电渗析膜污染研究进展

1,2,1,1(1.,163318;2.,150090):,,,:;;;:TQ051.8:A:1673-6850(2006)06-0042-05TheInvestigationinMembraneFoulingofElectrodialysisTechnologyJINGGuo2lin1,2,WANGXiao2yu1,ZHAOHai1(1.FacultyofChemistryandChemicalEngineering,DaqingPetroleumInstitute,DaqingHeilongjiang163318,China;2.SchoolofMunicipalandEnvironmentalEngineering,HarbinInstituteofTechnology,HarbinHeilongjiang150090,China)Abstract:Accordingtotheionexchangemembranefoudingdefinitionofelectrodialysisunit,weexpatiatedthefoulinglawsofCa2+,CO2-3,humicacid,fattyacidandcarboxylicacidetc.toionexchangemembrane.Anditalsointroducedevaluationmethodsofmembranefoulingacross-the-board.Thepaperbroughtforwardtheseveraleffectiveandnewmethodstopreventandmitigatefoul2ing.Keywords:electrodialysis;membranefouling;foulingmitigation;ionexchangemembrane(electrodialysis,ED),3,,,,[1],,1,,,:2006-05-08:(1969-),,,,,:973(:2004CB418505);(:50402220404)[14].¡ŸÓÔÀŠÓ[J].,1986,204:30-35.[15]AyaUmeno,YoshitakaMiyai,NorioTakagi,RameshChitrakar,Ko2hjiSakane,andKentaOoi,PreparationandAdsorptivePropertiesofMembrane-TypeAdsorbentsforLithiumRecoveryfromSeawater[J].Ind.Eng.Chem.Res.2002,41:4281-4287.[16],.[J].,2003,19(1):55-60.[17].[J].,2000,17(3):307-309.[18],,,.LiAlTiO4Li+[J].,2005,22(7):754-758.[19],,,.LiMg0.5Mn1.5O4Li+[J].,2004,20(9):1126-1130.24356,,,1,[2]122.1[3],CaCl2400mg/L800mg/L,;CaCl2400mg/L(),LaurentBazinet[3],,,(40min),,[1]CaCl2800mg/L1600mg/L,,[3],2.2Hong-JooLee[4],,zeta(1),ACM,AMX100mg/L,,CMXACM,pH4.8pH5.8,,[5],,1(/cm2)()(meq/g-)Zeta(mV)pH6.06.3AMX2.53.53.4766701.41.72.5-5.33.4772761.8-6.7AM-11.32.02.4566801.82.22.3-3.92.4970822.2-4.0ACM4.05.06.3574781.41.74.0-7.47.6488922.1-2.1AMV3.04.53.1672783.2-5.04.2870762.7-3.7:AMX,AM-1,ACMNEOSEPTA(TokuyamaCorp,Japan);AMVSELEMION(AsahiGlass,Japan)2.3,,,[6]VikoiaLindstrand[6],AMV(SDBS),CMV(2),(),;,pH,,,(),,48h,(2)(SD2BS),200h300h(),(3);,34356480h2AMVCMV3SDBSAMVCMV2.4VikoiaLindstrand[7],,,[9],(),,,,[6],,;,/,,,,,2.5,[8],,,(1nm),,1nm,,33.1,[9],,,,3.2(),()[10];LaurentBazinet[3]2004,,YSI,3.3,0.4mm0.7mm;0.2mm0.5mm,0.10mm0.15mm,(,NaCl,,),,[3](MitutoyoCorp.IDCtype),3.4,,5kV,,[1]44356,3.5(AFM),[11]APMManagerversion210,,3.6,,,3.7[12]()/,44.1,,,4.1.1,,,AMXCMX30Hz,AM-1100Hz[13]4.1.2,,,,,[10]4.1.3,,[14],,,[10]4.1.4[15],(),(PEI)120,(PEI),PEI,(AEMs),4.2,,,,,,,(1),,,,(2)1%2%,,0.5h1h,,,,[16,17],,[18]5,54356,,,,,[][1]LaurentBazinet,MonicaAraya-Farias.Electrodialysisofcalciumandcarbonatehighconcentrationsolutionsandimpactoncomposi2tionincationsofmembranefouling.JournalofColloidandInterfaceScience.2005,286:639-646.[2]J.L.Booster,A.VanSandwijk,M.A.Reuter.Opposingscalingandfoulingduringelectrodialysisofsodiumfluoridesolutioninamem2branecellreactor.J.L.Boosteretal./Hydrometallurgy.2004,73:177-187.[3]LaurentBazinet,Monica,Araya-Farias.Effectofcalciumandcar2bonateconcentrationsoncationicmembranefoulingduringelectrodi2alysis.JournalofColloidandInterfaceScience.2005,281:188-196.[4]Hong-JooLee,Jae-HwanChoi,Jaeweon.Moonetc.Characteriza2tionofanionexchangemembranesfouledwithhumateduringelectro2dialysis.JournalofMembraneScience.2002,203:115-126.[5]E.Korngold.E.DeKorosy,R.Rahav,Desalination.1970,(8):195-220.[6]VikoiaLindstrand,GoranSundstrom,Ann-SofiJonsson.Foulingofelectrodialysismembranesbyorganicsubstances.Desalination.2000,128:91-102.[7]ViktoriaLindstrand,Ann-SofiJonsson,Goran,Sundstrom.Organicfoulingofelectrodialysismembraneswithandwithoutappliedvolt2age.Desalination.2000,130:73-84.[8],,,1[J]1,2004,28(1):41-43.[9],,1[M]1:,1990.310-3251[10]1[M]1:,1995,27-321[11]ParedesJI,Marenez-AlonsoA,TasconJMD.Applicationofscanningtunnelingandatomicforcemicroscopiestothecharacter2izationofmicroporousandmeoprousmaterials[J].Microporousandmesoporousmaterials.2003,65(2-3):93-126.[12]E.JamesWatkins,PeterH.Pfromm.Capacitancespectroscopytocharacterizeorganicfoulingofelectrodialysismembranes.JournalofMembraneScience.1999,162:213-218.[13]J.-S.Park,H.-J.Lee,S.-H.Moonetc.Foulingmitigationindesaltingelectrodialysis.Separation&PurificationTechnology.30(2):101-112.[14],,,1[J]1,1982,(46):29-33.[15]Jin-SooPark,Hong-JooLee,Seok-JuChoietc.Foulingmitiga2tionofanionexchangemembranebyzetapotentialcontrol.JournalofColloidandInterfaceScience.2003,259:293-300.[16]H.M.Yuan.Desalinationofsurfacewatertoindustrialwaterwithlowerimpactontheenvironment.ProtectionChem.Eng.1998,18:146-149.[17]D.M.Li,J.OrganicfoulingofEDmembraneswithandwithoutap2pliedvoltage.ColloidInterf.Sci.1994,163:108-119.[18]1[J].,2000,(1):37-40.2007()CN12-1221/TQ,ISSN1009-1785,16,12,200710,120(),,:1861105;:300192;:[phone];:[phone];E-mail:[e-mail]()()1972,,,,,:16,56,8,:6-34,:BM4144,:ISSN1673-6850,CN12-1388/TS:1201074000030:831;:300450;:[phone],65271737;:[phone];E-mail:[e-mail]64356