烟气脱硫脱硝活性炭的研究进展_宋欣钰

7櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃殭殭殭殭2017－02－222462015YQ0314C2016031990—*1979—。*102249。、、、。、。TQ424．1X511A1008－021X201707－0071－05ＲeviewoftheActiveCarbonUsedforDesulfurizationandDenitrificationofFlueGasSongXinyuNingGuoqing*StateKeyLaboratoryofHeavyOilProcessingChinaUniversityofPetroleumBeijing102249ChinaAbstractThemechanismoffluegasdesulfurizationanddenitrificationofactivatedcarbonisintroduced．Theresearchadvanceofpreparationstructurecontrolandsurfacemodificationofactivecarbonaresummerized．Theeffectsofsurfaceareaporevolumeandsurfacechemicalpropertiesonthedesulfurizationanddenitrificationefficiencyareanalyzed．Highsurfaceareahighporevolumeandstrongadsorptionperformancearetheuniqueadvantagesofactivecarbon．Pointedouttheprimaryobjectivesforfurtherresearchesarethecontrollingofporestructureandthemodificationofsurfacefunctionalgroupstopromotingtheperformanceofactivecarboninthegaspurificationprocesses．Keywordsactivecarbondesulfurizationdenitrificationstructurecontrolsurfacemodification。《2015》33821．6%22．5%。、、、SOxNOx。－、。NOx、、、－1SO2NOx、、、。20、、、90%2－3。19794。20115－998%。、。11976Bergbau－ForschungMitsui－BF11～3。SOx1380～·17·DOI:10.19319/j.cnki.issn.1008-021x.2017.07.023420℃210SO2SO2NOx3N2。100～200℃SO297%NOx80%～85%11－12。SO2+1/2O2+H2O→H2SO41H2SO4+1/2C→SO2+1/2CO2+H2O2NO+NH3+1/4O2→N2+3/2H2O31Mitsui－BFNOxSO2。22．113－14。15、16。17、18、19－21。、、、。。。。。20350～600℃10mm750～900℃950mg/g。。22CMC、4MPa600mg/g500～800℃120N/cm。、、。2350%450℃1h1600m2/g。24。2．2。25。Baran2640%150μm800kg/m31323K10MPa18MPa。、、27－29AＲ30160～800、560～670、340200～600kg·m－32．5～18．7、8～18．2、3．91～4MPa。。、。。。。315MPaPVBDBP、、900℃400MPa6．02MPa0．55g·cm－34．50MPa0．59g·cm－332。3315%NPA200kN800℃90min180min93．04%88．32%。34600℃800℃CO211．21MPa90%。33．1。35850～950℃SO22000ppm5000h－10．0115cm3/gSO2SO3。36CH2SO4300W400W17·27·SHANDONGCHEMICALINDUSTＲY201746719%27．8%524．9m2·g－1721．2m2·g－170mg·g－185mg·g－1。37SO2SO2SO2SO2。3．2。。3830℃H2S2%SO21%237．7h－110mg/m364．27mg0．5nm。25120℃500～800m2/g。Daley39ACFACFSO21000℃ACF。40ZnCl21485m2/gSO20．7nm41Ｒaymundo42。37298K75000mg/m30．9578。SO2。。SO2NO。4。。、、。、。2243SO2。Davini44/SO2。NN。2。2O、N45－46。4．1、、NaOH、KOH47。Daley39/SO2400～1000℃。48200℃35%NaOH45%HNO350．9%10%36．4%。。Daley39ACFSO2CO2ACFSO2Lizzio49SO2。Ｒaymundo42SO2。4．2V、Cu、Mn、Fe、ZnCuV。50V2O52nmV2O5。51、20%20min100%30min·37·80%。52Cu、Mn、ZnCu0．75%1．5hSO2NO99．89%94．11%XＲDCuO。4．3SO2。、。SO2。53900℃23．9%55．17%21．92%51．67%。。54SiO2332．6～455．5m2·g－1－78．6mg·g－120mg·g－1NSO255。564．25%～10．23%1000m2/gSO2NN10．23%48．3mg/gNSO2N、SO2。57SO2。SO2、NOx。。5。。。1．J．201036－9．2．J．20092325－333．3．J．2009656－59．4．J．