煤中有害物质及其对环境的影响研究进展

176200212ADVANCEINEARTHSCIENCESVol.17No.6Dec.,2002:100128166(2002)0620840208X,,(,100083)::;;;;:P618111:A0,,2050,[1],(PAHs),,,,,()SClFCrBeAsSbSePbHg,PAHs[2,3],PAHs,,[4,5]PAHsPAHsPAHsPAHs,,,,,10m,10m,PAHs2.5m,,[5],,PAHs,,,[6,7]1,X:2002203221;:2002207210.3:PAHs(:Qh979817);PAHs(:20002367).:(19652),,,,.E2mail:[e-mail]1985,,,[8,9],,[10],()1.1(1),[11](2),,4,()()()(),Prosser[12]3:,1cm,34S10.3;,,34S9.3;,34S10.434S,(3)[13],,;;,CoAsSe,,(4),[20,22],,,1.2(1)PostovskiHar1ampovich[21]MinraYanagiMieka,3%9%,6%13%,28%37%,7%19%WhiteLee6Attar[14],10%30%Chou[15],,[16]GC-MS,(65.5%),(17.5%),(5.58%)(7.4%),,(2),,Tseng,[17],[16]1.3(1),,,,,[18],,34S,1486:,()[19]Postgate,pH6.38.5,,,,32SH2S,34S[20](2)Fe2+SO2-4[20],,:;[15,16],,[21]1.4SO2,2000SO21995.1t,,,SO2SO2,,,SO2,,,pH4,pH3[1]2SrBaBKNa;GeGaVU;CoMoWZn;AsHgPbCdSeSbF,,[22],[23]2.1(),(AsFCl)(PtUTh),Harris[24]2;ParreekBardhan(Bokaro);Mukherjee[25];VanderFlier[26]U2Th;[27]As;GaGeUAs[28][29],,70,80,,198411090,,40,,RusevaElhovo,3::CoGeMoVY;:AsCrCuMnNiPbPScTaThTiUW;:BaGaHfSbSrZnZr[29]ChenMinkin[30]McIntyre[31](SIMS)X24817(XPS)2.2,,2:,;,[32][33]XAsZubovic[34],:GeVBeTiGaNiCrCoYMoCuSnLaZn;[35]Ge;TesslerHgCdCoCuNiPbZn;[36]AsCuPbZnCoNiSrMnCdFe10,,[37],,,[38,39][36]BrClMnCa,,,,,G1uskoter[40],(OAI),OAI:GeBPBeSbTiCoSeGaVNiPbCuHgZrCrMnAsMoCdZn2.34:;;;[41],,,[41]:2.4[27]As,As;;[42];HgHg,BeCoCrCuMnNiPbVZr,,pH,AsZnPbNiSr5,;AsHgCdCrCuPbZnNiCoMnBaCl12,[43]FAsSe3PAHs3.1PAHsPAHs,PAHs()910t,,PAHs,,,PAHs,PAHsPAHs,,PAHs3486:PAHs:45PAHs,PAHs60%70%,PAHs,67PAHs(45)PAHs,PAHs:[44,45,4](),PAHs,1.0%1.2%,[a][a,h]PAHs,,PAHs,[a][a,h],PAHs;;,,PAHs3.2PAHsPAHs,PAHs,,1/3,23,45[k]PAHsPAHs,,PAHs,PAHs,,,PAHs,40%;,10%;[k][e][a]4%PAHs,3.3PAHs[46]38,[a][a,h],,[5][47][48],,PAHs,PAHs,PAHs;,[49];PAHs,;TEFLONPAHs,,PAHs[50];[5]PAHs;PAHs[51];PAHs,PAHs,;Mumford[52]PAHs;[53]PAHs,,PAHs[5456]4,:,;,;,,44817;PAHs,PAHs;(),:,;,,,;,,;(References):[1]YangQi.CoalresourcesofChina[J].BulletinoftheChineseA2cademyofSciences,1998,12(4):1562162.[2]MastralAM,CallenM,MurilloR.PAHatmosphericcontami2nationfromcoalcombustion[J].PolycyclicAromaticCompounds,1996,9(14):37244.[3]OavisCS,FellinP,OtsonR.Areviewofsamplingmethodsforpolyaromatichydrocarbonsinair[J].JournalofAirPollutionControlAssociation,1987,37(12):13297.[4]ZhangLizhu,LiuYongqing,ChenWenlin.Distributionandoc2currenceofPAHsextractedfromcoalinChina[J].JournalofChinaUniversityofMining&Technology,1997,26(3):32235.[,,.[J].,1997,26(3):32235.][5]YaoWeixi,CuiWenheng,XuXiaobai.RelationofgrainsizeofsootfromcoalcumbustionwithdistributionofPAHsandmutation[J].EnvionmentalSciences,1991,12(2):9213.