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当前位置:首页 > 商业/管理/HR > 质量控制/管理 > 钠离子电池碳基负极材料研究进展-胡明祥2017
31120172JOURNALOFQILUUNIVERSITYOFTECHNOLOGYVol.31No.1Feb.20172016-08-122017-01-01973-2015CB9325002014CB9324011993—.*1980—lvruitao@tsinghua.edu.cn.1004-4280201701-0001-08DOI10.16442/j.cnki.qlgydxxb.2017.01.001,*100084。。、、。TQ035ARecentProgressonCarbon-basedAnodeMaterialsforSodium-ionBatteryHUMing-xiangLVRui-tao*KeyLaboratoryofAdvancedMaterialsMOESchoolofMaterialsScienceandEngineeringTsinghuaUniversityBeijing100084ChinaAbstractAsanimportanttypeofthenext-generationenergystoragedevicessodium-ionbatteriesSIBsareattractingincreasingresearchattentions.ComparedwiththecathodematerialsofSIBsdevelopinghigh-performanceanodematerialsisbecomingabottleneckissuewhichwilllimitthepracticalapplicationsofSIBs.ThisarticlesummarizestheresearchprogressesondifferentanodematerialsforSIBsincludingalloysmetaloxidesmetalsulfidesandcarbon-basedmaterials.Inparticulartheapplicationsofcarbon-basedstructureswithdifferentdimensionalitiesasanodematerialsforSIBsarediscussedindetail.Basedoncurrentachievementstheperspectivesandfutureresearchalongthislineareproposed.Keywordssodium-ionbatteryanodematerialscarbon-basedmaterialshierarchicalstructures、。、、1。30、、、。EV。SIBs6012LIBs。。311.060.760.3VSIBs。1/2034。15、678。NaxCoO2NaxMnO219-10。11-14、15、16-17。11811988Mireille1930mAh·g-1NaC64。0.42nm18。。20“—”NaC6LiC6+0.03eV/atom>0-0.01eV/atom<0。>0。DFT<020。、、。2000。StevensDahn9300mAh·g-1。1.1/。。。SIBs“”houseofcardsstructure21。。SIBs。。sp、sp2、sp321-24。。18。、、。25。、。14。26-28。1229。。Hou30、21。0.42nm。2.5A·g-1200150mAh·g-1。7。。Wang31、44-。5A·g-17000200mAh·g-1。15A·g-1175mAh·g-1。。。Wang14CTAB50~70nm2。600℃50mA·g-1180mAh·g-1150。Na+14。aPPybc50mA·g-1d2141.2/。HummersGOSIBs。Wang27KOH。50mA·g-1349.7mAh·g-1260155.2mAh·g-120A·g-150mAh·g-127。。331。Wang28rGO、rGO。0.61nm150mAh·g-11h300mAh·g-15h100mAh·g-1。Na+5h0.37nm1h0.42nm“”。。、“—”、。。。。。200nm~5μm。。Tang12。、、13nm。100mAg-1100200mAh·g-1。Wenzel290.2C130mAh·g-1。。1。。。。10.10A·g-1100380mAh·g-1。1mAh·g-1mAh·g-1320.05Ag-1100243mAh·g-10.20Ag-1210mAh·g-10.50Ag-1175mAh·g-15.00Ag-1100mAh·g-1310.10Ag-1100380mAh·g-10.50Ag-1320mAh·g-11.00Ag-1280mAh·g-115.00Ag-1150mAh·g-1330.10Ag-1100298mAh·g-10.20Ag-1290mAh·g-11.00Ag-1155mAh·g-15.00Ag-170mAh·g-1280.10Ag-1300127mAh·g-10.20Ag-1145mAh·g-11.00Ag-1128mAh·g-1340.10Ag-1100160mAh·g-10.20Ag-1168mAh·g-11.00Ag-1120mAh·g-15.00Ag-175mAh·g-11.3。41。Yan21“”。。。50mA·g-1450mAh·g-1。。。Xu35。3。1C0.02~3.00V852.6mAh·g-1150594mAh·g-1。、。abcd3352IVV。Sb36Na3Sb660mAh·g-1、Sn37Na15Sn4847mAh·g-1、Ge38NaGe369mAh·g-1、PNa3P2596mAh·g-139。Pblackphosphorene。Cui390~1.5V0.05A·g-12440mAh·g-110083%。