酯交换法制备生物柴油的研究

©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(2008)02-0033-04(,467000):,,:;;:Q819:A,,,100a,,3050a[1],,,,,[23],,(FAME),,,[4]()(),,,[5]1,C18[6],[67]:,52.9,,,,-20,,,,,,2,,,,[8],4:[811]2.1:;,80%;;:;;[12]2.2,(21020),1-,,,,,2.3:2008-01-10:(1964-),,,17220083JournalofPingdingshanInstituteofTechnologyVol.17No.2Mar.2008©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(),;,,,:2.4.1[8,1316],,,,,,,,,,,2.4.2,,3040:1,6:1,2.4.3(NaOHKOH),NaOH,:6:1NaOH1%6018h,90%11:;;:,/,,,/,,,,;,,2.4.4[1720],18h24min,,,,2400,40:1,,3[11,21],,,,,,14[2226]1999,10t4,30t/a,5%3420083©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(,)(,)1218h24min0.1MPa30658.09MPa239.455.160%75%,,(NREL),,,(Cyclotellacryptica)60%,40%:,,;,;30[27]5.2,,,,,,:,,,,;,,/,;[1720,27]5.3,,,5.4,,20007.0107t,6.7107t,,,,,[1],,.[J].,2003(1):32-36.[2]Chun,L.H.,Overend,R.P.Biomassandrenewablefuels[J].Fuelbioprocess,2001(17):187-195.[3]TunahanCakir,K.YalcinArga,M.MeteAltintas,etal.FluxanalysisofrecombinantSaccharomycescerevisiaeYPB-Gutilizingstarchforoptimalethanolproduction[J].ProcessBiochemistry,2004(39):2097-2108.[4]Krawcyk,T.Biodiesel-Alternativefuelmakesinroadsbuthurdlesremain[J].Inform,1996(7):801-829.172:35©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[5]Shay,E.G.Dieselfyelfromvegetableoils:statusandopportunities[J].BiomassandBioenergy,1993(4):227-242.[6].[J].,2001(26):73-74.[7],,.[J].,2002(18):32-38.[8]FangruiMaMifordA.Hanna.Biodieselproduction:areview[J].BioresourceTechnology,1999(70):1-15.[9],,.21[J].,2002(21):299-302.[10],.[J].,2002(18):23-27.[11],,.[J].,2003(12):30-33.[12]Pryde,E.H.Vegetableoilsasdieselfuel:Overview[J].JAOCS,1983(60):1557-1558.[13]KaiedaM.,SamukawaT.,MatsumotoT.,etal.BiodieselfuelproductionfromplantoilcatalyzedbyRhizopusoryzaelipaseinawa2ter-containingsystermwithoutanorganicsolvent[J].Bioscience,1998(8):627-623.[14]H.Noureddini,X.Gao,R.S.philkana.ImmobilizedPseudomonascepacialipaseforbiodieselfuelproductionformsoybeanoil[J].BioresourceTechnology,2005(96):769-777.[15]P.Ellaiah,T.Prabhakar,B.Ramakrishna,etal.ProductionoflipasebyimmobilizedcellsofAspergillusniger[J].ProcessBiochem2istry,2004(39):525-528.[16]KazuhiroBan,MasaruKaieda,TakeshiMatsumoto,etal.WholecellbiocatalystforbiodieselfuelproductionutilizingRhizopuoryzaecellsimmobilizedwithbiomasssupportparticles[J].BiochemicalEngineeringJournal,2001(8):39-43.[17]AyhanDemirbas.Biodieselfuelsfromvegetableoilsviacatalyticandnon-catalyticsuperiticalalcoholtranseseterificatiosandothermethods:asurvey[J].EnergyConversionandManagement,2004(44):2093-2109.[18]GiridharMadras,ChandanaKolluru,RajnishKumar.Sythesisofbiodieselinsupercriticalfluids[J].Fuel,2004(83):2029-2033.[19]WeiliangCao,HengwenHan,JingchangZhang.Preparationofbiodieseformsoybeanoilusingsupercriticalmethanolandco-sol2vent[J].Fuel,2005(84):347-351.[20],,.[J].,2003(23):15-18.[21]YZhang,M.A.Dube,D.D.Mclean,etal.biodieselproductionfromwastecookingoil:1.Processdesignandtechnologicalassess2ment[J].BioresourceTechnology,2003(89):1-16.[22],,.[J].,2002(22):4-6.[23]W.Korbitz.BiodieselproductioninEuropeandNorthAmerica,anencouragingprospect[J].RenewableEnergy,1999(16):1078-1083.[24]PeterClery.LiquidbiofuelsintheUK[J].Refocus,2002(5):16-18.[25],.[J].,2005(5):16-18.[26],,.[J].,2004(5):22-25.[27],.[J].(),2003(19):1-6.ResearchandproductionofbiodieselZHOUAi2ping(PingdingshanEducationCollege,Pingdingshan467000,China)Abstract:Thispaperdiscussedthemainproperties,productionmethodsandapplicationhomeandbroadforbiodiesel,introducedwaysofblending,micro-emulsion,thermalcracking(pyrolysis)andtranseterificationaswellassomeproblemsforbiodeselproductionareaddressed.Keywords:biodiesel;productionmethods;researchprocess3620083