_均三嗪系列膨胀型阻燃剂的合成及应用

1001-9731201512-12001-08*1，2，1，2，1，2，1，2，1，2，1，21．0300242．030024、、、，。，，，，。TQ314．24ADOI10．3969/j．issn．1001-9731．2015．12．0011IFRPP、PUABS、、、、1-3。3PER、APPMEL。。、、4-5。C、N、P36-7。1888、、。68-10。。2JustusLiebig1834、。“”。、、11-12。2．1MPPMPPER1。YuanLiu13MPPERMPPPP。3%90．5%。MPP1%3%MPPPPLOI30．5%32．5%MPP。YinghongChen14MP、PERPPPPMPP/PPMPP/PPPP25%PER∶MP1∶1．6PPMPP25%3．2mm1．6mmUL-94V-020%3．2mmV-0。25%MPP70℃168hV-0。10021*[e-mail]1988－。1MPPER13Fig1ThechemicalreactionmechanismofMPwithPER13ShiqiangSong15POCl3、PER、MEL、TEOA、SPDSSPDM2EPEP。15%SPDSSPDMEPLOI29．4%27．2%EPLOI。PSiSPDSSP-DMLOI1∶110．4%15%LOI30．8%32．1%。2SDPSSPDM15Fig2SynthesisroutesofSDPSandSPDM152．2GongpengLin16AHMP3MPyP-6。3AHMP16Fig3ChemicalstructureofAHMP16AHMP5%MPyP25%1．6mm3．2mmUL-94V-0LOI31．0%700℃40．6%HRRTHR。2．3YuhuaZhong17、4IFRTPEE。15%IFR3∶10∶2TPEELOI17．3%30%UL-94V-00．6%15．7%MPP。2002120151246417Fig4Chemicalstructureofmelaminepolyphosphate172．4YuxuanWang18TGICMEL5APP1∶5PP32%LOI32%UL-94V-0PHRR486kJ/m2PP47．5%714sPP54．9%。5MELTGIC18Fig5ChemicalreactionschemeofMELandTGIC183CYCCYC3—NH2—OH。、。PERAPP19-20。3．1JianLu21CYCNH324--6--135-6。APPPER2∶3∶1ABS30%ABSLOI23．3%。624--6--135-21Fig6Thechemicalstructureof24-diamino-6-hydroxylethylamine-135-triazine21。LijunQian22Trif-DOPO。TrifTrifDOPOTrif-DOPOTrif-DOPO7。Trif-DOPOEPLOI22．5%UL-94。Trif-DOPO1．2%LOI36%UL-94V-0Trif-DOPOEP。XinWang23POCl3PERPEPAPEPACYCPEPATA8。APPEPPEPATAEPAPP20%PEPATALOI33．0%UL-94V-05%PEPATA5%APPLOI34．0%UL-94V-0。300217Trif-DOPO22Fig7ThesynthesisofTrif-DOPO228PEPATA23Fig8ThechemicalstructureofPEPATA233．2、、。IFR。XiaopingHu24CYC、、CACA9。9CA24Fig9ThechemicalstructureofCA24CAAPPLDPE8%CA22%APPLDPELOI31．2%UL-94V-0CA。。、、。GangLiu25CYC、-10700℃45%。ZhaozanXu26CYC、、PTPA11APPIFR。PP/IFR。IFR18%APP∶PTPA2∶1PP/IFRUL-94V-0LOI32．1%。IFR25%IFRPPLOI34．0%UL-94V-0。HRR、PHRR、THR、SPRTSPHRRSPR85%79%。PP/APP25%、PP/PTPA25%PP/IFR25%3PP/IFR25%、、。PTPAAPP。XinqingSu27CYC、、PTCA12APPPP。PP20%IFRPTCA6．67%APP13．33%LOI17%31．5%UL-94V-0PHRR90%THR54%TSP51%。PTCAAPPPPPTCA/APP。400212015124610-25Fig10Diagramforsynthesisofpolymercontainedphosphorousandnitrogen2511PTPA26Fig11ThesynthesisrouteofPTPA2612PTCA27Fig12SynthesisrouteofPTCA27YunLiu28APP/CAnAPP∶nCA=2∶1CA13PP。0．5%LOI29．8%31．8%UL-94V-0。7．21%、9．23%、2．56%、6．81%50021。13CA28Fig13ThechemicalstructureofCA283．320、、。。A2B329-30。YujuanJin31CYC14。APPIFRPP。N2600℃44．8%。IFRPPLOI17．5%27%625s85．7%。1431Fig14Thechemicalstructureofhyperbranchedaromaticaminetriazinepolymer31MahapatraSibdasSingha32CYC、44'-14--HBPA15。HBPA290℃。HBPA1∶1IFRPVCLDPE。HBPA2．5PVCLDPELOI38．