BYK_润湿分散剂

BYK润湿分散剂毕克化学技术咨询（上海）有限公司Contents内容•BasicsofPigmentStabilization颜料稳定基础知识•StabilizationMechanisms稳定机理•InteractionW/DAdditiveswithPigments润湿分散剂与颜料的相互作用•FormulationGuidelines(AdditiveDosage,EvaluationMethods)配方指导（助剂添加量、评价方法）•WettingandDispersingAdditivesbasedon润湿分散剂基于EstablishedTechnologies成熟技术CPT可控聚合技术•AdditiveRecommendation–Quickreference助剂推荐-快速参考Drypigment干颜料Dispersion分散Primaryparticles原始颗粒(idealdispersion)理想的分散状态Agglomerates聚集体Pigmentinresinsolution颜料在树脂溶液中DeflocculationofAgglomerates聚集体的解絮凝ParticleSizeVersusSurfaceArea粒径与比表面积对比Pigment颜料Particlesize颗粒大小(µm)Surfacearea比表面积(m2/g)Ironoxidered氧化铁红0.25012Carbonblack1炭黑10.09520Phthaloblue酞菁蓝0.07064Carbonblack2炭黑20.013460WettingandDispersingProcess润湿分散过程2Dispersing分散1Wetting润湿3Stabilization稳定StepsofStabilization稳定步骤Reduced:降低-settling沉降-sagging流挂-flood&float浮色发花-strongflood&float严重浮色发花-highviscosities高粘度Reduced:降低-colorstrength色强-gloss光泽-lessflood&float更少浮色发花-highergloss更高光泽-lowviscosity低粘度-highestcolour最高的色强strengthControlledFlocculation受控絮凝Flocculation絮凝Deflocculation解絮凝Improved提高Improved提高Deflocculation解絮凝Deflocculation/ControlledFlocculation解絮凝/受控絮凝Gloss,hazeHidingpower光泽、雾影、遮盖率Improved提高Slightlyreduced轻微降低Anti-settling,sagcontrol抗沉降、流挂控制Reduced变差Improved提高Contr.Flocculation受控絮凝Flooding&floatingcontrol浮色发花控制TOPCOATS,面漆highgloss高光PRIMERS,highbuildlow–mediumglosscoatings底漆，厚涂层低-中光泽涂料Idealfor:最好用于：WettingandDispersingAdditives–Effects润湿分散剂-效果Deflocculation解絮凝型Appearance外观ControlledFlocculation可控絮凝型Protection保护TypesofStabilization稳定的类型Electrostaticstabilization静电稳定Stericstabilization位阻稳定(osmotic/entropicrepulsion)渗透/熵排斥•electrostaticstabilizationmainlyinwater-bornesystems(e.g.,emulsions)静电稳定主要在水性体系里（例如乳液）•stericstabilizationinsolvent-andwater-bornesystems位阻稳定在溶剂以及水性体系•combinationofbothmechanismsinwater-bornesystems水性体系中两种机理结合WettingandDispersing润湿与分散Toselecttherightadditive,youneedtoknow:要选择合适的助剂，你需要知道：Polarityofthesystem(low,medium,high…)系统的极性（低中高）Typeofthecoating(primer,topcoat,basecoat…)涂料的类型（底漆、面漆、底色漆）Pigmentation:pigmenttype(organic/inorganic),surfaceareaandsurfacechemistry(acidic/basic)颜料：颜料类型（有机/无机），比表面及表面化学（酸性/碱性）Co-GrindorsingleGrind共研磨或是单独研磨Grindingmethod(w/oresin)研磨方式（有无树脂）Fattyacidchemistry脂肪酸化学Polyesters,polyamineamides,聚酯，多胺酰胺Polyaddition,Polycondensation加聚、缩聚WettingandDispersingAdditives:EstablishedTechnologies1stGenerationWettingandDispersingAdditives润湿分散剂：成熟的技术第一代润湿分散剂Deflocculating解絮凝ControlledFlocculating控制絮凝1stGenerationWettingandDispersingAdditivesFattyAcidChemistrybasedW/DAdditives第一代润湿分散剂脂肪酸化学类的润湿分散剂lowerPolarity极性higherlowerMolecularWeighthigher分子量BYKUMEN®BYK®-P104SBYK®-220SANTI-TERRA®203ANTI-TERRA®204DISPERBYK®-108ANTI-TERRA®-UDISPERBYK®-101DISPERBYK®DISPERBYK®-130Deflocculating解絮凝Controlledflocculating控制絮凝DISPERBYK®-192WettingandDispersingAdditives:EstablishedTechnologies1stGenerationWettingandDispersingAdditivesPhosphoricAcidEsters磷酸酯polyester/polyetherpolymers,polyetherpolymerse.g.Disperbyk®-110,111,180,聚酯/聚醚聚合物，聚醚聚合物onepigment/filleraffinicgrouppermolecule每个分子有一个颜填料亲和基团POLYESTER聚酯POLYETHER聚醚-O-PO(OH)21stGenerationWettingandDispersingAdditivesPhosphoricAcidEsterbasedW/DAdditivesDISPERBYK-111DISPERBYK-180DISPERBYK-110lowerMolecularWeighthigherlowerPolarityhigherDeflocculatingDISPERBYK-103DISPERBYK-106DISPERBYK-102WettingandDispersingAdditives:EstablishedTechnologies1stGenerationWettingandDispersingAdditives•Stabilizationoforganicpigmentsisoftennotoptimum对有机颜料的稳定通常不是最佳的•Stabilizationoffoampossible(surfactant-likestructure!)可能会稳泡（与表面活性剂类似的结构）Remarks:评述Predominantlydevelopedforinorganicpigmentsandfillers大多用于无机颜填料WettingandDispersingAdditives:EstablishedTechnologies2ndGenerationWettingandDispersingAdditives第二代润湿分散剂HighMolecularweightAdditives高分子量助剂Manypigmentaffinicgroups很多颜料亲和基团2ndGenerationWettingandDispersingAdditivesBasedonPolyurethaneChemistry基于聚氨酯化学polyesterurethanes,polyether/polyesterurethanes,聚酯PU、聚醚/聚酯PUdifferentfunctionalities:acidic,basic,不同的官能团：酸性、碱性DISPERBYK®-160~169,DISPERBYK®-182,183,184,185,DISPERBYK®-170,171,174DISPERBYK®-2163,2164Disperbyk®-2150BYK®-9077Durableadsorptionlayer持久的吸附层manypigmentaffinicgroupspermolecule每个分子上有很多颜料亲和基团2ndGenerationWettingandDispersingAdditivesBasedonPolyurethaneChemistry基于聚氨酯化学lowerMolecularWeighthigherlowerPolarityhigherDeflocculatingDISPERBYK-161DISPERBYK-162/-168DISPERBYK-163/-167/2163DISPERBYK-174DISPERBYK-164/2164DISPERBYK-166DISPERBYK-170DISPERBYK-2150DISPERBYK-182DISPERBYK-183/185DISPERBYK-184BYK-9077DISPERBYK-2155DISPERBYK-169DISPERBYK-171DISPERBYK-115DISPERBYK-160NextGenerationPolyurethaneChemistry下一代聚氨酯化学DISPERBYK-2155Linearstructure线性结构M=20.000g/mol分子量η=∞粘度(solids=100%)Globularstructure球形结构M=20.000g/molη=13.000mPa·s(solids=100%)ConventionalPUchemistry传统PU化学NextGen.PUchemistry下一代PU化学PerformanceDISPERBYK-2155性能100%solids/activeSubstance100%固含/活性成分Widecompatibilityincluding2KPU,TPA,bakingsystems,NC,AC相容性宽，包括2KPU，TPA，烤漆，硝基漆，酸催化体系highlyefficientinUVsystemsUV系统中高效Themillbaseviscosityreductionissimilar/betterthanDISPERBYK161对研磨料的粘度降低能力与D-161相似甚至更好Defocculationandfloodingandf