制药废水深度处理技术的研究现状及进展-宋鑫

401220126GuangzhouChemicalIndustryVol．40No．12June．20121211111000832050015。、、、、。X703．1A1001－9677201212－0029－031985－。1963－。ThePresentSituationandResearchProgressintheAdvancedTreatmentofPharmaceuticalWastewaterSONGXin1RENLi－ren2WUDan1XIANGFeng－xin1SUNChun－bao11CivilandEnvironmentalEngineeringInstituteUniversityofScienceandTechnologyBeijingBeijing1000832InstituteofEnvironmentalProtectionNorthChinaPharmaceuticalGroupHebeiShijiazhuang050015ChinaAbstractWiththeoverallenforcementofthenewdischargestandardofwaterpollutantsforpharmaceuticalindus-trythedevelopmentoftheadvancedtreatmenttechnologyofpharmaceuticalwastewaterwasurgent．Thetechnologiesforadvancedtreatmentofpharmaceuticalwastewaterincludingcoagulationactivatedcarbonadsorptionmembranesepara-tionadvancedoxidationbiologicaltreatmentetc．wererewiewed．Characteristicsresearchprogressandthepresentsituationofeachpharmaceuticalwastewatertreatmenttechnologywerealsodiscussed．Moreoverthedevelopmenttrendsontheadvancedtreatmentofpharmaceuticalwastewaterwasprospected．Keywordspharmaceuticalwastewateradvancedtreatmentresearchprogress。、、。20096807527181．72%2．52%1。12。201071《》。、、、、。。1、。、、。、。。、。、、。、、、、、、、。。。30201262“－－—”。2。、。、、。、、。。。。3、、、。3。3．1、、4。。、5。。6PAC120mg/LpH=8t=25℃CODCr74．12%CODCr38．83～90．58mg/L89．98%。。、。3．2。、、、、。7CODCr400mg/L25L/h1000CODCr100mg/L。。3．3202060。、、、、、、8－9。10、、11。、。。。90%70%CODBOD85%90%、。MBR。、、。12MBRDO246mg/LCOD63%75%80%NH3－N88．5%93．6%94%。。3．42080AOPsAdvancedOxidationProcesses、、、·OH、、、、、13。Fenton、、、、、14。15Fenton、、、pHFeSO4·7H2O3mmol/LpH=3H2O2/Fe2+3∶160min。COD87．50%COD62mg/L。DantasRF16pH200mg/L0．4g/L15min10%60minBOD5/COD00．28。AchilleosA17UV－A/TiO2、H2O2。NaddeoV18401231、、pH。2．5～5mg/L。19COD0．5g/L30L/h2hpH6．2、、//+COD9．7%58．2%88．6%63．5%3．5、。。、。－。、、、。20154hCODCr。323～1021mg/LCODCr。4。。－Fenton21、Fenton－22、H2O2－23、－24。/25、26－27、28。/、29。、、、。1．－2010M．2010．2．J．2009173/416－18．3．J．201038－13．4．J．20083966－10．5．M．2010198－206．6．J．2010206136－139．7．J．201030438－42．8LiSZLiXYWangDZetal．MembraneRO－UFfiltrationforan-tibioticwastewatertreatmentandrecoveryofantibioticsJ．SeparationandPurificationTechnology2004341－3109－114．9ZhuANZhuWPWuZetal．Recoveryofclindamycinfromfermenta-tionwastewaterwithnanofiltrationmembranesJ．WaterResearch2003373718－3732．10．J．200929491－97．11．－－－J．200828372－77．12．－J．201124235－37．13．J．201137712－15．14．J．201038526．15．FentonJ．2009414575－579．16DantasRFContrerasSSansCetal．SulfamethoxazoleabatementbymeansofozonationJ．JournalofHazardousMaterials2008150790－794．17AchilleosAHapeshiEXekoukoulotakisNPetal．Factorsaffectingdi-clofenacdecompositioninwaterbyUV－A/TiO2photocatalysisJ．ChemicalEngineeringJournal201016153－59．18NaddeoVBelgiornoVKassinosDetal．Ultrasonicdegradationminer-alizationanddetoxificationofdiclofenacinwaterOptimizationofoperat-ingparametersJ．UltrasonicsSonochem201017179－185．19．J．20113916108－110．20．J．20044541－43．21OllerIMalatoSSánchez－PérezJ．A．CombinationofAdvancedOxi-dationProcessesandbiologicaltreatmentsforwastewaterdecontamina-tion－AreviewJ．ScinenceoftheTotalEnvironment20114094199－4166．22．－FentonJ．201128133－36．23．Fenton－J．200827638－41．24．H2O2－J．201142317－20．25．－J．2008281066－1068．26．－J．201036888－91．27．－－J．2009291174－76．28．J．2004241116－19．29．－J．20056583－86．