导电聚合物简介

1,2,3(1.200062;2.200233;3.223602):,:;;;:1005-6629(2001)02-0022-03:O631.2+3:B10102000(Shi2rakawaH.)[1](MacdiarmidA.G.)(HeegerA.J.),:??1,Shirakawa,ShirakawaMacdiarmid,MacdiarmidShirakawa,,HeegerX,,,:,,,,Br2Cl2I2,,I2,,100,[1],,10,,,2,,(p-)(n-),,[2],,,,,:,,,,,,(1),,,,,(),,,222001,2©1995-2005TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.,,,,,,31977Shirakawa,,(1)[3],,1()max/S.cm-1(1977)105(1981)103(1978)103(1980)103:10-9S/cm105S/cm,,,,,UNIX,,,4MB[4],(),-,,[2],1987,3(LiAl/LiBF4-PC/PAn),1000h,,[5],-,[2]-,-0.2+0.8V()--,PAn/WO31s,104,31%80%[4][5],(10-11esu),,,,,,,,,,4,322001,2©1995-2005TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.:,,,,,,,,,,,!:[1]ShirakawaH.,LouisE.J.,MacdiarmidA.G.,etal.J.C.S.Chem.Comm[J].,1977:578[2].[J],1999,3:4753.[3].[J],1999:48.[4],,.[J],1998,29:353.[5]BaughmanR.H.,Macromol.Chem.Macromol.Symp[J].1991,51:193.(,310024):,:;;:1005-6629(2001)02-0024-03:TB383:B8010-710-9,,,,,11100nm(200300nm)(200600nm),,,1.1,,1.2,,,,,10nm,90m2/g,5nm,180m2/g,2nm,450m2/g,,,,,1.3,422001,2©1995-2005TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.