1981692．5．C//．．2013．6．J．2013493－96．7．J．2014138－42．8．SO2J．2012226－30．9．450m2C//．．2011．10．J．2012461－63．11TsujiKShiraishiI．Combineddesulfurizationdenitrificationandreductionofairtoxicsusingactivatedcoke1．ActivityofactivatedcokeJ．Fuel1997766549－553．12OlsonDGTsujiKShiraishiI．ThereductionofgasphaseairtoxicsfromcombustionandincinerationsourcesusingtheGE－MITSUI－BFactivatedcokeprocessJ．FuelProcessingTechnology200065/6699393－405．13．《》J．2015523－26．14．D．2015．15．J．2011403448－452．16．J．2015168－73+85．17．J．2014103674－3682．18．J．2014592－95．19．J．20173111－115．20．J．20151104－110．21．D．2015．22．J．201161068－1074．23．D．2013．24．J．200620161－63．·47·SHANDONGCHEMICALINDUSTＲY201746725．J．2012353546－52．26BaranDYardimMFAtakülHetal．SynthesisofcarbonfoamwithhighcompressivestrengthfromanasphaltenepitchJ．NewCarbonMaterials2013602564．27ChenCKennelEBStillerAHetal．CarbonfoamderivedfromvariousprecursorsJ．Carbon20064481535－1543．28ＲaleyCFAsherDＲ．Processforpreparingmacroporousopen－cellcarbonfoamfromnormallycrystallinevinylidenechloridepolymerUS3960770P．1976－06－01．29SimandlＲFBrownJD．MicrocellularcarbonfoamandmethodUS5208003P．1993－05－04．30MochidaIYoonSHKoraiYetal．CarbonfibersfromaromatichydrocarbonsJ．Chemtech199525252．31QiaoWKoraiYMochidaIetal．PreparationofanactivatedcarbonartifactfactorsinfluencingstrengthwhenusingathermoplasticpolymerasbinderJ．Carbon200139152355－2368．32QiaoWKoraiYMochidaIetal．PreparationofactivatedcarbonformII．ＲolesofactivatedcarbonsonthestrengthofactivatedcarbonformusingathermoplasticpolymerasbinderJ．NewCarbonMaterials20011621－7．33．D．2013．34．J．201022511－14．35．J．201531126－1132．36．SO2J．20147890－896．37．SO2D．2013．38ShiLYangKZhaoQPetal．CharacterizationandmechanismsofH2SandSO2adsorptionbyactivatedcarbonJ．EnergyFuels201529106678－6685．39DaleyMAMangunCLDebarrbJAetal．AdsorptionofSO2ontooxidizedandheat－treatedactivatedcarbonfibersACFSJ．Carbon1997353411－417．40．SO2、NOD．2014．41．SO2J．2014S1548－553．42Ｒaymundo－PieroECazorla－AmorósDSalinas－MartinezDeLeceaCetal．FactorscontrolingtheSO2removalbyporouscarbonsrelevanceoftheSO2oxidationstepJ．Carbon2000383335－344．43．SO2/NOx/HgD．2007．44DaviniP．AdsorptionanddesorptionofSO2onactivecarbonTheeffectofsurfacebasicgroupsJ．Carbon1990284565－571．45BoehmHP．SurfaceoxidesoncarbonandtheiranalysisacriticalassessmentJ．Carbon2002402145－149．46ParaknowitschJPThomasAAntoniettiM．AdetailedviewonthepolycondensationofionicliquidmonomerstowardsnitrogendopedcarbonmaterialsJ．Jmaterchem201020326746－6758．47．J．201573405－3410．48．J．2014792－95．49LizzioAADebarrJA．EffectofsurfaceareaandchemisorbedoxygenontheSO2adsorptioncapac