黄腐酸研究进展-周少丽

43820154GuangzhouChemicalIndustryVol.43No.8Apr.2015712000、、、、、。、、。TQ917A1001－9677201508－0041－031983－。ＲesearchProgressonFulvicAcidZHOUShao－liDepartmentofGeologyandTopographyShaanxiEnergyInstituteShaanxiXianyang712000ChinaAbstractsSourcompositionstructureandapplicationstatusoffulvicacidwereintroducedthemainapplicationofFAwereagriculturemedicinehealthcareandaquaculture.Meanwhilethepreparationmethodswereintroducedincludingfermentationionexchangeelectrodialysis.FermentationproducedFAfromagricultureleftoverionexchangeproducedFAbyionexchangeresinelectrodialysisproducedbyionexchangemembraneFAproducedbythemethodslowpurityandhighpricesoitwasimportantandnecessarytofindanewmethodtoproduceFA.KeywordsfulvicacidapplicationpreparationFulvicacidFAFA、、、、、、1。、2FA。11.1、FA、、、。FA、、、。、3FA。。、10%～80%4。5、、、、。40%～60%30%～50%、1%～4%0～2%0～0.03%。1.2FA、、、、、、6、、。。Stevenson7FA170℃3h、。FA、n－、。8。、、。9。4220154。10FAFA、、、。FA665nm465nmE6/E4FAE6/E40.2。11FAFA、、、。FA1720cm－11600cm－1。1.3FAFA。FA2080、、、、、、、、12。。FA。FA、、、。FAFA13。14TC、TG。15。FA16FA、、。、。FA17FA15.5%21.8%15%～20%。FA。FA、、、。FAFAFA、、FA。2FA2.1FA1Fig.1ProductionprocessofFAbyfermentationmethod2090FAFA。1880%～90%70～75℃15～18、。1FA19。20NaOH6hpH2。2.2FAH+FA。21H+NH+4NH+4。Na+95.90%82.10%。2.3FAFAFA22。。FAFA、FA。3FA、FA23FA。、、。1．J．200325118－20．2．J．200123112－14．3GrassetLAmblesA．StructureofhuminandhumicacidfromanacidicsoilasrevealedbyphasetransferhydrolysisJ．OrgGeochem199829881－891．4．J．1997164311－315．5．J．2000133205－209．6．J．．200121－5．7HayspeatasaＲawMaterial．J．2002138－43．8．J．2014421015－17．9．J．1981395401－408．10．UvaiJ．200619243－45．11．J．200121240－41．12．J．2004103281－285．4543845CN1745726A20。CN103632739A21。。3、。。1．J．201206065－068．2．J．200927284－88．3KatzbauerB．PropertiesandapplicationsofxanthangumJ．PolymerDegradationandStability199859181－84．4．J．19951202125－128．5VenkatarajuaMPGowdaaDVＲajeshKSetal．XanthanandlocustbeangumfromCeratoniasiliquamatrixtabletsfororalcontrolleddeliveryofpropranololhydrochlorideJ．AsianJournalofPharmaceuticalSciences200726239－248．6．J．199904460－464．7BejenariuAPopaMLeCerfDetalStiffnessxanthanhydrogelssynthesisswellingcharacteristicsandcontrolledreleasepropertiesJ．PolymerBulletin2008615631－64l．8GilsPSＲayDSahooPK．Characterisfcsofxanthangum－basedbiodegradablesuperporoushydrogelJ．InternationalJournalofBiologicMacromolecules2009454364－371．9CANNING＆COLTDW．ELECTＲODEPOSITIONOFMETALSP．AU30196711975－12－21．10BEIEＲSDOＲFAG．CosmeticordermatologicalcompositionespeciallylightprotectantcompositioncompriseshydrogelandboronnitrideP．EP00110189．82000－11－29．11BEIEＲSDOＲFAG．Chitosanisusedforstabilizationofcosmeticordermatologicalskin－careformulationinformofemulsionhydrodispersionoleodispersionhydrogeloroleogelP．DE10145111．32003－04－03．12BEIEＲSDOＲFAG．Cosmeticordermatologicalcompositionswithanaqueousphasecontaincreatinecreatinineand/oracreatinederivativetogetherwithanelectrolyteP．DE203184152004－04－01．13BEIEＲSDOＲFAG．Colorequalizationofdifferentlypigmentedskinregionsusefulforcosmeticordermatologicaltreatmentse．g．oflentigooragespotscontainsaself－tanningagentP．EP047345162004－05－24．14DEXCELPHAＲMATECHNOLOGIESLTD．Delayedonsetslowreleasecompositionusefulfortreatinge．g．liversideeffectsandmusclepaincomprisesslowlydisintegratingcoreofstatinfillerandreleasecontrollingagentandratecontrollingcoatingP．WO2006/0003872006－10－05．15BＲYANTCM．Preparationofhydrogelusefulinfragranceandflavorproductsbymixingfunctionalpolymerandactiveingredientsextrudingmixtureunderdryconditionsandforminghydrogelin－situbycontactingwithwaterP．US11/1148202006－10－26．16MALLINCKＲODTLLC．CompositionfortreatingpaincomprisesimmediatereleaseportioncomprisingacetaminophenandoxycodoneoritssaltP．US13/4735632014－02－25．17CHUNGHWAPICTUＲETUBESLTD．Manufacturingpelletizedfertilizerusedinhydroponicculturecomprisesmixingwater－solublemanureandcolloidalsolutiontoaformaqueoussolutionoffertilizerandaddingaqueoussolutionoffertilizerintowaterP．US13/7837162014－2－13．18UNIVCHONBUKNATINDCOOPFOUND．Manufactureofhydrogelusedforselectiverecoveryofvaluablemetalinvolvesaddingmixedsolutionofmetal－reducingsubstanceandpolymersolutiontomembranouspolymer－coagulatingagentsolutionandsolidifyingresultantbubbleP．KＲ10－2013－01082302013－11－12．19．P．200510023273．92005－10－12．20．P．200510030452．52006－3－15．21．60P．201310681093．42014－檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵03－12．4213LiangHJTaiCLLuFJ．OxidaativestressinducedbyhumicacidsolventextractionfractioninculturedrabbitarticularchondrocytesJ．ToxicolEnvironHealth1998547477－489．14．J．201136564－48．15．J．2000166354－357．16．J．2002329－30．17．．1M．200016－19．18．J．200325118－20．19．D．2004121－23．20．J．200020528－30．21．J．201418595－99．22．J．2000325－28．23．D．2008．辀辀