第十五章含硫含磷化合物

第十五章含硫含磷化合物1.解:(5)(1)(2)(3)(4)(6)(7)(8)(9)(10)CH3CH2OSO3CH2CH3CH3SO2ClNO2SO3CH3(Ph)3P=ONH2SO2NH2ClCH2CH2SCH2CH2ClPhSO2PhSOOPhPOHOC2H5PhPClOH2.解:(1)2-巯基乙醇(2)2-巯基乙酸;(3)对磺酸基苯甲酸;(4)对甲基苯磺酸甲酯;(5)乙基羟甲基硫醚;(6)碘化二甲基环已基锍;(7)氯化四羟甲基鏻;(8)N,4-二甲基苯磺酰胺;(9)O,O-二乙基苯膦酸酯;(10)甲基乙基亚膦酰氯3.解:(1)(2)(3)(4)CH3SO2ClC2H5SHCH3SCH3NaOH分层一相CH3CH2SO3HCH3SO3CH3Na2CO3无变化SHCH2CH2SCH3HOCH2CH2SCH3NaOH分层一相CH3COClH2OAgNO3无变化白色4.解:(5)(1)(2)(3)(4)CH3O）3P=O（(n-C4H9)4P+Br-CSSHSCH2CH2OHCH3CH2CH2CHCH2O5.解:(1)CH3H2ONBShvClCH2S=C(NH2)2CH3CH2OHOH-HSCH2(2)CH3CH3ClSO3HCH3CH3SO2ClZn+H2SO4CH3CH3SH(3)CH3ClSO3HCH3SO2ClCH3AlCl3T.M.(4)T.M.CH3CH2CH2OHHBrNaSHCH3CH2CH2SHCH3COSH(5)HBrNaSHCH3CH2CH2SHCH3CH=CH2CH3CHCH3SHNaOHCH3CHCH3SNaHBrCH3CH=CH2H2O2NaSHT.M.(6)HBrNa2SO2BrCH2CH2CH2CH2BrS(7)CH2OHHBrPh3PCH2P+Ph3Br-n-C4H9LiT.M.(8)CHOCHOPh3P=CHCH2CH2CH=PPh36.解:(1)n-C4H9LiT.M.CH3SCH3OCH3SCH2-OCH3CH2COOCH3CH3CH2CCH2SCH3OOAl-HgH3O+(2)CHOT.M.H3O+HSCH2CH2SHHClCHSSn-C4H9LiBrCH2CHCH3OCSS-CSSCH2CHCH3OLiAlH4或(2)CHOT.M.H3O+HSCH2CH2SHHClCHSSn-C4H9LiBrCH2COCH2CH3OCSS-CSSCH2COCH2CH3OCH3SCH3On-C4H9LiLiCH2SCH3OAl-Hg(3)T.M.BrCH2COCH2CH3OCH3CCH3On-C4H9LiPh3PPh3P=CHCOOC2H5