1-氨基蒽醌合成工艺述评

19951(310012),,:,1,11(1NHZAQ)C:HoOZN,,,,,1NHZAQ22:::=3:2:5[],,,,,2.2,1,4,,,,[]:151,4,l,3,NaHS,2.3[]0NO:0Nrl:}{/\}NH}{lZ\/\/\/\/\/}}3se)}1!}I+NHNO:\/\/\/}{22.1,,1NHZAQ,,2NH:AQOO,1NHZAQ,99%,63.5%:1NOZAQ75%HNO:2635.88MPa(2.85L/h)(2L/h),,3999X103Pa,29499%(DE4,215,193)11NHZAQ,NaZS,,45.6%24[,,7NaZSOˆ\/Z!0NO{}l/\/\/\111.}+Na:S+H:owe)/\/\ZON|00/\/\/\\/{,+NaHs+H,o~~)24/\/\/++NaZSZO3O10~20%NaZS95~1001,,,,,,,,,1NHAQ60~70%HZSO4,96%,1NHZAQ,,,,,2-NHZAQ1,51,61,71,8,96.2~982%[]2s[0,01-NHZAQ1NHZAQO,,pH2.0~12.0,HF,,,1NHZAQ2.6PdPtRuCoCu,,,,Pd/C,Pd/C::1N02AQ491N02AQ(6%1,5,3%1,8)4009,100.495%Pd/Csh320995%H:50,65%HZSO,199525.69,759l%5%[z:1NOZAQ41109lNOZAQ5%Pd/C90~100,0.196~o.sssMPa4h,ZgNa0H50~60lh,8910%98%:1NO:AQ2591NO:AQ(99%,10010%),7597.59In113h,99%301NO:AQ,l000C0.196~o.58sMPa4h2.229%,,7050%[,:lN02AQ(92%)5,50%100Na0HI665%Pd/C.293000221mol,0.3391NHZAQlh(30),4.891NHZAQ,98%[]PdA12O:rPdPhCH(OH)MeDMF,Pd/C1RuCOiN02AQRu(CO)1:,152.98MPaCO,100%l,9,101NOZAQ,,33.11,,,,,,32,1,,,,,3.3,,,,,,1,.,1991.7832.2(4).1,,23E.P.249,69(1987)(CA.,108.169186)J.P.7521325(CA.,54:695),J.P.75/126717(CA.,83:18116)B.P.1,428,620,D.E.2,576,651(CA.,86:206240),J.P.75/40267(CA.,83:114088).J.P.7601030(CA.,55:178785);J.P.76/32552(CA.,85:4143);B.P.1,409,503(CA.,81:51141);D.E.2,541,663(CA.,55:826),D.E.2,211,411(CA.,78:17637),D.E.4,213,193(CA.,118:149559),D.E.2,349,70851J.P.7615455(CA.,as:414),J.P56/52,165(CA.,85:175955),B.P.i,97,l,t.5.P.4,e5,5,J.P.02/253,40(16)16199533,5,,2.32.72.8,3,5,,2.3,,3,5,ClTaThuCueetal,,ChimTher.2(6)-4223(1967)2,83,188,329CA.,100:131265W3Nobuol:hikawa,NipponKayakuZasohi86(11),12023(1965)CA.,65:135816NobuoIshikawaandl,aoFujii.NIPPonKayakuZasshi57(10),1052(1,66)C.,66:652022513,(4(67)CA.,68:68643W6Kobayash!,Hiroshietal.,Eur.Pat.ApPI.EP60,39(10)7G.C.Flngeretal,,J.Amer.Chem.Soe.,73()1535(1051).Nasu,Rikuoetal.,Eur.Pat.APpl.FP497,213(1992)gOotomo,Kikuoetal.,04,175,35592,178,355CA.,117:233580P[10Sehaeh,Thomasetal.,Eur.Pat.APPI.EP562,435(1993)[11FranzEffenbergeretal.,Chem.Ber12,15716(1931)(:19950109)(12)(CA,118:i242i3w).J.P.si/251306,..(6),,19887J.A.C.5.4.22982300,23032304-(1992)8..(2),11,19919J.P.01/94055(CA.,115:101543e)i,Reddy.G.Sunivasulu,J.IndionChem.Soe,1992,69(11).73740LllU.5.P.5,13C,448(CA.,118*38609y)12J.P.75/93,959(CA.,53,192944u)13J.P.76/c4,156(CA.,55:0948y)[14J.P.7551,931(CA.,54:123419k)15J.P.79/6,263(CA.,91:i412d)[16E.5.530,565(sPan)(CA.,IC4:168103a)17J.P.02/26860(CA.,115:23735n).E.P.26,536(CA,116,216353d),J.P.92/266.833(CA.,118:11531a)(:19950221)50%,20/DOW,85~72/Halon1301FAA12HFC125,(NisT),Halon2301OOWDOWMatsushitaCFC,,,14