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ADVANCESINFINEFlOCHEMICALS97~,.~,~~,(,10(X)83);,,,,,,40%80%[3],,:(SRM)(CRM)(POM)(ATR)CO:,,,,,,,5,,Amiridist6J,,,sJ,,,,,30%50%CO,()CO10xloco,,Amiridis,:(l)CH4():CH4oC./[C(H)]J+(22)HZ(2)()HZOCOZH::Cod/[C(H)+HZO(:+(2+2)HZ,,,8J,1CO+HZ1:,,CO,;,;CO(0.5%)CO,,,CO::2(X)80301:,,,20087.J22.1,FeCoNiRuRhPtpdIrMO90FCoNiBRRh,,dd,:CoRuNiRhPtReIrPdCuWFeMoRhR,,B,FeCoNiMurasuvFeNi,,,CO,AvdeevaCo/A12O3Co60%75%,,,NiwangCo/Mgo900CO,CO1030run,,2Co/Sio:BaoLaZO3z2C,Co;Co,,(3NiNi,NiNiNi,NA1203,Ni(NiNi,NiNi1040nm,3759_/g_C:t(,Kuvshinov,34nmNi(18]NiNiCeO:9Ni,Ni,NiNi3c,Ni,[22.2Ni,CoodmanNitzlNHY,NHZSM5,N510:N5102/A12O,550,HZSM5,lh,NHZSM5,NHY,N510:N5102/A1203,NiThkenakaNiTioZ5102,,A1203MgO510:-MgoXRD(x)xANES(X),,Ni,ADVANCESINFINEPETROCHEMICALS97]Ni;,,Nixuzro:ANNi,Nzro:CP,NzroZANt24],Ni/ZrO:ANNi(10nm)Z2(725nm)2,25,,NirOZANNiZ2CPZNZrO:ANNUZrO:CP(Ni)2.3,ChenNi-CA1203Cu,NiCu2,NiCA1203z8J,cu,,;CuNiCNbZo,NiCu2.6,29;GdceoZNi[30Huffman(Pd,Mo,Ni)MFe(M=pd,Mo,Ni)400,700,PdFe(3la2.4,,,CO:/AmiridisN510:3h,,XRD,,NiGdmanChoudharyNi,Ni/z2Ni/Ce(72)NaY/VOP7%NA1203,,94%chouldary723K,,Zein15Mno:ZoNTi0263,COZTakenakaCOZNi/510:,,NA1203NTioZ,XANESXRDSEM(),60100nmNi,N510:Ni,,NA1203NTioZNi(6,,,CO:,20087.27,/123(l),,(2),;;l3l4l5l6l,,..,2(X)5,17(01):69772SongCS.FuelProcosingforwtemperatureandHightem-ratureFuelCells:Challenges,andopportunitiesforSusnabledevelmentinthe21steentury.catal,2002,77(2):17~493.,2005,33:6416494Mu~vN.C02eRxluetionofHydnenbyCatalytie01-ysisofHyd.dnFuel.E,1998,12(l):41485ChoudhTV,QmanDW.NondativeAetivationofMeth-ane.CIR,2(X)3,45(l):1512036ZhangT,AmiridisMD.HydrogenPduetionviatheDirectCekingOfMethaneoverSilieasuprtedNiekelCatyste.CaralA,1998,167(2):1611727ChoudhTV,GomanDW.StepseMethanesteamRefor.ming:aRoutetocoehyn.clt,1999,59(2-4):93978ChondharyTV,GomanDW.COePKluetionofHy-nviaStwiseSteamRe6rmingOfMethane.JCatal,2X),192(2):3163219HuangTJ,YuTC.EffeetofSteamandCarbonDioxidePItreat-mentsonMethaneDecompositionandCarbonGasifieationoverDodeaSupportedNiekelCatalyst.Catalt,2(X)5,102(34):17518210KrisT,DeelenMJ,SantenRA.HnFortnationfromMethanebyaLwtemPeratureTwostepReactionSeq1Jenee.JCatal,1992,138(l):10111411AvdeevaLB,KochubeyDl,Shaikhutdinov5K.CobaltCata-17l819202l22232425lystsofMethaneDeeomposition:AeeumulationOftheFIlamen-tousCarbon.1CatalA,1999,177(l):4351WangHY,RuekensteinE.FortnationOfFilamentousCarbordutingMethaneDecompositionoverCoMgoCatalysts.Car-6on,2002,40(11):19111917UXN,ZhangY,SmithKJ.MetalsuPPortInteraetionEffeetsontheCnwtllOfFilamentousCarlnoverCo/Si02Cata-lysts.1CataIAn,2(X)4,264(1):8191TakenakaS,IshidaM,SerizawaM,etal.FOationofCarlonNanboandCarbonNanotubestughMethaneDecom51-tionoverSuprtedCobaltCatalysts.JPhysChemB,20,108(31):1146411472ShkhutdinovSK,ZaikovskiiVl,AvdeevaLB.Crecipita-tedNialuminaandNiCualuminaCatalystsofMethaneDe-eomsitionandCarlnDep.itionIll.MhologyandSudceStruetureOftheCalbonFilaments.1CatalA,1996,148(1):123133MoleinLT,JohannesHB,DillenAJ,etal.ImctoftheStruetureandReactivityOfNiekelPartielesontheCatalytieCrOWthofCbonNanofibe..Ca1Today,22,76(l):33-42ErmakovaMA,YuD,ErmakovGG,etal.NNiekelCata-lystsfortheFomlationOfFilamentousCbonintheReactionofMethaneDeconllsition.JCa,1999,187(l):7784ErmakovaMA,YuD,KuvshinovGG.EffeetiCatalystsforDirectCkingOfMethanetoPrcueeHydronandFilamen-tousCon:P1.NiekelcatalystsICaalA,2();201(l):6170MuovN2.CO:ePduetionOfHgenbyCatalytiePysisofHydarbonFuel.Ene&F,1998,12(l):41~48BaiZQ,ChenHQ,UBQ,UW.MethaneDpositiono-verNiladedAetivatedCarbonforHydrogenPnuetiondtheForntionofFilentou,Carbon.JofHydroeenEne,2(X)7,32(l):3237ChoudharyTV,SivadinarayanaC,ChusueiCC,etal.HydgenPuetionviaCatalytieDecompositionOfMethane.JCatal,2(X)1,199(l):918ChoudhTV,SivadinalayanaC,ChusueiCC,etal.CatalytieDecomsitionOfMethane:t,aldsuetionOfCOehy-drogenforFuelCells.StudSCl,20()l,136:197-202TakenakaS,ogih,H,Yamanakal,etal.Decom,itionofMethaneoverSupportedNiCatysts:EffectsOfthesupportsontheCaytiUtime.ICaalA,2(X)l,217(l-2):101110lluHM,YeQ,XuBQ.EffieientHydnPrluetionviaStePwisedSteamReformingofMethaneUsingNanocompositeN2102Catalyst.StudSSdCatal,2007,127:473475XuBQ,WeiJM,YuYT,UY,etal.SizeUmitOfSuPPortParticlesinanoxideSuPPOrtedMetalCatalyst:Nanocomposite28ADVANCESINFINEPETROCHEMICALS97NZ:forUtiliZationOfNaturdlGas.JPhCemB,2(X)3,107(22):52035207XuBQ,WeiJM,YuYT,etal.CarbonDideRennlngofMethaneoverNanocompositeNZTO:Catalysts.,Catal,2(X)2,22(l2):7785ZhangQH,UY,XuBQ.RefornlingOfMethaneandCoalbedMethaneoverNanocompositeN2102Catalyst.Catal.TOJ,2004,98(4):601605ChenJL,UYD,UZQ,etal.RluetionOfCoxeHy-genandNanocarbonbydirectDeeompositionofUndilutedMethaneonNiCualuminaCatalts.CaIAn,2(X)4,269(12):179186UJZ,GX,UK.PmotiEectOfNbZAdtiontoNieueatalystsonnRuetionviaMethaneDecom-sition.C,2(X,33:652HuangTJ,WangCH.MethaneDeeompositionandSelfDe-eokingoverGadoliniadedCeriasupportedNiCatalysts.ChemiealEen9journal,2(X)7,132(l3):97103ShahN,PanjalaD,HI11anGP.HygenPuctionbyCat-alytieDeeomPositionOfMethane.Ene,2(X)l,1532262733283435293630373l(6):15281534.AielloR,FiseusJE,AmiridisMD.HydrogenluetionviatheDirectCekingOfMethaneoverN5102:catalystdeactivtionandregeneion1
本文标题:甲烷分步重整制氢催化剂研究进展
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