锂离子电池阻燃添加剂研究

:(1968-),,,,,:;(1979-),,,,:;(1980-),,,,:;(1932-),,,,,::(04120001100),(040302500)1,1,1,2(11,453007;21,410082):,3,,:;;;:TM91219:A:1001-1579(2004)03-0189-03Researchonflame2retardantadditivesforLi2ionbatteriesZHENGHong2he1,QINJian2hua1,SHILei1,XUZhong2yu2(11CollegeofChemistry&EnvironmentalSciences,HenanNormalUniversity,Xinxiang,Henan453007,China;21InstituteofNewCarbonMaterialResearch,HunanUniversity,Changsha,Hunan410082,China)Abstract:Thecurrentstatusofflame2retardantadditivesusedinelectrolytesofLi2ionbatterieswerereviewed1Themechanismmaintainingnon2flammabilityoforganicsolventwasdiscussed1Theflame2retardantadditiveswereassortedintoorganophosphoruscompounds,halogenatedcompoundsandcompositecompounds1Structuralcharacteristics,flame2retardationefficiencyandimpactsonelectrolytepropertiesofdifferentflame2retardantadditiveswerecompared1Theprospectofflame2retardantadditivesinLi2ionbatteriesinthenearfuturewaspredicted1Keywords:Li2ionbattery;electrolyte;flame2retardant;additives,,[1-2],,1,[3],,,,:,,,,X1M1Wang[3](TMP),,,,,,,,34320046BATTERYBIMONTHLYVol.34,No13Jun1,2004©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[3],HF,:,;,;,,,;,,,F,,22,2211,,,(TMP)(TEP)[3-4](TPP)(TBP)[5],(HMPN)[4],-(2,2,2-)(TFP)-(2,2,2-)-(BMP)(2,2,2-)-(TDP)[6-7],K1Xu[6],,TMPPC,,EC,SEI,TMP,,EC+PC+TMP(10%)EC+DEC+TMP(25%),HMPN,,[4]H1Ota[8]1mol/LLiPF6/EC+DEC+TMP(622)5%(EEP),TMP,SEI,Y1E1Hyung[5]1mol/LLiPF6/EC+DEC(11)5%TPP,160210,K1Xu[6-7]TFPBMPTDP,,,,TFP212,2,CH2F2ECCHF22ECCF32EC,,,,,F,,(SEI),,J1Arai[9]CF32EC+Cl2ECCF32EC+EC,,,CF32EC+Cl2ECR1McMillan[10](Fluoro2EC)1mol/LLiPF6/PC+EC,(MFA)(EFA)[11-12]-2,2,2(MTFEC)-2,2,2(ETFEC)-2,2,2(PTFEC)-(2,2,2-)(DTFEC),,,,LiPF6/MFA,(DSC),LiPF6/EC+DMC,LiPF6/MFA110(400),,,,MTFECETFECPTFECDTFEC,,-40-20,,2(AFE)2(MFE)2(EFE)J1Arai[13]1mol/LLi2BETI/EMCMFE,,,213,,,2(P2N)(P2X),,,:FP,FP,;F,SEI,;F,,;,TFPBMPTDP,091BATTERYBIMONTHLY34©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(2,2,2-)(TTFP)S1S1Zhang[14]TTFP110mol/LLiPF6/PC+EC+EMC,TTFP,TTFP15%,,TTFP,PC,,5%,,3,(),:a1,,;b1,;c1,PNFCl,;d1,,,,,:[1]LeeCW,VenkatachalapathyR,PrakashJ1Anovelflame2retardantadditiveforlithiumbatteries[J]1ElectrochemSolid2StateLett,2000,3(2):63-651[2]YokoyamaK,SasanoT,HiwaraA1Fluorine2substitutedcycliccar2bonateelectrolyticsolutionandbatterycontainingthesame[P]1US:6020806,2000-06-041[3]WangXM,YasukawaE,KasuyaS1Nonflammabletrimethylphos2phatesolvent2containingelectrolyteforlithium2ionbatteries[J]1JElectrochemSoc,2001,148(10):A1058-A10711[4]XuK,DingMS,ZhangSS,etal1Anattempttoformulatenon2flammablelithiumionelectrolyteswithalkylphosphatesandphos2phazenes[J]1JElectrochemSoc,2002,149(5):A622-A6261[5]HyungYE,VissersDR,AmineK1Flame2retardantadditivesforlithium2ionbatteries[J]1JPowerSources,2003,119-121:383-3871[6]XuK,ZhangSS,AllenJL,etal1Nonflammableelectrolytesforli2ionbatteriesbasedonafluorinatedphosphate[J]1JElectrochemSoc,2002,149(8):A1079-A10821[7]XuK,DingM,ZhangSS,etal1Evaluationoffluorinatedalkylphos2phatesasflameretardantsinelectrolytesforLi2ionbatteries[J]1JElectrochemSoc,2003,150(2):A161-A1691[8]OtaH,KominatoA,ChunWJ,etal1Effectofcyclicphosphatead2ditiveinnon2flammableelectrolyte[J]1JPowerSources,2003,119-121:393-3981[9]AraiJ,KatayamaH,AkahoshiH1Binarymixedsolventelectrolytescontainingtrifuoropropylenecarbonateforlithiumsecondarybatteries[J]1JElectrochemSoc,2002,149(2):A217-A2261[10]McMillanR,SlegrH,ShuZX,etal1Fluoroethylenecarbonateelec2trolyteanditsuseinlithiumionbatterieswithgraphiteanodes[J]1JPowerSources,1999,81-82:20-261[11]SatoK,YamazakiI,OkadaS,etal1Mixedsolventelectrolytescon2tainingfluorinatedcarboxylicacidesterstoimprovethethermalsta2bilityoflithiummetalanodecells[J]1SolidStateIonics,2002,148(3-4):463-4661[12]YamakiJ,YamakiI,EgashiraM,etal1Thermalstudiesoffluori2natedesterasanovelcandidateforelectrolytesolventoflithiumme2talanoderechargeablecells[J]1JPowerSources,2001,102(1-2):288-2931[13]AraiJ1Anovelnon2flammableelectrolytecontainingmethylnon2afluorobutyletherforlithiumsecondarybatteries[J]1JApplElec2trochem,2002,32(10):1071-10791[14]ZhangSS,XuK,JowTR1Tris(2,2,2-trifluoroethyl)phosphiteasaco2solventfornonflammableelectrolytesinLi2ionbatteries[J]1JPowerSources,2003,113(1):166-1721:2003-10-23[]8632004420,,,,;,;,SCD,;3001913,:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.