有机化学课后习题答案南开大学版5脂环烃

第五章脂环烃1.试写出下列化合物的结构式：(2)(3)(1)ClCCHClCl(4)(5)(6)CH3CH(CH3)2CH32.命名下列化合物（后三种包括英文命名）(1)3,4-二甲基-1-氯双环[4.4.0]-3-癸烯(2)1,7-二甲基螺[4.5]癸烷(3)8-氯双环[3.2.1]辛烷(4)顺-1,2-二甲基环己烷(cis-1,2-dimethylcyclohexane)(5)3-甲基环己烯(3-methylcyclohexene)(6)双环[2.2.2]辛烷(bicycle[2.2.2]octane)3.写出下列化合物的最稳定构象:(2)(3)(1)(4)C(CH3)3CH2CH3ClCH(CH3)2ClCH3(CH3)3CCH3CH3CH34.完成下列反应式:(2)(1)Br2/CCl4BrBrBr2300。CBr(3)(4)H3CClCH3HClH3CCH3BrHBrROOR(5)(6)OHOHKMnO4,H2O冷，碱性热KMnO4,H2OCOOHCOOH(7)(8)冷的浓RCO3HCH3OHH3CH2SO4O(10)(9)HClCH3O3Zn/H2OCH3CHCH2CH2CHOCHOCl(12)Br2/CCl4(11)Cl2高温ClCH2CH2CH2BrBr+HBr(13)CH3CH3CH3CH2CHCH3CHCH3BrCH3CH2CHCHCH3BrCH3(14)+HBrCH2BrCH3CH3Br+(15)OOOOOO5.试说明下列反应结果(*表示13C):NBS****25%25%*25%25%相同Br*50%Br*Br*25%25%+6.7.CH3CH3ABCDH3CBrBrOOOH3C8.ABCCH3或CH3CHCH2CH3BrCH3CH=CHCH3CH2=CHCH2CH39.CH3C=CHCH2CH2C=CHCH2OHCH3CH3H+H2OCH3C=CHCH2CH2C=CHCH2+CH3CH3+H+H2OOH10.11.从环己醇及其必要的原料出发,合成下列化合物:(1)Br2OHNaOHNBS醇BrBrBrHBrBrNaOH醇NaOH醇(2)H+OHRCO3HO(3)Cl+Cl(4)H2/Ni