羟基丙烯酸树脂的合成研究进展-李红强

2013352CHEMISTRYANDADHESION。、、、、。。、、、、、。。1。～～∶～∶、、。～℃～℃。。。TgWTgWTgWTg…、、。～～～。、*、。。ProgressinSynthesisofHydroxylAcrylateResinLIHong-qiang1,CHENJing-hua1,ZENGXing-rong1,ZOUFa-ze2andZHENGYe-mei21.CollegeofMaterialsScienceandEngineering,SouthChinaUniversityofTechnology,Guangzhou510640,China;2.GuangdongTopchemindustryCo.,Ltd.,Zhaoqing526241,ChinaAbstractHydroxylacrylateresinisanovelkindofresinwithrapiddevelopment,whichnotonlyhashighsolidcontentandlowviscosity,butalsocanbereactedwithisocanatetoformcrosslinkedstructure,andtheobtainedcoatinglayerhasgoodoverallperformance.Nowhydroxylacrylateresiniswidelyappliedtoautomobilecoatings,woodwarecoatings,etc.Themolecularstructuredesignandrecentprogressinsynthesisofhydroxylacrylateresinaresummarized,anditsdevelopmenttrendisalsoproposed.KeywordsHydroxylacrylateresin;highsolidcontent;organicsilicon/fluoromodification;waterborne;progressinresearch··Vol．35No．22013～。2、。2.1。～、·。。。、、、、。～。。、、、、·。。、、·。———·。2.2/、、、、、、、、。“”、、。、、。。、、、。。。、。、、、γ。°°、、、、。、、β、。、、。°°。、、。··2013352CHEMISTRYANDADHESION2.3。、、、、～·～～μ～。、、、、、、。、、。。。。、、、、。。、。。1PAS、PAEPATFig.1SchematicdiagramofpolymerizationmethodofPAS,PAEandPAT··Vol．35No．22013hydrogenperoxidandcatalyticseleniumdioxideJ.SyntheicCommunications,1999,2514:2121~2133.9AMRITAROY,REDDYKR,MONBANTAPK,etal.HydrogenPer－oxide/BoRicAcid:AnEfficientSystforOxidationofAromaticAld－hydesandKetonestoPhenolsJ.SyntheicCommunications,1999,2921:3781.10MASAKATSUMATSUMOTO,HISAKOKOBAYASHI.Hexa－cyanoferrateCatalyzedOxidationofTrimethoxybenzenestoDimethoxy-p-benzo-quinoneswithHydrogenPeroxideJ.J.Org.Chem.,1985,50:1766~1768.11HIDEAKIOTSUKA,MAMITAKEUCHI,SHOGOINOSHIRIL.Phe－noliccompoundsfromcoixlachrymal-jobivar.ma-yuenJ.Phy－tochemistry,1989,28:883～886.12HORTONWJ,MASONGS.BoronTrifluoride-CatalyzedAcety－lationofMethoxyhydroxybenzenesJ.J.Org.Chem.,1962,27:830~833.13STOUTMASONG,REICHHANS,HUFFMANMAXN.4',5,6-Oxygenatedflavonesandflavanones.J.J.pharmacy.Sci.1964,53:192~195.!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!3。、、、、、、、。。1NATHALIEH,ACHIMK,MARCCARLOM,etal.ShellOilCompany,Highsolidscoatingcompositions:US,6069203P.2000-05-30.2,,,.J.,2012,425:32~35.3./HDIJ.,2007,232:153~156.4.J.,1995,2:10~15.5,,,.M.:,2011:118.6,,,.J.:,2003,24:402~405.7,,.J.,2002,403:5~9.8,,,.J.,2007,2412:25~27.9,,,.:CN,200710031047.4P.2008-05-07.10.J.,200012:8~10.11ZHANGK,FUHQ,HUANGH,etal.Waterborneepoxy-acrylicdispersionsmodifiedbysiloxaneJ.JournalofDispersionScienceandTechnology,2007,288:1209~1217.12,,,.J.,2011,335:57~59.13HANSENNML,JANKOVAK,HVILSTEDS.FluoropolymermaterialsandarchitecturespreparedbycontrolledradicalpolymerizationsJ.EuropeanPolymerJournal,2007,432:255~293.14LIXF,ZHANGJF,ZHOUXP,etal.Synthesisofcore-shellfluoroacrylatecopolymerlatexviaemulsionpolymerizationanditsapplicationinink-jetinkJ.JournalofAppliedPolymerScience,2012,1261:110~115.15,,,.J.:,2004,326:45~49.16,,,.J.,2006,441:7~9.17,,.J.,2011,2710:19~22.18,,.J.,2009,123:17~20.19,,,.J.,2009,176:750~751.20,,,.:CN,200510134997.0P.2006-7-12.21,,,.J.,2005,229:717~720.22,,,.2K-WPUJ.,2012,427:1~5.··