润滑剂生物降解性能试验方法研究进展

20086Jun.2008LubricatingOil233Vol.23,No.3:100223119(2008)0320001206,,(,100083):,,CO2,,;DOC;BOD/COD,,;,,:;;:TE626.3:A0,,,[1]13%,32%,[2],,,,,,OECD301ISOASTMCECL-33-A-93,,,1,,:,(CO2)(H2O),(O2),(),,:(1)CO2,,STURMISOASTM(2)O2,BOD/DOC,MITI(3),,CECL-33-A-932,OECDCECL-33-A-93ISOASTM,80,,CECL-33-T-82,1993CECL-33-A-93,1981OECD301:2007-10-09:(1973-),,,2005,,2200823,(ISO),ISO9408ISO9439ISO14593(ASTM)ISOOECD,,ASTMD5864ASTMD6139ASTMD6731,,2.1OECD1981OECD301A301B301C301D301E301F[3-8],,:(),1,,(DOC),,(CO2)(H2O)DOCO2CO2,,28,,,,;28,12,1,(100mg/L),11OECD301ADOCDOC--+/-301BSTURMCO2+-+301CMITIBOD/DOC++/-+301DBOD/COD+/-++301EOECDDOC--+/-301FBOD/COD++/-+:+,;-,;+/-301B301C301D301F,301F,,,2.1.1STURM,,CO2,CO2,,CO2CO2CO2,,28CO260%CO2,28,10,10%CO2,101060%CO2,2.1.2MITI(),,,3.3CO260%BOD/DOC,10MITI2.1.3,,,,,,CO2KOH(ThOD),CODBOD28CO260%BOD,102.1.4OECDOECD301,,,[9]301D,,301F,,2.5mg/L,CO2O2,CO2O2,301BSTURM,CO2(DIC),CO2,,02OECD2OECD301A301B301C301D301E301F/mgL-1100210100DOC/mgL-1104010201040ThOD/mgL-151050100/cellsmL-1107108107108107108104106105107108pH7.40.27.40.27.07.40.27.40.27.40.2/2222222512222222222.2CEC2.2.1021,()(252),,,,1,1,2-,IR,CH3-CH2-C-H2930cm-1:95%110%;CEC;80%3CECL-33-A-932.2.2CECCECL-33-A-93[10],,C-H,,CEC,CO2,,,14.8%,25.2%,3CECL-33-A-93CECL-33-A-93/mgL-150/CFUmL-1104107/2512.3ISO,,ISO7827[11],4200823DOC;ISO9408[12],;ISO9439[13],CO2;ISO10708[14],;ISO14593[15],CO22.3.1ISO9439,,CO2,CO2,CO2CO2CO2,28,(DIC)5%;14,60%;pH68.5,CO24070mg/L,2.3.2ISO14593ISO14593(CO2),,,28,14,60%;,15%,2.3.3ISO14593CO2,,pH3,1h1mL,:pH3,CO21,CO2,CO24ISO9439ISO145932.3.4ISOISO9439,;ISO14593,CO2,CO2,[13];,CO2,ISO14593,,,,124ISO9439ISO14593ISO9439ISO14593/mgL-12020/cellsmL-1103106102105pH7.46.5/202520252.4ASTMASTMD5864[16]ASTMD6139[17]ASTMD6731[18],ASTMD6006[19]2.4.1ASTMD5864ASTMD5864OECD301B,,,CO2,CO22025,28,60%;CO225mg/L,2.4.2ASTMASTMD6139ASTMD5864,4L2L,;,ASTMD6731ISO9408OECD301F,,,ASTMD58643.5ASTMD6139,,,,ASTMD6731OECD301F55ASTMASTMD5864ASTMD6139ASTMD6731/mgL-11020102020/cellsmL-1106107106108106107pH7.07.07.4/2025222024CO2CO2BOD3OECD301ISOASTMCECL-33-A-93,6,CEC,OECD3016DOCDOCOECD301ASturmCO2OECD301BMITIDOCOECD301CBOD/CODOECD301DOECDDOCOECD301EBOD/CODOECD301FDOCDOCISO7827BODISO9408ISO9439CO2ISO9439BODISBOD/CODISO10708CO2CO2ISO14593CECIRspectrumCECL-33-A-93D5864-00CO2ASTMD5864-00D6139-00:GledhillCO2ASTMD6139-00D6731-01:BODASTMD6731-01[20]CECL-33-A-93[21-22]CEC,,CECL-33-A-93CEC,,[23],,()CEC,,,,,OECD301FBODCO2,BODBOD,,,,,CO2,CO2,,CO2,CO23715%,OECD301FASTMD6731ISO15462[24],,CO2,[25-26]6200823CO2,DOC(OECD301AISO7827),1010%(OECD301BISO9439),,CO2(IR)CO2KOH,CO2421,,,,,:[1]LouHonary.MakingaCaseforSoy-BasedLubricants[J].LubEng,1998,54(7):18-20.