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○ SUMMARIZATIONAND SPECIALCOMMENT周盾白1,2, 贾德民1, 黄险波2(1., 510640;2., 510620) :、。,,,50%。—、、,。、、、,。,()。:;;;:TQ436.5 :A :1001-0017(2006)04-0248-05AdvancesinApplicationandResearchofAqueousAdhesivesZHOUDun-bai1,2,JIADe-min1andHUANGXian-bo2(1.CollegeofMaterial,SCUT,Guangzhou510640,China;2.KingfaCo.Ltd.,Guangzhou510620,China)Abstract:Theprospect,applicationandadvancesintechnologyandresearchofaqueousadhesiveswerereviewedinthispaper.Thewholeworldpaidattentiontothedevelopmentofenvironment-friendlyadhesives.Insomedevelopedcountries,theaqueousadhesivesincreasedatalltimeandnearlyaccountedfor50%oftotalamountsofadhesives.Somehigh-performanceaqueousadhesives-suchasacrylic,PU,epoxyetc,wereabletosubstituteforthesolventadhesives.Theaque-ousadhesiveswerewidelyusedinthefieldsofbuilding,packaging,transportation,tapesetc.Thetransitionofadhesivesfromsolvent-basedtowater-bornehadbecomenecessitywithpayingmoreattentiontoenvironmentprotection.Keywords:Aqueousadhesives;application;research;development前 言,,,、、。,,、,,,,[1]。(),、。,[2]。,,,,[3]。,,,,,。:、、、、[1,2]。,,,。:2006-01-18:(1972-),,,-。。1∶0.32、1%、1∶1。、,,。,、。 :[1] ,,,.[M].:,1983.[2] ,.[M].:,1998.·248· , Vol.28.No.4,20061 世界胶黏剂发展动向:,。,。1998,50%,20%,20%。“”,。,。、、。,。1.1 [4]1998261,14.0%,86.0%。:9.2%、59.3%、20.0%、0.4%、10.4%。1 Table1TheapplicationdistributionofadhesivesinUSA/%/%33.22012.1351.2 1998140,,(18%,17%)[5]。2 、、Table2ThemarketdistributionofadhesivesinGermany,EnglandandFrance/%/%、303281、19151481.3 3 Table3ThespeciesofadhesivesinJapan/%/%29.427.2917.010.8114.713.6010.887.03 1995120.9,1997[5]。1998、1999100,2000111,101。,。1.4 2000240,、、、。、、、VAE、。4 1997Table4TheconsumptiondistributionofadhesivesinChinain1997/%/%3472582845 1997Table5ThespeciesandproductionofadhesivesinChinain1997//432.5201.5200.8150.7100.550.553VAE2.5130 DDNA,、,、、、。、、、。。2 水性胶黏剂研究进展2.1 2.1.1 氯丁胶乳胶黏剂,,、[3]。,。:2--1,3-2,3--1,3-、、()、、、[6]。,,Latex735,La-tex5587,Latex654。pH,12~13,40%~60%,45~600mPa·s[7]。,·249·2006284 CHEMISTRYANDADHESION ,L-100。,pH7~8,、。L-10050/,40/,L-100,。,,Aquastik2161,58%,、、,[7]。2.1.2 丁苯(SB)胶乳胶黏剂SB-。。50%,。,。20%~30%。。(25~50℃),(10℃),,,、[3]。2.1.3 丁腈(NB)胶乳胶黏剂-。NB,(35%~40%)、(25%~35%)、(20%~25%),。,,。NB、、、、,。、,[8]。2.2 ,。,。[9]/。。,、MMABA,。。[10]Wetlink78。Wetlink78,,,。H.B.FullerPN-3759-Z-X,,210~240m/min,,[11]。,CET100A/CET10B,,A,B。AB,[12]。F-102,-A,15℃,[13]。2.3 (APU)。、、NCO[14,15]。H.B.FullerWD-4003、WD-4006WD-4907,[16]。ZenecaResinsNeo-RezR-563(PVC),ZeoRezR-550()[7]。PU,API,-(WPI)。,,,,、,,,,[16]。、、,。:50%,40~60℃。(EVA、),,,[17]。