原子吸收光谱法在药物分析中的应用和发展

:20010308:(1965),,,.(,714000):,FIA.:;;;:O65713:A:10095128(2002)02003602ApplicationandDevelopmentofAtomicAbsorptionSpectroscopyinPharmaceuticalAnalysisJIAOGeng2sheng(DepartmentofChemistry,WeinanTeachersCollege,714000Weinan,China)Abstract:PharmaceuticalanalysisbyatomicabsorptionspectroscopyhasdevelopedinrecentyearsanditsdevelopingcourseisthecombinationofindirectatomicabsorptionandFIA2AAS.KeyWords:atomicabsorptionspectroscopy;pharmaceuticalanalysis;applicationanddevelopment;chemicalreaction1955,.,,.,.,(AAS).1,AAS.:VB12,240.7nmVB12[1];242.8nm[2];30[3],AAS.2,AAS,AAS.,,,AAS.Christian[4],,.ClarkE.R.,MillerAAS[5],,AAS.,AAS,.(1)AAS1AAS,.CuCoZnNiAgCrPb.:Cu2+Ag+[6];Cu2+--,,;20023172JournalofWeinanTeachersCollegeMar.2002Vol.17No12©1995-2004TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.Ag+[7];Cu2+21[8];11.,.:,MIBK[9]..,,(),,AASAAS16.,.AAS.(2).,AAS.:,MIBK1,2-,Zn2+;Co(SCN)2-4,,[10];Cu2+Co2+Cd2+,MIBK,[11-12];Fe(SCN)3-6Co(SCN)224Ni(SCN)2-4BiI-4,MIBK;,;Cu2+,[13].,AAS,.(3)AAS.,,,.,,VB2AgNO3,Ag+VB2[14];Ag(I),,AAS[15];Cu2+Benedict,Cu2O,[16],,HNO3AAS[17];Cu2+Cu+,SCN-CuSCN,[18].(4)AAS.,,AAS,.:,KMnO42--4--6-,Ni2+,AAS;L-Cu2+,,..AAS,AAS.,,..:,,.Ca2+,.,.,AAS.,:AAS,,,.,AAS,.FIAAAS,AAS.:[1]DiazF..J.Anal.Chim.[J].Acta.1972,58(2):455458.[2][Z].C-645.[3].[M].:.19921890.[4]ChristianG.D.,FeldmanF.J..Anal.Chim.[J].Acta.1968,40(2):173179.[5]RousseletF.andThullenF..Prog.Atom.[J].Spectrosc.1979,1:353355.[6]HassenandEldesouki.J.Assoc.offAnat.[J].Chem.1981,5:1158.(44)7320022:©1995-2004TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.2(X,,1)FI,:(1)x((xy)y)=1;(2)1x=x.4X1X2FI,h:X1X2,x,yX1,h(xy)=h(x)h(y).hFI.5XFI,X1X,X1,X1X.3X1,X2FI,h:X1X2,h(X1)X2FI.x,yh(X1),a,bX1,x=h(a),y=h(b),xy=h(a)h(b)=h(ab)h(X1),h(X1)X2FI.6XFI,TX,TXFIXFI,TFI,C(T).4XFI,TX,C(T):(1)TC(T);(2)x,yC(T),xyC(T);(3)C(T).TFI;,T.:[1].Fuzzy[J].,1990,4(1):5664.[2],.FuzzyMV[J].,1998,12(1):2025.[3]K.Iseki.BCIalgebras.[J]1MathSeminarnotes,1976,(4):7786.[4].[M].:,2000.[5].[J].,1993,(1):2027.[](37)[7],,,.[J].,1994,24(3):215218.[8],,,.[J].,1997,31(4):8792.[9]AndrealM.O..Anal.Chim.[J].Acta.1984,156:147157.[10].[J].(),1992,28(6):366367.[11],.[J].,1988,16(3):248250.[12].[J].(),1983,19(3):1820.[13],,,.[J].,2000,19(5):911.[14],,,.(Ê)B2[J]..1997,27(4):316319.[15],,,.[J].,1996,12(1):5254.[16],,.[J].,1983,11(9):717.[17],.[J].,1982,40(11):10661068.[18],,.[J].,1988,16(9):809811.[]44:Fuzzy17©1995-2004TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.