[2]WilfriedJBartz.LubricantsandtheEnvironment[J].Tri2bologyInternational,1998,31(1-3):35-47.[3]OECD301A-1993,DOCDie-AwayTest[S].[4]OECD301B-1993,CO2EvolutionTest[S].[5]OECD301C-1993,ModifiedMITITest()[S].[6]OECD301D-1993,ClosedBottleTest[S].[7]OECD301E-1993,ModifiedOECDScreeningTest[S].[8]OECD301F-1993,ManometricRespirometryTest[S].[9]LeonPO’Malley.EvaluationandModificationoftheOECD301FRespirometryBiodegradationTestMethodwithRegardtoTestSubstanceConcentrationandInoculum[J].Water,Air&SoilPollution,2006,117(1-4):251-265.[10]CECL-33-A-93-1993,BiodegradabilityofTwo-StrokeCycleOutboardEngineOilsinWater[S].[11]ISO7827-1994,EvaluationinanAqueousMediumoftheUltimateAerobicBiodegradabilityofOrganicCom2pounds.MethodbyAnalysisofDissolvedOrganicCarbon[S].[12]ISO9408-1999,EvaluationofUltimateAerobicBiode2gradabilityofOrganicCompoundsinAqueousMediumbyDeterminationofOxygenDemandinaClosedRespirometer[S].[13]ISO9439-1999,EvaluationofUltimateAerobicBiode2gradabilityofOrganicCompoundsinAqueousMedium.CarbonDioxideEvolutionTest[S].[14]ISO10708.-1997,EvaluationofUltimateAerobicBiode2gradabilityofOrganicCompoundsinAqueousMedium.MethodbyDeterminingtheBiochemicalOxygenDemandinaTwo-PhaseClosedBottleTest[S].[15]ISO14593-1999,EvaluationofUltimateAerobicBiode2gradabilityofOrganicCompoundsinAqueousMedim-MethodbyAnalysisofInorganicCarboninSealedVessels(CO2HeadspaceTest)[S].[16]ASTMD5864-00-2000,StandardTestMethodforDe2terminingAerobicAquaticBiodegradationofLubricantsorTheirComponents[S].[17]ASTMD6139-00-2000,StandardTestMethodforDe2terminingtheAerobicAquaticBiodegradationofLubricantsorTheirComponentsUsingtheGledhillShakeFlask[S].[18]ASTMD6731-01-2001,StandardTestMethodforDe2terminingtheAerobic,AquaticBiodegradabilityofLubri2cantsorLubricantComponentsinaClosedRespirometer[S].[19]ASTMD6006-97a-2003,StandardGuideforAssessingBiodegradabilityofHydraulicFluids[S].[20]Rebeccal,Goyan.BiodegradableLubricants[J].lubEng,1998,54(7):10-17.[21]AndreasWilling.OleochemicalEsters-EnvironmentallyCompatibleRawMaterialsforOilsandLubricantsfromRe2newableResources[J].Fett/Lipid,1999,101(6):192-198.[22]BattersbyNS,CiccognaniD,EvansMR,etal.AnIn2herentBiodegradabilityTestforOilProducts:DescriptionandResultsofanInternationalRingTest[J].Chemo2sphere,1999,38(14):3219-3235.[23]BattersbyNS,PackSE,WatkinsonRJ.ACorrelationBetweentheBiodegradabilityofOilProductsintheCECL-33-T-82andModifiedStu