75%26．0%PVCLDPELOI5%8．5%IFRP/N。ChenhaoKe33CYC44'-HCFA16。HCFAAPPPLA30%HCFAAPP2∶3PLALOI36．5%UL-94V-0。HCFAAPP30%700℃19．6%PLA0。JuanLi3444'-HPCAAPPABS。600212015124615HBPA32Fig15DiagramforthemolecularstructureofHBPA3216HCFA33Fig16Synthesisofhyperbranchedpolyaminecharringa-gent334、。、。、、、。1LuShuiyuHamertonIan．Recentdevelopmentsinthechemistryofhalogen-freeflameretardantpolymersJ．Pro-gressinPolymerScience20022781661-1712．2JimenezMaudeDuquesneSophieBourbigotSerge．Intu-mescentfireprotectivecoatingtowardabetterunderstand-ingoftheirmechanismofactionJ．ThermochimicaActa20064491-216-26．3FouadLaoutidLeilaBonnaudMichalAlexandreetal．Newprospectsinflameretardantpolymermaterialsfrom70021fundamentalstonanocompositesJ．MaterialsScienceandEngineeringRReports2009633100-125．4BourbigotSergeDuquesneSophie．FireretardantpolymersrecentdevelopmentsandopportunitiesJ．JournalofMate-rialsChemistry200717222283-2300．5MngomezuluMfisoEJohnMayaJJacobsValenciaetal．ReviewonflammabilityofbiofibresandbiocompositesJ．CarbohydratePolymers201411113149-182．6ChenLiWangYuzhong．Areviewonflameretardanttech-nologyinChina．PartⅠdevelopmentofflameretardantsJ．PolymersforAdvancedTechnologies20102111-26．7YinZhaoluLiFengZhangZejiang．Structureandproper-tiesofhalogen-freeflameretardantwater-blownpolyure-thanerigidfoamJ．JournalofFunctionalMaterials201344z2285-288．8YuGuipengLiuChengWangJinyanetal．Synthesisofphenyl-s-triazine-basedcopolyarylethersderivedfromhydroquinoneandresorcinolJ．PolymerDegradationandStability200994112065-2071．9YangKunXuMiaojunLiBin．SynthesisofN-ethyltria-zine-piperazinecopolymerandflameretardancyandwaterresistanceofintumescentflameretardantpolypropyleneJ．PolymerDegradationandStability20139871397-1406．10LiangHongboShiWenfangGongMing．Expansionbe-haviourandthermaldegradationoftriacryloyloxyethylphosphate/methacrylatedphenolicmelamineintumescentflameretardantsystemJ．PolymerDegradationandSta-bility20059011-8．11MoXianzhongLiaoZhengfuGanChunfang．Preparationandapplicationinintumescentcoatingsofmelaminephos-phatesJ．JournalofFunctionalMaterials200435z11725-1727．12BaoDongmeiLiuJiping．Researchonsynthesisandther-malpropertiesofhexakis4-formacylphenoxycyclot-riphosphazeneJ．JournalofFunctionalMaterials2013443396-400．13LiuYuanWangQi．Catalyticactionofphospho-tungsticacidinthesynthesisofmelaminesaltsofpentaerythritolphosphateandtheirsynergisticeffectsinflameretardedpolypropyleneJ．PolymerDegradationandStability200691102513-2519．14ChenSingsongLiuYuanWangQietal．Performanceofintumescentflamereta