1科宁UVEB技术产品简介中文

Dr.AnbuNatesh1UV/EB技术产品简介中译文科宁中国吴晓天2007.1UV/EB技术讲台021203Dr.AnbuNatesh2•核心产品•辐射交联化学品(PHOTOMER®)–化学结构–水性UV产品–EB配方科宁公司技术总览Dr.AnbuNatesh6科宁的技术研发与产品结晶技术组合-溶剂型-水性-能量辐射固化产品组合-基料/树脂(齐聚物)-活性稀释剂(单体)-引发剂-助剂原材料总括-烷氧基多羟基化合物(EO/PO)-二聚酸-脂肪醇Dr.AnbuNatesh7Photomer产品范围PHOTOMER®3000系列环氧丙烯酸酯PHOTOMER®4000系列丙烯酸单体PHOTOMER®5000系列聚酯丙烯酸酯PHOTOMER®6000系列氨基甲酸乙酯丙烯酸酯PHOTOMER®7000系列羟基官能团多元醇PHOTOMER®8000系列甲氧基醚丙烯酸酯PHOTOMER®RM树脂丙烯酸流变改性剂引发剂助剂Dr.AnbuNatesh8来自科宁的高端技术•无溶剂UV/EB单体(世界专利)–应用于低气味，无挥发涂料、油墨、粘合剂体系•自引发的齐聚物(PHOTOMER®5424)(US专利)–在低抽出物体系中潜力无限–提高在金属及塑料基材的附着力–极佳的颜料润湿性能•UV固化的有机流变改性树脂(世界专利)–PHOTOMER®RM370及RM445–应用于平版墨及涂料体系–喷涂涂料(防流挂)Dr.AnbuNatesh9来自科宁的高端技术•低表面张力甲氧基醚丙烯酸酯(PHOTOMER®8127)–改善在低表面能的薄膜表面的流动–减少涂料缺陷–减少收缩及改善在UV固化薄膜的附着力•油酸基丙烯酸酯和甲基丙烯酸酯的范围(C12-22)–具有杠杆作用的科宁油酸化学品性能卓著–用于抗水及平光涂料–压敏粘合剂Dr.AnbuNatesh13环氧丙烯酸酯Photomer®机械性能010002000300040005000600070008000900010000Photomer®Type拉伸强度(psi)0102030405060708090100延伸率(%)TensileStrength(psi)Elongation(%)TensileStrength(psi)114575134154780442701349382729175285Elongation(%)15.886.033.075.264.9810.464.1025.126.02300530153016303830723082321536943071InstronTesting:FilmThickness=7milavg.Dimensions=2x0.5Headspeed=1inch/minFilmCompostion:EpoxyAcrylate=80.0%TPGDA=15.0%Photoinitators=5.0%CureConditions:LampTypeH-BulbEnergy=300W/inLineSpeed=50ft/inPasses=4XDr.AnbuNatesh15聚酯丙烯酸酯Photomer®机械性能0500100015002000250030003500400045005000Photomer®#拉伸强度(psi)05101520253035404550延伸率(%)TensileStrength(psi)Elongation(%)TensileStrength(psi)1175137818748543262Elongation(%)10.321.110.214.49.750185424542954305432InstronTesting:FilmThickness=7milavg.Dimensions=2x0.5Headspeed=1inch/minFilmCompostion:PolyesterAcrylate=80.0%TPGDA=15.0%Photoinitators=5.0%CureConditions:LampTypeH-BulbEnergy=300W/inLineSpeed=50ft/inPasses=4XDr.AnbuNatesh17Photomer®SeriesUrethaneAcrylatesTensileStrengthandElongation010002000300040005000600070008000900010000拉伸强度(psi)0.010.020.030.040.050.060.070.080.090.0100.0延伸率(%)TensileStrength(psi)682420588183538014073255105319779681991130125312742Elongation(%)8.445.07.97.439.527.368.731.886.460.146.620.042.1600860106019618462106217623063636572689168926788-20R6893-20RInstronTesting:FilmThickness=7milavg.Dimensions=2x0.5Headspeed=1inch/minFilmCompostion:UrethaneAcrylate=80.0%TPGDA=15.0%Photoinitators=5.0%CureConditions:LampTypeH-BulbEnergy=300W/inLineSpeed=50ft/inPasses=4XDr.AnbuNatesh19Photomersbasedonrenewableproducts产品:-Photomer3005F环氧大豆油丙烯酸酯-PhotomerECX3006改性亚麻油环氧丙烯酸酯-Photomer3049F脂肪酸改性环氧丙烯酸酯-Photomer3082亚麻仁油环氧丙烯酸酯-ECX4022二聚二醇二丙烯酸