YoshihiroOkamoto[18],,。,。[19]PU,PUA,PUA·250· , Vol.28.No.4,2006、。M.Hiroset[20],,。,。JungHyukKim[21],,MMA。IPDIDMPAPU,,。、。[22],、。,。HuntsmanPolyurethanesRubinate9236,10%Rubinate9236Rohm&Hass,/,2MPa,200%;Rubinate923615%,2.62MPa60%[23]。BASF,[17]。2.4 ,,。,A,、、,A。,。,、。-。,。、、、、[24]。DowDeutschland[25],(VOC),。,,、,。3 水性胶黏剂的应用,,、、、、、。,、、、;,,199626%;,、[1]。3.1 ,。GarrettJ[32]/:(a)--/-(PBA/AA);(b)---(PMMA/AL-MA)/(PBA/AA)。,,。,[26],、50%,。[27],-,、、、。[28]、、、,、、,,,,。。[29]BST-7,-(VAE),,。BST-7ARO-COAT,,。[30]VAE,NL-1。50%,3Pa·s,、,。3.2 ,·251·2006284 CHEMISTRYANDADHESION 。1992,1994“”。,ISO(ECP),[31]。,,107。107。[32]-108,,、、,,。[33],、、,。,,、,,、、,,。[34],,,。3.3 ,,。,,,。,、、、,,[35]。,。[36]、,,、,。MDI,100N·cm-1。[37]PU,,PU,。 :[1] ,,.[J].,2000,9(5):34~37.[2] .[J].,1990,11(12):12~15.[3] .[J].,1991(4):47~50.[4] .[J].,2000(18):33.[5] .[J].,1999,27(2):30~35.[6] CHRISTELLLANCEALAN.High-performancewater-basedchloroprenepolymeradhesivecomposition:WO,9413703[P].1994-6-23.[7] RICHARDTABIBIAN.Globalcompetitionleavesnotimetorest[J].AdhesivesAge,1993(5):32~39.[8] AMSNOW.Adhesives,sealants&caulkingcompoundsincluded[J].AdhesivesAge,1980(7):35~37.[9] .D4-[J].,2000,9(6):10~12.[10] ,,.[J].,2003(3):36~38.[11] PETERAVOSS.Adhesionandadhesives[J].AdhesivesAge,1998(5):26~28.[12] ,,.[C]//2000.:,2000:7~11.[13] ,.[J].,1997(4):1~4.[14] ,,.[J].,2001,22(3):11~12.[15] BETHW,MCNINW,SCOTTS,etal.Syntheticlatexproducts[J].AdhesivesAge,1995(11):34~41.[16] .[J].,2002(5):28~31.[17] ,.[J].,1999():92~94.[18] YOSHIHIROOKAMOTO,YOSHIKIHASEGAWA,FUMIOYOSHINO.Urethane/acryliccompositepolymeremulsions[J].ProgressinOrganicCoatings,1996(29):175~182.[19] ,,,.[J].,2001,28(5):31~32.[20] MHIROSET,FKADOWAKI,JIANHUIZHOU.Thestructureandpropertiesofcore-shelltypeacrylic-polyurethanehybrideaqueousemulsions[J].ProgressinOrganicCoatings,1997(31):157~169.[21] JUNGHYUKKIM,JINSUPSHIN,INWOOCHEONG,etal.Seededemulsionpolymerizationofmethylmethacrylateusingaqueouspolyurethanedispersion:effectofhardsegmentongraftingefficiency[J].ColloidsandSurfaces,2002(207):169~176.[22] ,,.[J].,2002,17(1):12~14.[23] .[J].,2002,11(4):43~47.[24] ANGEA.Epoxydispersionsinadhesiveapplication[J].AdhesivesAge,1995(5):34~37.[25] KLEINDH,JORGK.Two-componentaqueousepoxybindersfreeofvolatileorganiccontent(VOC)[J].ProgressinOrganicCoatings,1997(32):119~125.[26] GARRETTJ,LOVELLPA,SHEAAJ,etal.Water-bornepressure-sensitiveadhesives:Effectsofacrylicacidandparticlestructure[J].MacromolecularSymposia,2000,151:487~496.·252· ,
本文标题:水性胶黏剂的应用及研究进展-周盾白
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