我国环境化学研究新进展_张爱茜

*[e-mail][e-mail][e-mail][e-mail]。[e-mail]2014-04-23。2010。20102011。。。、。。。45。LatestProgressesinEnvironmentalChemistryinChinaZhangAiqianLiuJinfuJinChuanyongGuoLianghongZhengMinghui*ＲesearchCenterforEco-EnvironmentalScienceChineseAcademyofSciencesBeijing100085AbstractEnvironmentalchemistrywasbornwithitsinterdisciplinarynatureresultingfromthecomplexityofenvironmentalissues．Suchmultidisciplinarycharacteristicsarecontinuouslyintroducingvigorousgrowingpointstothefield．Bothhealtheffectsofchemicalpollutantsandpotentialhazardofemergingcontaminantsandnanomaterialshaveraisedconcernsince2010andthescopeofenvironmentalchemistryhasbeenextendedwithit．Simultaneouslynumberofemergingcontaminantscontinuestoriseaswell．Afterreportingpresenceandpartitioningbehaviorofpolyfluorinatediodinealkanesinenvironmentalmatricesaroundafluorochemicalmanufacturingplantin2010ChinesescientistshavesuccessfullyidentifiedanewpersistentorganicpollutantorpotentialprecursortetrabromobisphenolAdiallyletherasanemergingneuronaltoxicantinenvironmentalsamplesbybioassaydirectedanalysiswhichmarkedthebeginningofanewerainwhichChinesescientistsplaytheleadingroleinthestudyofemergingcontaminants．ActiveinvolvementinpolarscienceandenvironmentalexplorationinTibetleadsextendingourresearchtoglobalscale．Underthehelpoflarge-scalescientificfacilitiessuchasShanghaiSynchrotronＲadiationFacilityithasbecomepossibletocarryoutmechanismstudyonmicro-interfacialenvironmentatmolecularlevel．Besidesbreakthroughshavealsobeenmadeinelucidatingenvironmentalformationbehaviorandfateofnanoparticles．Variousadvancedmethodssuchassurfaceplasmaresonanceandtheoreticalsimulationhavebeenadoptedtoresolvethemolecularinteractionbetweenpollutantsandbiomacromoleculesandthetoxicitymechanismofchemicalmixtures．Suchhasenrichedthecontentofthedisciplineandbuiltasolidfoundationforfurtherdevelopment．Forty-fivereferencesarecited．KeywordsEnvironmentalchemistryEmergingcontaminantsNanomaterialsEnvironmentandhealth·456·2014777http//．hxtb．orgDOI:10.14159/j.cnki.0441-3776.2014.07.005。。2010。。、、。POPsSCI103。20101//POPs20112A。3。。《EnvironmentalScienceandTechnology》2010。。POPs。《EnvironmentalScienceandTechnology》、《EnvironmentalPollution》、《ToxicologyScience》、《ChemicalＲesearchinToxicology》、《Chemosphere》。40。《》420112011921～24。1700《EnvironmentalScienceandTechnology》JerrySchnoor、《EnvironmentalHealthPespectives》HughATilson、《JGＲ》ZhangＲenyi《AtmosphericEnvironment》ChakKChan《AppliedCatalysisB》HiromiYamashita《Langmuir》TetsuroMajima、、。20103。。1。、、。56。。TritonX-114ZnO7。、、、、、。·556·http//．hxtb．org2014777SCCPs。8SCCPs、SCCPs。9SCCPsSCCPs56C1074.4mg/tSCCPs。10SCCPsSCCPsC10C11SCCPsPOPsSCCPs。。2。3。Polanyi。Polanyi-。《Langmuir》、《ChemicalＲeviews》《EnvironmentalScienceandTechnolog》11～13。。。14、XXZnO、。XTLACX-3.34TLACTiO2TLAC15。。、。16C60C6017《ACSNano》。3。3。18α-。CpG19P53CpG-CpG。。20。·656·2014777http//．hxtb．org。。CdSeDNAUDNATmC60-PVPPCＲ2122。23。4。、。Cd2+、Cu2+24～2627。Ti/SnO2-Sb-BiCF228。、。TiO200129。TiO2/、ZnO/、CdS/30～33。3435。36。。。124--237。。124-Mars-VanKrevelen-38。5。。。α-AＲG39439T4TBGT4TBGreactiveloopA-sheetTTＲ-7.31TBG7.192。TTＲTBGTTＲ40。·756·http//．hxtb．org201477741γβ。42、π－π。。43。44MIM。6《》2“973”、“863”、。201014020111642012178201035.0811.69201160.0615.02201278.0219.502.8。POPs2010～2013“”2009～2013973“、”．973geodata．cn/index．jsp2010～2012863“”。2012“”“”、“”、“”、“”“”5、252.5。3。“”2012228。10025000。17.5116.5。45。7。。。。-。。T2D。-·856·2014777http//．hxtb．org、-。。、。。1TＲuanYWWangTWangetal．Environ．Sci．Technol．201044155755～5761．2GBQuJBShiTWangetal．Environ．Sci．Technol．201145115009～5016．3YMLiDWGengFBLiuetal．Atmos．Environ．201251140～145．4．2011.6．5ZQTanJFLiuGBJiang．Nanoscale201246735～6738．6QLiuJShiJSunetal．Angew．Chem．Int．Ed．2011505913～5917．7JBChaoJFLiuSJYuetal．Anal．Chem．20118376875～6882．8LZengTWangPWangetal．Environ．Sci．Technol．201145135529～5535．9YGaoHZhangFSuetal．Environ．Sci．Technol．20124673771～3778．10QLiJLiYWangetal．Environ．Sci．Technol．2012462111948～11954．11KYangDLinBXing．Langmuir20092563571～3576．12KYangBXing．Chem．Ｒev．2010110105989～6008．13KYangWWuQJingetal．Environ．Sci．Technol．20104483021～3027．14JLvSZhangLLuoetal．Environ．Sci．Technol．201246137215～7221．15CJingJCuiYHuangetal．ACSAppl．Mater．Interf．201242714～720．16LLWangYHuangATKanetal．Environ．Sci．Technol．201246105422～5429．17YGYinJFLiuGBJiang．ACSNano2012697910～7919．18YGaoXXLiLHGuo．Environ．Sci．Technol．2013471634～641．19YWeiYLinAQZhangetal．Sci．Total．Environ．2010408246285～6290．20XMZouZFLinZQDengetal．Chemosphere201286130～35．21MYSongGBJiangJFYinetal．Chem．Commun．20104691353～1564．22WLiuSPZhangLXWangetal．PLoSOne201169e24406．23BZhaoMHZhengGBJiang．Environ．HealthPersp．20111193A112～A113．24GZhaoJLiXＲenetal．Environ．Sci．Technol．2011452410454～10462．25ZPeiLLiLSunetal．Carbon201351156～163．26JXuLWangYZhu．Langmuir201228228418～8425．27ZSuiQMengXZhangetal．J．Mater．Chem．2012228767～8771．28QZhuoSDengBYangetal．Environ．Sci．Technol．20114572973～2979．29YZhaoWMaYLietal．Angew．Chem．Int．Ed．2012513188～3192．30JDuXLaiNYangetal．ACSNano201151590～596．31BLiHCao．J．Mater．Chem．2011213346～3349．32XLiuLPanTLvetal