgONKMnO4H+CHOCH3CHO+稀OH-O①CH3MgI②H3O+?H2SO4△?B2H6①②H2O2?CrO3?CH3CH2CH2CH2SHHNO3CH3CH2CCH3O+O2NNHNH2NO2HOAcCH2CH3?HNO3CF3?△H2SO4HNO39160．161．162．163．164．165．166．167．168．169．170．171．172．173．174．175．176．177．HOCH2CH2CHOHCN?H3O+?△CH3CH3KMnO4H+?P2O5?CH3?CH3NO2FeHCl?(CH3CO)2O?△H2SO4HNO3?H3O+?CH3CH-CHCH3CH3ClKOH乙醇O3H2OZn？？？+？CH2=CH-CH=CH2+180℃CF3-CF=CF2ZnCl2CH2Cl+？60℃+？CH3CH2CH-C≡CHCH3+H2OH2SO4HgSO4CH3CH2OCHCH3CH3+HI(过量)？+？CHCH3CH3CH3HNO3回流稀CH2OH+PBr3？Mg乙醚？CH3C≡CH？+？CH2HOCCl4NBS+HBrCH3CH-CH-C-CH3OHOHOHCH3HIO42CH≡CCH2CH2CH2CH3Na液氨△CH3INa液氨????CH3C≡CHNa液氨CH3CH2Br液氨?H2Pd/BaSO4??CH3C≡CCH3Na液氨H2+CH2=CH-CH=CH2+CH=CHCNCl2HCHOZnCl2HCl，Fe??NaOHH2O?CH3CH2=CH-CH=CH2+CH=CHCHO10178．179．180．181．182．183．184．185．186．187．188．189．190．191．192．193．194．195．H2COCHCH2CH3H2OHIO4?BrNaOHEtOH+COCl无水AlCl3CH=CHBrKCNCH2ClOCH2CH3HIOO+CH3HIO3H2OZn/CH3HBrCl2+FeCl3OOO+H2+Ni80℃OOO+CH=CHBrClNaOC2H5CH3CH3CH3HBr+OOO△OCH3+HI11196．197．198．199．200．201202．203．204．205．206．207．208．209．211．H+CH2+H2OCH3CH=CHCH2CH2CH2OH+KMnO4△BrONaCH2Br+?BrClMg干醚?H2OH+??OHOH+HIO4+CH2=CHCH3?CH(CH3)2O2110~120℃0.4MPa?H2OH+/80~90℃?+??H2OH3CCH3Br2+?Br2+CH≡CCH2CH=CH2(1mol)?CH(CH3)2H3CKMnO4H+?+CH3H2SO4HNO3+??H2C80℃NiH2/BrClMg干醚?+?CH(CH3)2AlCl3BrCH2BrMg干醚?CH3COOH?CH2B2H6①②H2O2/OH-12211．212．213．214．215．216．217．218．219．220．221．222．223．224．225．226．Br2?CH=CH2+CCl4CH2HBrMg过氧化物D2ODBr乙醚？？？Mg乙醚？？KOH？？乙醇Cl2CH2=CH-COOEt++Br2△+(CH3)2C=CH2HClCH2CH2CH3NBS？Me3COK？KMnO4？KMnO4△PhCH2CH2CH3Cl2光?KOH醇?稀KMnO4冷?KMnO4H+?CH3(BH3)2?H2O2OH-?CH3OCH3+CH3CH=CH2无水AlCl3CH3OC2H5HI?+??CH3CH2C≡CHHOBrCHMe2+CH2=CMe2无水AlCl3CH3CH=CH2+HOCl+(CH3)2C=CH2HCl过氧化物13227．228．229．230．231．232．233．234．235．236．237．238．239．240．241．242．243．244．CH2=CHCN+?H2SO40~60℃H2SO4浓浓??CH3CH2C≡CCH2CH3+H2Na液氨CH3CH2CH=CH2+Cl2500℃①O3②ZnH2O，NBSCH3+CH≡CH+HCNCu2Cl2△CH3CH2CH2CH3+Br2127℃?OH-H2OCH3CHCH3OH醇?CH3CH2CH2Br+?H2O