两性与氨基酸型阴离子表面活性剂形成自增稠体系的性质研究-袁旻嘉

45120151ChinaSurfactantDetergent＆CosmeticsVol．4[e-mail]。11122211．2017022．200237pHCAPBLS。Cryo－TEM。NaCl。NaClw＜0.5%pH40℃5℃pH。pH。TQ423A1001－1803201501－0011－06DOI10．13218/j．cnki．csdc．2015．01．003Studyonpropertiesofself－thickeningsystemcomposedofamphotericsurfactantandamino－acidbasedanionicsurfactantYUANMin－jia1DONGChao1SHENPei－lin1LUHai－wei2WANGJin－shuang2FANGBo2GUOYi－guang11．ShanghaiJahwaUnitedCompanyLtd．Shanghai201702China2．LabofＲheologyCollegeofChemicalEngineeringEastChinaUniversityofScienceandTechnologyShanghai200237ChinaAbstractAviscoelasticmicellesystemself－thickeningsystemblendedwithanamphotericsurfactantcocamidopropylbetaineCAPBandanamino－acidbasedanionicsurfactantsodiumlauroylsarcosinateLSwasformedbyadjustingthemassratioandpH．ThenetworkofwormlikemicellesintheblendwasconfirmedviacharacterizationwithCryo－TEMimages．EffectofNaCldosageontheviscosityoftheself－thickeningsystemwasidentifiedandtheviscosity－temperaturecharacteristicsaswellasthefoamingperformanceoftheviscoelasticsystemwereemphaticallyinvestigated．ＲesultsshowedthatwhentheNaClcontentisloww＜0.5%itseffectonviscosityofthesystemisrathersmall．EstablishmentofviscosityofthesystemismainlyaffectedbymassratioandpHofthesystem．Theviscositydecreasesathighertemperature40℃andincreasesatlowertemperature5℃respectively．ThefoamingperformancebecomesworseaspHdeclines．AdoptingthemethodsofadjustingthemassratioandthepHaseriesofself－thickeningsystemsformedbyblendingofanionicamino－acidbasedanionicsurfactantandamphotericsurfactantcanbeobtained．Keywordssurfactantblendself－thickeningwormlikemicellesviscosity－temperaturecharacteristicsfoamperformance、、、、1－3。N－4。·11·45。2α－α－、α－COOH4。、5－7。8。LSCAPB249。pH2。NaCl。。11.1CAPBwCAPB=38%wNaCl=6.2%DHSBwDHSB=30%CHSBwCHSB=30%CBwCB=30%SLwSL=31%LSwLS=30%wNaCl=0.1%SCSwSCS=30%SMSwSMS=93%SPSwSPS=93%NaOHCAw=99%NaClw=99%。NＲCH3CH3+CH2COO－CBＲ=CAPBＲ=NＲCH3CH3+CH2COHCH2SO3－DHSBＲ=CHSBＲ=NCＲOCH3CH2COO－Na+N－LSＲCO=SCSＲCO=SMSＲCO=SPSＲCO=NCH2CH2NHCＲOCH2COO－Na+CH2CH2OCH2COO－Na+SLＲCO=PL4002、S20pHMettlerToledoＲW20digitalIKAIncucell3MDV－2ProBrookfieldJEOLJEM－1400TEM501。1.21.2.1NaOHCApHNaCl24h。pH。1.2.2DV－2Pro。1.2.3GB/T7462—94。2g800mL80g0.342g/L718g40℃40℃。·21·13。50mL50mL。200mL90°。。。2。1.2.4Cryo－TEM25℃CEVS。5μL。－165℃。Gatan626JEOLJEM－1400TEM120kV－174℃GatanCCDDigitalMicrograph。22.1CAPBLSNaCl2.1.1CAPB/LSCAPBLS12%QB1994—2004pH25℃24h。。pH1。1pHCAPB/LSTab.1EffectofmassratioandpHonviscosityofCAPB/LSsystemw/%CAPBLSpHη/mPa·s1204.00～7.0020934.603600845.105400755.304200665.402900575.401700485.405500124.00～7.002012pHpH4.00～7.00CAPB/LB8/4pH=5.10CAPBLSpHCAPBLS。