浙江大学有机化学(丙)试题库(完成反应2)

112CH2=CHCH2CHO+CH2OHCH2OHHCl(g)KMnO4/OHr.tH2OH+3+CHONO2O2NH2NHN4+CHOCH3MgIH2OH+52CH3CHO稀OH6+CHOOCH3HCHO浓碱7+CH3CH2COCH3I2/NaOH82+CHOAg(NH3)2OH9CHONaBH4H2O乙醇10+OCH2=CHMgBrH2OH++CH2CCH3OBr2/NaOH21112+CHOCHOHCHO（过量）浓碱13OHCH2CCH3OZnHgHCl141.CH3CH2CHO2.H3O+CH3CHMgBrCH315+OOH2NNHCNH2O216+CHOCH2OHOHHHCNOH（用式表示）Fischer17H2OH++OMgBrH+18H2OH+(CH3)3CMgBrCO2+19+CH3CHCH2CH3OHNaOH/I220H2SO4CH2CHO1.2.H3O+CH3CH2MgBr321高温COH2NNH2OHDMSO,,22CH3OLiAlH4H2O1.2.23CHOCHCHOCH3Fehling24ONOH()25O()OO26OH2/NiH+Cl2光NaOHH2O27CH3CHCH2CHOCH3OH稀2CH2CHO(C6H5)3P=CHCH(CH3)228CH2CHCOOHCH3NaOH/Br2NH3429TollensCHOCHCHOCH330H+CH3CH2ONa1.2.CH3COOC2H531CH2CH2CH2COOHOH32OONaOH33NH3CH2COOHBr2/NaOH34CH2CH2COOHCH2CH2COOH35OCOOHHOOC36CH2CH2COOC2H5CH2CH2COOC2H5H+CH3CH2ONa1.2.H3O+537H2SO4+COOHOHCH3COCCH3OO38CH2ClCOCH2ClH3O+H3O+HCNNaCNEtOH39+OCH2OHNaAcCH3COCCH3OO40+CH3CHCH2COOHCH3NaHCO341+CH3CHCH2COOHCH3PCl342OOOCH3CH2OH43CH3NHCCH3ONO2H2OOH稀44吡啶OHSOCl2(CH3)3CCOOH645SOCl2COOH(CH3)3COH吡啶46NH+CH3OCOBrNaOH47OH+CH3OCOBrNaOH48+OOONH3249CH2CH2COOC2H5CH2CH2CH2COOC2H5CH3CH2ONaCH3ONa1.2.CH3IH3O+50LiAlH4H3O+1.2.KMnO4/H+COOC2H551Br20℃NaNO2H2SO4H3PO2CH3NH2527NH20℃NaNO2H2SO4CH3OOH弱碱性53NH20℃NaNO2H2SO4HClCu2Cl254NO2Fe/HCl0℃NaNO2N(CH3)2HClH+55NO2Fe/HClCH3COCl吡啶56+NHCH3CH3SO2Cl57+NHHNO258Br2(H2O)OH59+CH3CH3COClAlCl3无水H3O+I2/NaOH860CH3CHCH2CONH2CH3NaOH/Br261（酮式）（烯醇式）+CH2COClCOClH2NCONH262+N2ClCH3N(CH3)263+CH3CH2CH2CHO(C6H5)3P=CCH2CH3CH364+OOO265+OCCCF3CF366OCHO浓NaOH679+NKNO3/H2SO4(SO3)300℃68NHKNH2NH3（液）+69+HNO3NCH2CH370+KNO3/H2SO4(SO3)NFe/HCl71+NHNa72+CH2OCO(CH2)16CH3CHOCO(CH2)14CH3CHOCO(CH2)7CH=CH(CH2)7CH3NaOH3(aq)73H3O++CH3(CH2)12CH=CHCHCHCH2OPOO(CH2)2N(CH3)3OOHNHCOR7410+CH2OCORCCH2OHRCOOPOOHOHHOCH2CH2N(CH3)3OH+75+OCH2OHOHOHOHOHBr2/H2O76+OCH2OHOHOHOHOHCH3CH2OHHCl77OCH2OHOHOHOHOH+Ag(NH3)2OH783OCH2OHOHOHOHOH+NO2NO2NHNH279稀HNO3CHOHOCH2OHOHOHHHH1180H2OLiAlH4CHOHOCH2OHOHOHHHH1.2.81OCH2OHOHOHOOCH2OHOHOHOHHHH3O+HO82+Ag(NH3)2OHOOHOOHOHOH83OOCH3OCH3CH3OH3O+OCH3CH3O84HOOOHCH2OHHOHOCH2OCH2OHOHOHOHH3O+85HCCNaCH3CCH3OH2O+章小波