Xx4aNa3P531yz。4b10C500mAh·g-1。aNa+b-4-3938。。。>600mAh·g-1Fe2O31007mAh·g-140CuO674mAh·g-141MoO31117mAh·g-142NiCo2O4890mAh·g-143。。Yuan41CuOCuOH2。200mA·g-1400mAh·g-120020%。CuO。。。3。。、。1。。61。。2。。。B、N、P、S。。3。。。。。。1MARCAMetal.ElectrochemicalinsertionofsodiumintocarbonJ.JournalofElectrochemistrySociety199314012169-170.2ASHERRCBERKSD.ALamellarcompoundofsodiumandgraphiteJ.JournalofInorganicChemistry1959103-4238-249.3DELMASCBRACONNIERJJFOUASSIERCetal.ElectrochemicalintercalationofsodiuminNaxCoO2bronzesJ.SolidStateIonics19813165-169.4DIPANKTVICTORTLINDAF.N.TheemergingchemistryofsodiumionbatteriesforelectrochemicalenergystorageJ.AngewandteChemieInternationalEdition2014543431-3448.5DELMASCBRACONNIERJJHAGENMULLERP.AnewvarietyofLiCoO2withanunusualoxygenpackingobtainedbyexchangereactionJ.MaterialsResearchBulletin1982171117-123.6OHSMMYUNGSTHWANGJYetal.HighcapacityO3-typeNaLi0.05Ni0.25Fe0.25Mn0.50.95O2cathodeforsodiumionbatteriesJ.ChemistryofMaterials201426216165-6171.7ANANTHARAMULUNKOTESWARARKRAMBABUGetal.Awide-rangingreviewonNasicontypematerialsJ.JournalofMaterialsScience20114692821-2837.8GONGZYANGY.Recentadvancesintheresearchofpolyanion-typecathodematerialsforLi-ionbatteriesJ.Energy&EnvironmentalScience2011493223-3242.9STEVENSDADAHNJR.Highcapacityanodematerialsforrechargeablesodium-ionbatteriesJ.JournalofTheElectrochemicalSociety200014741271-1273.10KIMHKIMDJSEODHetal.AbinitiostudyofthesodiumintercalationandintermediatephasesinNa0.44MnO2forsodium-ionbatteryJ.ChemistryofMaterials20122461205-1211.11XUCLIBDUHetal.EnergeticzincionchemistrytherechargeablezincionbatteryJ.AngewandteChemieInternationalEdition2012514933-935.12TANGKFULWHITERJetal.Hollowcarbonnanosphereswithsuperiorratecapabilityforsodium-basedbatteriesJ.AdvancedEnergyMaterials201227873-877.13ZHOUJSHENGZHANHetal.FacilesynthesisoffluorescentcarbondotsusingwatermelonpeelasacarbonsourceJ.MaterialsLetters2012661222-224.14WANGZHQIELYUANLXetal.FunctionalizedN-dopedinterconnectedcarbonnanofibersasananodematerialforsodium-ionstoragewithexcellentperformanceJ.Carbon201355328-334.15ZHUYHANXLIUYetal.ElectrospunSb/Cfibersforastableandfastsodium-ionbatteryanodeJ.ACSNano2013776378-6386.16LAMUELDBGURPREETS.MoS2/Graphenecompositepaperforsodium-ionbatteryelectrodesJ.ACSNano2014821759-1770.17QUBMACJIGetal.LayeredSnS2-reducedgrapheneoxidecomposite-ahigh-capacityhigh-rateandlong-cyclelifesodium-ionbatteryanodematerialJ.AdvancedMaterials201426233854-3859.18PANHUILINYONG-SHENGHULIQUANCHEN.Room-temperaturestationarysodium-ionbatteriesforlarge-scaleele
本文标题:钠离子电池碳基负极材料研究进展-胡明祥2017
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