Autolab操作手册

14.9.0052381.82.GPES83.FRA11GPES121.122.213.224.23FRA351.352.403.FRA414.FRA415.436.447.FRA358.FRA35Autolab4.9…………………………………………………………………52:GPES79:FRA89FRA92341.USB2.AUTOLAB3.4.NEXT5.Yes6.NEXT57.”C8.GpesDiagnosticsFraFRAMutlichannel9.2003USBAutolab-USB(Internal)orAutolab-USBInterfaceboxNEXT10.WindowsNEXT611.AUTOLAB12.13.714.Finish15.NoIwillrestartmycomputerlaterFinish15YesIwanttorestartmycomputernowFinish16.1317.USBUSB18.WindowsME/2000/XPC/AUTOLAB/USB819.Refresh20.91231GeneralPurposeElectrochemicalSoftware(GPES)1.1AutolabSoftwaresGpesGPES1.2GPESMethod101.3File1.4Editprocedure111.5Manualcontrol1.61.7CVLSV13a)FileSavescanasCVLSVb)FileSavedataSavedatabufferasCVLSVc)DatapresetationFileSaveworkdata1.8122FrequencyResponseAnalyserSoftwareFRA2.1AutolabSoftwaresFraFRA2.2Method2.3File2.4Editfrequencies(beginfre)(endfre)10=X10+1CalculateOKbeginfreendfre2.5Editprecedure2.62.7Z’~-Z”DataPresentationViewBode2.82.913GPES11.1File1.1.1Openprocedure1.1.2Saveprocedure1.1.3Saveprocedureas1.1.4PrintGPES1.1.5Printsetup1.1.6Loaddata(Loadscan)ShiftControl101.1.7LoaddatabufferCVLSV141.1.8SavedataSavescanasCVLSV1.1.9Savedataas1.1.9.1SavedatabufferasCVLSV1.1.9.2Exporttoscanno.VsQ+Q-file~~1.1.9.3ExportChronodataCVCV1.1.9.4ExporttoBAS-DigiSimdataBAS-DigiSimCVDigiSim.TXTASCII1.1.9.5ExportdatabuffertotextfileCVLSV1.1.10DeleteFiles1.1.11ExitGPES1.2Methods1.2.1VoltmammetricAnalysis1.2.1.1SampledDC1.2.1.2NormalPulseVoltammetry1.2.1.3DifferentialPulseVoltammetry1.2.1.4DifferentialNormalPulseVoltammetry1.2.1.5SquareWaveVoltammetry151.2.1.6ACVoltammetry1.2.1.7AC2ndHarmonicVoltammetry1.2.2CyclicVoltammetry(staircase)()1.2.2.1Normalmode1.2.2.2Stationarycurrent1.2.2.3ScanAveraging1.2.2.4CurrentIntergration1.2.2.5GalvanostaticCyclicVoltammetry1.2.2.6FastscanVoltammetry1.2.3CyclicVoltammetry(linearscan)(-SCANGEN)1.2.3.1Normalmode1.2.4LinearSweepVoltammetry(staircase)()1.2.4.1Normalmode1.2.4.2Stationarycurrent1.2.4.3ScanAveraging1.2.4.4CurrentIntergration1.2.4.5GalvanostaticCyclicVoltammetry1.2.4.6FastscanVoltammetry1.2.4.7Hydrodynamic1.2.5ChronoMethods(intervaltime0.1s)(0.1s)1.2.5.1Amperometry1.2.5.2Coulometry1.2.5.3Potentiometry(zerocurrent)OCP1.2.5.4Potentiometry(galvanostatic)1.2.6ChronoMethods(intervaltime0.1s)(0.1s)1.2.6.1Amperometry1.2.6.2Coulometry1.2.6.3Potentiometry(zerocurrent)OCP1.2.6.4Potentiometry(galvanostatic)1.2.7MultimodeElectrochemicalDetection1.2.7.1DCAmperometry1.2.7.2MultiplePulseAmperometry1.2.7.3DifferentialPulseAmperometry161.2.8PotentiometricStrippingAnalysis1.2.8.1ChemicalStripping1.2.8.2ConstantCurrent1.2.9StepsandSweep1.2.10ElectrochemicalNoise1.3Utilities1.3.1Electrodecontrol1.3.2BuretteControlDIO48171.3.3RDEcontrolDAC164RDE1.3.4MUXcontrol1.3.5I-interruptPGSTAT12/30/100181.3.6Positivefeedback1.3.7CalibratepH-ElectrodepHpH191.3.8Checkcell1.3.9Plate1.3.10Sleepmode1.3.11Setdefaultcolors1.4Options201.4.1TriggerDIO48TTL1.4.2Rescaleaftermeasurement1.4.3Rescaleduringmeasurement1.4.4ProcedurenameinDatapresentation1.4.5ShowallGPESfilesinFiledialogboxGPESGPES1.5ProjectsFRA2112FRAFRAFRA3GPESFRA1.5.1New1.5.2Open1.5.3Save1.5.4SaveAs1.5.5EditWizard1.5.6Execute1.6Windows1.6.1Tile1.6.2Close1.6.3Toolbar1.6.4StatusBar1.6.5Manualcontrol/1.6.6Datapresentation/1.6.7Editprocedure/221.6.8Analysisresults/1.7HELP2ManualControl¾ECD¾BIPOT¾BSTR10A/20A¾FI202.1Currentrangecurrentoverload.2.2Settings2.2.1Cellon/off2.2.2HighSenson/off23(100)1102.2.3HighStability/HighSpeeds10kHz100s2.2.4Potentiostat/Galvanostat/PotentiostatGalvanostat2.2.5IR-comp.on/off2.3Potential/\/SettingCellon/off2.4Noisemeters2.5IR-compensationSettingiR-compon/off2.6IntegratorPGSTAT12/30/100FI20AutolabIII2.7FilterpanelFI20ECD2.8//Zz.UtilitiesSleepmode3Editprocedure24()4Datapresentationa¾Range¾Ticks¾Grids¾Interceptposition//¾Scale¾LineAttributes25b¾Type+¾Data¾Lineattributes¾MarkerAttributescDataPresentation¾Graph¾PlottingAread¾LabelsPosition¾Format¾TextParameters264.1File4.1.1Saveworkdata4.1.2Saveimpedancedata4.1.3QuicksaveofpreviousscanCVLSV4.1.4SaveasChronodataStepandSweep4.1.5SaveasLinearsweepdataStepandSweep4.2Copy4.2.1Copy4.2.2Pastetext4.2.3Copyto4.3Plot4.3.1NewplotCV4.3.2AutomaticF4F4274.3.3Resume/4.3.4Zoom4.3.5Setwindow4.3.6Firstand2ndsignalsignal//4.3.7Evstplotanddt/dEvsEplot/~dt/dEvsE4.3.8ShowIforwardSWDPV4.3.9ShowIbackwardSWDPV4.3.10Selectoverlayscan4.3.11Loadoverlayfile4.3.12Reverseaxes4.3.13EnterText4.4Analysis4.4.1Peaksearch28////PositionHeightAreaWidth1/2DerivativeEp-Ep/2peakwidth:0.03,peakheight:1.0E-6¾Search¾OptionsÆAutomaticÆCurvecursorÆFreecursorÆWholepeakÆFrontpeakÆBackpeakÆLinearBaselineÆExponentialbasecurveÆPolynomialbasecurveÆLin.FrontbaselineÆLin.rearbaselineÆNobaselineÆPeakwidth:ÆPeakheight:¾Showresults¾CloseClear29Result4.4.2Findminimumandmaximum/Y/X4.4.3InterpolateXY4.4.4LinearregressionSlopeYIntercept4.4.5IntegratebetweenmarkersCVC4.4.6FitandSimulation304.4.7WaveloganalysisSE1/2Tafel314.4.8Tafelslopeanalysis4.4.9Corrosionrate4.4.10CurrentDensity1cm2324.4.11Markstartpoint4.4.12HydrodynamicivssqrwRDE~4.4.13Hydrodynamic1/ivssqrwRDE~4.4.14Chronoamperometr