2.1.2Cryo－TEMCAPB/LS8/4pH=5.10Cryo－TEM1。1。pHCAPBLS、10－11。CAPBLS2p=v/lapvlapHCAPBLSp1/212－13。。1CAPB/LSCryo－TEMFig.1Cryo－TEMimageofCAPB/LSsystem2.1.3NaClCAPBLSNaClNaCl2。2CAPB/LSNaClpH。NaClCAPB/LS8/4pH=5.10NaCl·31·453.0%3。3NaCl0.5%NaCl1.0%NaClCAPBLSCAPBLS。2NaClCAPB/LS25℃Tab.2EffectofNaCldosageonCAPB/LSviscosityat25℃w/%CAPBLSpHwNaCl/%η/mPa·s485.400.680.621.30550650575.400.830.471.3017001750665.400.990.311.3029003000755.301.150.151.3042004400845.101.3001.30540054003NaClCAPB/LS25℃Tab.3EffectofextraNaCldosageonviscosityofCAPB/LSsystemat25℃wNaCl/%00.10.30.51.02.03.0η/mPa·s57006000580055004800240018002.2CAPB/LS。CAPB/LS8/4pH=5.10NaCl2。2NaClCAPB/LSFig.2Viscosity－temperaturecharacteristicvs．increaseofNaCldosageintheCAPB/LSsystem240℃5℃。22。NaCl5℃“”40℃Na+CAPBLS。。40℃、25℃5℃。2.3CAPB/LS2.3.1pH。CAPB/LS。4。4CAPB/LS9/311～12cmCAPB。9/34.6cmLS5.2cmpH4.605.00pH。LSpHpH。pH14－15。pHCAPB/LS8/4pH5。5pH。·41·14CAPB/LS40℃Tab.4FoamingperformancecomparisonofCAPB/LSsystemwithseparatemassratiow/%CAPBLSpHh/cm1205.0011.9934.604.6845.1012.2755.3011.8665.4011.6575.4010.8485.4011.40125.005.25pHCAPB/LSTab.5Foamingperformancevs．separatepHofCAPB/LSsystempH7.006.005.505.405.305.205.105.004.90h/cm16.015.514.311.911.711.612.07.96.02.3.2NaClCAPB/LS8/4pH=5.10NaCl6。6NaCl0.5%12cmNaCl1.0%9cm。NaCl15。NaCl。6NaClCAPB/LSTab.6Foamingperformancevs．increaseofNaCldosageintheCAPB/LSsystemwNaCl/%00.10.30.51.02.03.0h/cm12.611.411.312.19.39.810.52.42.4.1pH=4～7SCSLSSMSSPSCAPB6/625℃3。3pHpHpH。3CAPBFig.3ViscosityofthesystemofCAPB/sodiumN－alkyl－sarcosinatewithseparateC－chainlength2.4.2CAPB/7。7。16。LS。7CAPB/Tab.7FoamingperformanceofthesystemofCAPB/sodiumN－alkyl－sarcosinatewithseparateC－chainlengthw/%CAPBLSSMSSPSSCSpHη/mPa·sh/cm665.40290011.6666.00220007.3666.00280002.5665.3011756.52.5pH=5.30～5.60CAPBCBCHSBSLDHSBLS6/625℃Ｒoss－Miles40℃8。8pHLSCHSB/LS。·51·458Tab.8Comparisonofseparateamphotericsurfactantsystemw/%LSCAPBCBCHSBSLDHSBpHη/mPa·sh/cm665.40290011.6665.3062010.5665.401380016.8665.60140014.7665.5058011.53pHLSCAPB。pHNaCl。/CAPB/LSpHCHSB/LS。pH。1MAＲIAＲILOUＲDESPAUＲOＲAP．Aminoacid－basedsurfac-tantsJ．ComptesＲendusChimie2004617583－592．2．N－J．200636294－98．3YAMAMOTO．Alkylaminoacid－typesurfactantwithlowskinirrita-tionandgoodhardwaterresistanceJP2000144173A2P．2002－05－26．4CAＲMEN．“Green”aminoacid－basedsurfactantsJ．GreenChem200461233－240．5SAMPADGDIBYENDUKJOYKＲISHNAD．Interactionbetweenzwitterionicandanionicsu