升华在化工过程中应用

200296ChemicalProductionandTechnology225002[1～3]4[4][1,2]1-[1～3]1231[1,2]2(1)(2)1000ng/mL0.4～2ng/mL(3)221.///////.//.///////.//2002-08-1399KJB1500071β-DL-α-1-130℃1.2×10-3kPa2-180℃50℃0.13kPa150℃0.13kPaI2SAsAs2O3Hg-Cl2CaCl2CdCl2Zn-Cl2AgClMnCl2AlCl3(HClTaCl5(150℃NbOCl3(230℃NbBr5220℃TaBr5300℃TaI5540℃HCOOH200℃Al3+Fe3+SiC2/℃/℃/0.10MPa/(0.67～1.33)×10-5Paβ-2151311197912012277～7959～6143～4536～3843～4543～4528～3149～5230～34252533～3513[5～8]1121112121114[1～3,7～11]FickdmAdt=MDCs-CbL1m-A-t-M-D-Cs-Cb-dmAdt=MD1RTPeq-PbL(2)Peq=Bexp(ΔHsubRT)(3)4.121224.2122200296ChemicalProductionandTechnology232--345Herreshoff2[1]66.12%=rPAC+PBC/PAS+PBS1+r-PAC+PBC-ΔP/PAS+PBS×100(4)r-r=P1/(PAS+PBS)=(P-PAS-PBS)/PAS+PBSPAPB-ABSC-P1-ΔP-;P-ESPSECPCESEC4rr6.277.1[12]2H2S+O2#2S+2H2OSO22H2S+SO2#3S+2H2OSO2+C#S+CO27.2[13]98.5%115～125℃97℃50℃7.3[1]7.4[1417～19]2050X7.5[15]1978HerbertLehmkuklWjlhelmEisen-bachr[15]7.6[1416,17]402060EMU90Hermes7.7[18～21]7.8[2223]7024200296ChemicalProductionandTechnology25-281PerryRH.Perry'sChemicalEngineersHardbook.6Ed.McCraw-Hill1984.chapter172MeloanCE.ChemicalSeparations.JohnWiley&Sons,NewYork1999.81～833LemarchandD,GaillardetJ,GopelCetal.Numericalsimulationofflowinanarrayofin-linebluntboardsmasstransferandflowpatterns.ChemicalEngineeringScience,2001,56(5)1883～18964Ⅱ.1989.901～9025SassellaA,TubinoR,BorghesiA,etal.Entropy-drivenphasetransitions.PhysicaAStatisticalMechanicsanditsApplications,1999,263(1-4)26～386LittleCHA,StrunzGM,FranceRLa,etal.Thermaldegradationof1-deoxy-1-piperidino-D-fructose.CarbohydrateResearch,1970,15(2)205～2137..199713(3)13～188..199730(4)480～4849FoxECandThomsonWJ.Coupledheatandmasstransportinunsteadysublimationdrying.AICHEJ,1972,18(4)792～79710Ramsden,PaulA.(USA),Glow-in-the-darksublimation-receptivemediumandmethodofmaking.PCTInt.Appl.WO2002011995A211Volodin,AN;Gushchin,AA;Korablev,AM;Kras'ko,OV;Lazarchuk,VV(SibirskiiKhimicheskiiKombinat,Russia),Sublimationapparatusforuraniumsalts,Russ.RU2159659C112RubinIB,BuchananMV.Determinationoftheelementalsulphurcontentofmineralsandores.Talanta,1976,23(5)395～39713.10-.200034(2)187～18914L'vovBV.Theendurancelifetimeoficefragmentsincometarystreams.PlanetaryandSpaceScience,2001,49(1)23～2915..200127(2)106～10816..200026(5)552～55517VivienL,RiehlD,HacheF,etal.WatervapourintheatmosphereofMars.AdvancesinSpaceResearch,2002,29(2)183～19118Methodofmanufacturingsiliconcarbide,siliconcarbide,compositematerial,andsemiconductorelement.Eur.Pat.Appl.EP1160361A119MárquezN,YsamberttF,CruzCDL.Opticalpropertiesoforientedthinfilmsofoligothiophenes.SyntheticMetals,1999,101(1-3)538～54120HwangKS,SungHJ,HyunJM.PreparationofZnGa2O4thinfilmbysol-gelprocessandeffectofreductiononitselectricconductivity.JournalofNon-CrystallineSolids,1997,218135～13821BurtonJJ.Separationandpurificationofberylliumbythefractionalsublimationofberylliumacetylacetonate.AnalyticaChimicaActa,1969,44(1)159～16422SkorovYV,KomleNI,KellerHU,etal.Hotairandfreeze-dryingofhigh-valuefoodsareview.JournalofFoodEngineering,2001,49(4)311～31923BeechM,NikolovaS.Applicationsofmassspectrometrytofoodproteinsandpeptides.JournalofChromatographyA,2000,893(1)1～21....