导电聚合物聚吡咯的制备_性质及其应用

,,(,300131):(polypyrrole,PPy),,,:;;;;:O646.54:A:1009-4725(2010)05-0011-06Preparation,electrochemicalproperties,andapplicationofpolypyrroleCaiBenhu,iCaoLe,iWangZhaojun(CNOOCTianjinChemicalResearchDesignInstitute,Tianjin300131,China)Abstract:Polypyrrole(PPy),asatypicalconductingpolymer,hasmanyadvantagessuchasharmlessness,simpleandconvenientpreparation,highconductivity,electrocatalyticactivity,andhighenvironmentalstability,whichisconsideredthemostcommercialvalueofconductingpolymermaterials.Polypyrrolematerialshavebeenwidelystudiedandappliedinelectrocatalysis,sensors,metalcorrosionmaterials,secondarybatteryelectrodematerials,drugdeliverymaterials,andelectroniccontrolionexchangeetc..ThisarticleoverviewedthePreparationmethod,electrochemicalpropertiesandrelatedareasofapplicationwereoverviewed,andfuturedevelopmentofpolypyrrolewaspointedout.Keywords:conductingpolymer;polypyrrole;electrochemicalproperties;ionexchange;electrocatalysis,1977,Heeger,MacDiarmid(Polyacetylene,PA)(AsF5I2)P103S/cm[1,,[2,4,(10-9~105S/cm),,,,,,,,,,,,,[31C,N,,129.8!,0.97g/cm3,,,,[4;,11第33卷第5期2010年5月化工科技市场CHEMICALTECHNOLOGYMARKET,;,,,,,,,,;1.1CH3CN/NaClO4+0.76V(Ag/Ag+),,,,,,(NH4)2S2O8,FeC13,H2O2,K2Cr2O7,KIO3,,,1.2,,[5(/),(),,,,,22.1(),,,(DN),DN20,,pH,,,,,,,,pH,,2.2(),,(),,,;,(),,12化工科技市场第33卷第5期,,PPy,Cl-,(1);(pTS-)NO-3,(1)(2);(DBS-)(PSS-),(2),,(3),,,,,,,,,[6-72.3,pTS-,,NO-3ClO-4,110d25%~30%pTS-200!,ClO-4150!,NO-3,110!,,OH-,,433.1,,(ElectricallySwitchedIonExchange,ESIE),,,C.Weidlich,K.-M.Mangold,,,[8-103.2WollogongWallaceMurray,,,,[113.3,,,,,,,,,,;,,;,,[12132010年5月蔡本慧等:导电聚合物聚吡咯的制备性质及其应用3.4/,/,pH,NO-3Cl-Br-ClO-4(),,,,,,,,[13,()3.5,,Pawlizynwu,,,3.6,,,,,[14,;,,;3,,,[15AQDS/PPyAQDS(H2AQ)GC,AQDS/PPy,3.7,,,,,Tsutsumi[16(N-)(N-)/,1,2-,14.8Ah/kg,11.5Ah/kg3.8(),,,[17,,41997PA,,,3:1),14化工科技市场第33卷第5期,;2),,3),,,4.1,,,,,Jang4%[184.2,,[19,Jerome,Wang,4.3,,,,,,,,,,,;;,[204.4,5,,,,,,:[1]ChiangCK,FincherJrCR,ParkYWeta.lElectricalconductivityindopedpolyacetylene[J].Phys.Rev.Lett.,1977,39(17):1098-1101.[2]LippeJ,HolzeR.Electrochemicalin-situconductivityandpolaronconcentrationmeasurementsatselectedconductingpolymers[J].Synth.Met.,1991,43(2):2927-2936.[3]GaoHaixiang,JiangTao,HanBuxingeta.lAqueous/ionicliquidinterfacialpolymerizationforpreparingpolyanilinenanoparticles[J].Polymer,2004,45(9):3017-3019.[4]YongfangL.iEffectofanionconcentrationonthekineticsofelectrochemicalpolymerizationofpyrrole[J].JournalofElectroanalyticalChemistry,1997,433(1/2):181-186.[5],,,.[J].,2002,21(4):30-33.[6]SkaarupS,BayL,VidanapathiranaK.Simultaneousanionandcationmobilityinpolypyrrole[J].SolidStateIonics,2003,159:143-147.[7]JohansonU,MarandiM,TammTeta.lComparativestudyofthebehaviorofanionsinpolypyrrolefilms[J].ElectrochimicaActa.,2005,50:1523-1528.[8]WeidlichC,MangoldKM,JttnerK.Conductingpolymersasionexchangersforwaterpurification[J].ElectrochimicaActa.,2001,47(5):741-745.[9]SalehMM,WeidlichC,MangoldKMeta.lAbsorption/desorptionofcalciumionsonpolypyrrole-loadedreticulatedvitreouscarbon[J].JournalofAppliedElectrochemistry,2006,36:179-186.[10],,.152010年5月蔡本慧等:导电聚合物聚吡咯的制备性质及其应用[J].,2008,36(12):78-80.[11]ZhaoH,PriceWE,WallaceGG.Synthesis,characterisationandtransportpropertiesoflayeredconductingelectroactivepolypyrrolemembranes[J].JournalofMembraneScience,1998,148:161-172.[12]KontturiK,PenttiP,SundholmG.Polypyrroleasamodelmembranefordrugdelivery[J].JournalofElectroanalyticalChemistry,1998,453:231-238.[13]SaidmanSB.Thepotentiometricresponseofpolypyrroleelec-trosynthesisedinalkalinemedia[J].EuropeanPolymerJourna,l2005,41:433-437.[14]TkenT,ArslanG,YazycyB.Thepreparationofpolypyrrolecoatedbrassandcopperelectrodesforelectrocatalysis[J].ProgressinOrganicCoatings,2004,49:153-159.[15]GuoquanZhang,FenglinYang,WeishenYang.Theeffectofpolypyrrole-boundanthraquinonedisulphonatedianiononcathodicreductionofoxygen[J].Reactive&FunctionalPolymers,2007,67(10):1008-1017.[16]JinCY,YangFL.Iontransportandconformationalrelaxationofapolypyrrolefilminaqueoussolutions[J].SensorsandActuatorsB,2006,114:737-739.[17]LeHN,GarciaB,DeslouisC,eta.lCorrosionprotectionandconductingpolymers:polypyrrolefilmsoniron[J].ElectrochimicaActa.,2001,46:4259-4272.[18]JangKS,LeeH,MoonB.Synthesisandcharacterizationofwatersolublepolypyrroledopedwithfunctionaldopants[J].SyntheticMetals.,2004,143:289-294.[19]WangJ,MoX,GeD,eta.lPolypyrrolenanostructuresformedbyelectrochemicalmethodongraphiteimpregnatedwithparaffin[J].SyntheticMetals,2006,156:514-518.[20]ShimWS,LeeYH,YeoIeta.lPolypyrrole/thermallysensitivepolyelectrolytecomposite[J].SyntheticMetals,1999,104:119-127.:2010-04-21():(1982),,,:Emai:[e-mail].∀#,,,:47%~94%,2%~20%,2%~20%,0.5%~5.0%,1.0%~5.0%,0.5%~3.0%,,,,,,,,CN,101693851A,,,,,,,,,,,,,CN,101691512A,,,,,57.95%,,,,,,CN,101691326A,,,,99.9%CN,101691328A16化工科技市场第33卷第5期