酯-RCC14-102癸烷二醇二丙烯酸酯-Photomer4094F甘油(3PO)三丙烯酸酯-Photomer4812F月桂醇丙烯酸酯-Photomer4816hexadecyl丙烯酸酯-Photomer4818F硬脂酸丙烯酸酯-Photomer4822behenyl丙烯酸酯基于科宁层出不穷的丙烯酸酯PHOTOMERDr.AnbuNatesh20Photomersbasedonrenewableproducts产品:•Photomer3215脂肪族环氧二丙烯酸酯(官能度=3)•Photomer3691脂肪族环氧二丙烯酸酯(官能度=2)•Photomer3165改性环氧丙烯酸酯(官能度=2)•Photomer4155乙氧基化(7EO)TMP三丙烯酸酯(官能度=3)•Photomer4158乙氧基化(14EO)TMP三丙烯酸酯(官能度=3)应用于UV体系可水分散的原材料Dr.AnbuNatesh21快速固化,高交联密度低粘度(18,000mPa.s@25oC)极好的表面硬度LightFast改善在PETA表面的附着力PHOTOMER®3215Dr.AnbuNatesh22PHOTOMER®3215在水中的粘度01,0002,0003,0004,0005,0006,0007,0008,0009,00010,00011,00012,00013,00014,00015,00016,00001234567891011121314%水粘度[e-mail]23低粘度(400mPa.s@25oC)给予固化涂膜好的柔韧性能与所有种类的丙烯酸酯相容稍快可接受最多40%的水PHOTOMER®3165Dr.AnbuNatesh24PHOTOMER®3165在水中的粘度050100150200250300350400450010203040%水粘度cpsDr.AnbuNatesh25ECX-6026•100%solidurethane二丙烯酸酯–实验室产品•高粘度(125,000cpsat65C)•Tg~-55C•高柔韧性能Dr.AnbuNatesh26附着力促进剂•PHOTOMER®4703•PHOTOMER®4173•PHOTOMER®5424•PHOTOMER®4846Dr.AnbuNatesh27PHOTOMER®4173酸官能团单丙烯酸酯特色高酸值(200)中等粘度(20-60Pat25C)固化得到硬不粘膜优势在处理过得塑料上附着力好粘结方面表现为高的剥离强度在蚀刻墨中使用温和级的易于剥离应用负性光刻胶，抗蚀刻印刷电路板.层压粘合剂应用于处理过的PP,OPP,BOPP,PET,醋酸纤维素制品用于铜、铝、钢基材的涂料透明涂料用于有机玻璃,PP,乙烯基及聚碳酸酯基材用于含填料、封底、含颜料的木器漆用于乙烯基薄膜地石版印刷油墨Dr.AnbuNatesh28PHOTOMER®4846附着力促进剂特色低酸值(最大10)低粘度(5-10Pat25C)固化得到表干硬膜应用水平Uselevel:10-75%优势与丙烯酸胺相容与粘合剂有较高的剥离强度应用层压粘合剂应用于处理过的PP,OPP,BOPP,PET,乙烯基基材铝材及钢材涂料.Dr.AnbuNatesh29PHOTOMER®5424附着力促进剂特色中等酸值(85-95)Built-in引发剂可与所有低聚物形成共聚提高附着力优势在处理过的塑料基材表面附着力好无需引发剂可自引发低抽出性极佳的颜料润湿性能用途石版、柔版及丝网印刷油墨负性光刻胶，抗蚀刻印刷电路板压敏粘合剂用于处理过的PP,OPP,BOPP,PET,LDPE。用于铜、铝、钢材及PMMA和聚碳酸酯Dr.AnbuNatesh30用PHOTOMER®5424提高附着力0102030405060708090100%CrosshatchadhesiontocoldrolledsteelPHOTOMER4028PHOTOMER5429PHOTOMER3038PHOTOMER6210W/OPHOTOMER5424With10%PHOTOMER5424UrethaneacrylateEpoxyacrylatePolyesteracrylateBisA(4EO)DADr.AnbuNatesh31PHOTOMER®4703酸官能团单丙烯酸酯特色高酸值(260)低粘度(1.5-2.0Poiseat25C)交联后形成有粘性的膜添加量:10-80%优势在处理过的塑料基材表面附着力好可作为活性稀释剂使用在耐蚀刻墨中易于剥离用途负性光刻胶，抗蚀刻印刷电路板压敏粘合剂用于处理过的PP,OPP,BOPP,PET,LDPE用于铜、铝、钢材及PMMA和聚碳酸酯Dr.AnbuNatesh32附着力促进剂-PH4703的最优选择02550751000510152025%PHOTOMER4703inaUVcoatingformulationPendulumSwingsx-hatchadhesion,%MEKdoublerubsDr.AnbuNatesh33附着力促进剂-PH47030102030405060708090100Crosshatchadhesion,%AluminumPaperboardPET(Mylar)PolypropyleneAdhesionenhancementofepoxyacrylateformulationbyPHOTOMER4703onvarioussubstrates.w/oPHOTOMER4703with15wt.%PH4703Dr.AnbuNatesh34ProductsDescriptionABCPHOTOMER®4846Adhesionpromoter607065PHOTOMER®4703Adhesionpromoter******10PHOTOMER®43611,6-Hexanediol(2EO)diacrylate***1010PHOTOMER®4006Trimethylolprop