防老剂的最新发展动向(二)

()(,123000):,:;;:TQ330.38+2:B:167128232(2004)0320038207(b)ö,(n25)TMDQ,ET2MDQ;öADPAL()ADPAR()TMDQ,PO(),MBI(M)CR()(),,ETMDQ(AW),ETMDQ(,,),,ADPAL(2)())(c),(ODPA)(SDPA)(CDPA)(TDPA)(DPA),CR,CDPACR,CDPA(EPDMACMFKM)3EPDMPO,CDPATMQ(TMDQ)MBI,CDPA3:EPDM,(phr):EPDM(Epsyn70#):100;3#:5;:1;HAF:60;:35;Dicup40C:70;:,IPPD,(DPA),,,,,(SDPA)CR,TDPA(DPA),(),NR(),,,()(d)PBN(N2222)PAN(N2212),PBN,,PANPAN,CR2.2,,,,,(),7080832004(phr)CDPA(0.5)TMQ(0.5)CDPAöMBI(0.5ö2)TMQöMBI(0.5ö2)ML-135CVm35.537.037.038.037.0ts()10.910.712.511.59.5t$30()25.124.526.724.420.4160CMH(kg-cm)26.426.627.027.028.1100kg2cm3t(90)()20.319.520.922.517.06cpmt$80()17.316.517.718.614.4180C96hTT180C240hTTHS(JISA)M200(MPa)TB(MPa)EB(%)HSM200TB(%)EBHSTB(%)EB54545656562.52.72.52.62.916.716.916.317.217.4590580660630550+2+4+5+5+7-12+22+20+15--77-78-48-63-84-32-60-9-29-84+24+28+21+25+31-69-76-75-76--90-93-89-94-(CS%)100C22h25%2322393731:(160C)30min30min30min35min25min,[,Irganox1010(Geigy);Irganox565(Geigy);Cyanox1790(A.C.C.);Ethanox330(Ethyl)]SPDTBMP(BHT),MBMTB(),BBMTBP()TBMTBP(),,,,,,(GSGM)DBHQ(2,52)DAHQ(2,52),2.3(a)22,MBI()MMBIZn2MBIZnMMBI,,,,,,,TMDQMBI,,(),,DLTDP(),DSTDP(),,,(,PO),BTP()93313()BTP:nC12H25SCH2CH2COO(CH2CH2O)4CCH2CH2SOnC12H25,,,,,SBRCRNBRCSMCOECO,,,,NiDBC()NiDEC()NiDMC()(b),TNPP(),,,,(c)(),,,,,(1ö5,,,),()(),,,,(060C)(),5%,AFS(AFD),(1,3,521,32252),2,4,62(N21,42)(Uniroyal),,6PPD(d),(HHAP),,NR70C,IPPD(N22N2),()(N2)():APMA(NHNHCOCCH3CH2)MADA(NHNHCOCH2SH)MOHPPD(NHNHCH2CHOHCH2OCOCCH3CH2),APMANBR,MOHP2PD,BR,,NR,(),(,PPD),0420044,(),()(),,,,:NR100;1;5;HAF40;2;NS114.1(),,,,,,()14.2,,,,(NBR,CR)(),,8101NA(IPPD)44.3,(),,CD()white4NHNHCH(CH3)2(810-NA)NHNHCHCH2CH(CH3)2CH3(6C)810-NA6CEPDM0.51.9IR0.94.1BR1.66.8SBR1.98.1CR5.519.8NBR()26.8-gö100g,22CEPDMIRBR,SBRCRNBR()4.4,6C,,,,4.524.6,,,(),BHT(),,3,,MBI(14313()),235NRSBRCH2CCH3CHCH2(NR)(CHCH2)m(CH2CHCHCH2)n(SBR)NHNHCHCH3CH3(810NA)NHNHCHCH2CHCH3CH3CH3(6C)(224)(NS26)4.7,NRSBRBREPDMCR,,NBRCSMCPEIIRCl2IIR,,(),,,,,,,5,,5.1NRSBR55.2NBR242004NBR,NBR,NBR,5.3CRNRSBR,CR,,CR,810-NA(IPPD)6CDP,,,CD()5.4ECO(ECO),NBC()MB()224(TMDQ),,5.5ACM(),,CD,,2246C5.6EPDM,MBMBZ(),,,224CDEPDM,MB224CD,,647648t,,,34313()6IIS()TMDQ(224)(CR)NRSBRNBREPDM(PO)NHPAN(PA)CR,NBRC8H17NHC8H17ODPA(AD)NR,SBR,NBRCCH3CH3NHCCH3CH3(CD)ACM,CR,NBR,NR,EPDM(PO)NHNHDNPO(white)NBR,CR,ACMNHNHDPPD(DP)(CR)CR,NBRNHNHCH(CH3)2IPPD(8102NA)NR,SBR,NBR,CRNHNHCHCH2CH(CH3)2CH3(6C)NR,SBR,NBR,CRNC4H9C4H9CSSN22NiDBC(NBC)NBR,ECO,ACMMBI(MB)EPDM(PO)ECO,NR,NBR,CR[][1]½Ê¾}„˜ˆ™¨,Vol.54,No.9(2002)P4355[:]:01026804982268049823:010268016773:[e-mail]442004