[,,.[J].,1991,12(2):9213.][6]KissG,VargaPuchonyZ,RohrbacherG.Distributionofpoly2cyclicaromatichydrocarbonsonatmosphericaerosolparticlesofdifferentsizes[J].AtmosphericResources,1998,46(34):2532261.[7]KalfDF,CrommentuijiT,VandePlasscheE.Environmentalqualityobjectivesfor10polycyclicaromatichydrocarbons(PAHs)[J].EcotoxicologyandEnvironmentalSafety,1997,36:89297.[8]CohenAD,SpackmanW,DolsenP.Occurrenceanddistributionofsulfurinpeat2formingenvironmentsofsouthernFlorida[J].InternationalJournalofCoalGeology,1984,4:73296.[9]SinningheDamsteJS,LeeuwJW.Analysisstructureandgeo2chemicalsignificanceoforganicallyboundsulfurinthegeosphere:Stateoftheartandfutureresearch[J].OrganicGeochemistry,1990,16(46):107721101.[10]QuerolX,AlastueyA,ChinchonJS,etal.DeterminationofpyriticsulfurandorganicmattercontentsinSpanishsubbitumi2nouscoalsbyX2raypowderdiffraction[J].InternationalJournalofCoalGeology,1993,22:2792293.[11]KortenskiJ.TheoccurrenceandshapeofpyritesinBulgariancoal[J].InternationalJournalofCoalGeology,1996,29(4):2732290.[12]ProsserDJ,DawsJA,FallickAE,etal.Theoccurrenceand34SofauthigenicpyriteinMiddleJurassicBrentGroupsedi2ments[J].JournalofPetrology,1994,17(4):4072428.[13]TangY,RenD.ResearchondifferentpyritesinLatePermiancoalofSichuanprovince,southwesternChina[A].In:ParekVBK,GroppoJG,eds.ProcessingandUtilizationofHigh2Sul2furCoals[C].Netherlands:ElsevierSciencePublishersBV,1993.37245.[14]AttarA.Sulfurgroupsincoalandtheirdetermination[A].In:KarrC,ed.AnalyticalMeyhodsforCoalandCoalProducts[C].NewYork:AcademicPress,1979.5852624.[15]ChouCL.Geologicfactorsaffectingtheabundance,distribu2tion,andspeciationofsulfurincoal[A].In:YangQi,ed.Fos2silFuelGeology2Coal,Proceedingsofthe30thInternationalGe2ologicalCongress,Vol.18,PartB[C].Netherlands:VSP,1997.47258.[16]LeiJ,RenD.ThepetrologicalandgeochemicalcharacteristicsofPermianhighorganosulfurcoalfromGuiding,China[A].In:ParekBK,ProppoJG,eds.ProcessingandUtilizationofHigh2SulfurCoals[C].Netherlands:ElsevierSciencePublishersBV,1993.27235.[17]RenDeyi.Micro2beamanalysisoforganicsulfurincoalmaceralsandtheirdistribution[J].CoalGeology&Exploration,1993,21(1):27229.[.[J].,1993,21(1):27229.][18]SpikerEC,PierceBS,BatesAL,etal.Isotopicevidenceforthesourceofsulfurintheupperfreeportcoalbed(west2centralPennsylvania,USA)[J].ChemicalGeology,1994,114:1152130.[19]PriceFT,ShiehYN.Correlationbetweenthe34Sofpyriteandorganicsulfurincoalandoil2shale[J].ChemicalGeology,1986,58:3332337.[20]LiuDameng,YangQi,TangDazhen.Oc