苯选择性加氢技术的研究进展

3310Vol.33,No.10200410LiaoningChemicalIndustryOctober,2004(,113001):,:;;;:TQ031.4:A:10040935(2004)10057804,11[1]Birch,,,L-()(),,,,,,,,1,[2],,,,,,RuPhPtPdNi,Ru[1,2]1.1Ru,,,C.Milone[3]RuRuCl3Ru(acac)3Ru(NO)(NO3)3,RuCl3:Cl,,:2004208217:(1971-),,:,1.2[4],,17018046MPa,30%60%,20%40%;,,70%40%,m(La)/m(Zn)5,,5[5],RuCl3NaBH4,CrO2,CrO2,RuCl3CrO2,NaBH4,,42%,27%48%,11%1.3[1],,,d-,,,,1.3.1Zn,RuZnSO4Fe2(SO)4,Ru-Zn,,Ru,,Zn,,Zn,98%,10%Zn5%,(65%),Nagahara[6],:(1),;(2),1.3.2B[7],Ru,RuRuB,RuBB,B,,,,[8]XPSRu-B,,RuB,Ru,1.4,RuRu,,,,[9]Ru-B/SiO2,NaBH4H2Ru/SiO2,Ru,,,Ru2,9753310:,,(),[10],2.1,,,,,,,,,,,,[11]2.2,,[12],,BvB=-2,BvB=-1,:(9lnKx9P)T=-BvBP=-VRT,,,,,,2.3,,,,,,10001500r/min3,,,,RuT-50(T)50,,1500.39MPaH24h,,57%[13]SPt:S2120g/g24h,,8024h,S750g/g,[14],,,,0.51000g/g,,,RuAuCu,Ru[2],Fe,H2ONaOHZnOLa(OH)3RuNi,1504.9MPaH2,68g/g500h,30%,70%,,623h,16%68%,TiZr,46.9%,Ru,,(1)085200410;(2);(3)4,:(1):66Ru20/kg;(2),S,Cl,NO-3,NH-4,Fe,As,Cu,Pb,,(),[5];(3),(1),Ru;(2);(3),;(4)[1],,.[J]..2001,24(2):40245[2],,.[J]..2000,20(2):34239[3]C.Milone,G.Neri,A.Donatoetal.JournalofCatalysis.159(1996):253-258[4]Nagrahara.JP6388139,1988-05-11[5],,,.[J]..1999,20(4):1-5[6]H.Nagahara,M.Ono,M.Konishi,Y.Fukuokaetal.Ap2pliedSurfaceScience121(1997):448-451[7],,,.Ru-M-B/ZrO-2(J)..2002,16(3):217-222[8]ZhengLiu,Wei-LinDai,Jing-FaDengetal.JournalofCatalysis,187,253-256(1999)[9]SonghaiXie,MinghuaQiao,Jing-FaDengetal.AppliedCatalysisA:General176(1999).129-134[10],.[J]..1998,13(4):14218[11],,.Ru-M-B/ZrO-2[J]..2002,23(4):318[12]StrijkJ,MoeneR,KampTetal.AppliedCatalysisA:89(1992):77-102[13]OnoMitsuji,NagaharaHajime.JP0368453,1991-3-27[14]NagaharaHajime,FukuokaYohei.JP6265751,1987-6-21ResearchDevelopmentinSelectiveHydrogenationofBenzeneGAOBo(FushunResearchInstituteofPetroleumandPetrochemiacl,LiaoningFushun,113001,China)Abstract:Cyclohexeneisanimportantorganicchemicalproduct.Selectivehydrogenationofbenzene,catalystsusedinthisfieldandmaininfluentialfactorsonyieldofcyclohexenewerereviewedinthispaper,thepossibleapproachestoincreaseyieldofcyclohexeneweresuccessionallybroughtforward.Keywords:Benzene;Selectivehydrogenation;Cyclohexene;Rutheniumcatalysts1853310: