促进剂MSDS-OF-CBS

MaterialSafetyDataSheet(CBS)LastRevision:05/01/20161.CHEMICALPRODUCTANDCOMPANYIDENTIFICATIONProductName:ACCELERATORCBSChemicalName:N-Cyclohexy-2-benzothiazolesulfonamideSynonyms:ACCELERATORCZ,sulfenamideTSCASReg.No.:95-33-0Molecularweight:264.4Function：Ingranulatedmasterbatchesrubberchemicalsarepresentinapolymerbound,predispersedformforimprovedhandlingcharacteristicsandmixingproperties.SuppliedBy:LiaochengKingeSyntheticMaterialCo.,LtdWesternofMudanjiangroad,High-techEconomicandTechnologicalDevelopingZone,Liaochengcity,Shandongprovince,ChinaEmergencyTelephone:0086-159662569882.HAZARDSIDENTIFICATIONEmergencyOverview:WARNING!Combustibledust-explosionpotential.Thismaterialisirritatingtoskin,eyesandrespiratorytract.EyeContact:Causesmildeyeirritation.MildEyeIrritation:signs/symptomscanincluderedness,swelling,painandtearing.SkinContact:Causesmildskinirritation.MildSkinIrritation:signs/symptomscanincluderedness,swelling,anditching.Maycauseanallergicskinreaction.Inhalation:Maycausemildrespiratoryirritation.Mayirritatemouth,nose,andthroat.Irritation(upperrespiratory):signs/symptomscanincludesorenessofthenoseandthroat,coughingandsneezing.Ingestion:Illnessmayoccurafterasingleswallowingofrelativelylargequantitiesofthismaterial.3.COMPOSITION/INFORMATIONONINGREDIENTSComponentCAS-NoWeight%N-Cyclohexyl-2-benzothiazolesulfenamide95-33-095MercaptobenzothiazoleDisulfide120-78-50-12-Mercaptobenzothiazole149-30-40-1Benzothiazole95-16-90.5Cyclohexylamine108-91-80.54.FIRSTAIDMEASURESSymptomsandeffects:Repeatedcontactmaycauseskinsensitization.FirstaidGeneral:Inallcasesofdoubt,orwhensymptomspersist,seekmedicalattention.Inhalation:notapplicable.Skin:Removeallcontaminatedclothingimmediately.Washoffwithplentyofsoapandwater.Seekmedicaladviceifirritationdevelops.Launderclothesbeforereuse.Eye:Rinsethoroughlywithplentyofwater.Eyelidsshouldbeheldawayfromtheeyeballtoensurethoroughrinsing.Seekmedicaladviceifirritationdevelops.Ingestion:Rinsemouth,givewatertodrink.Advicetophysician:Nospecificrecommendations.5.FIREFIGHTINGMEASURESExtinguishingmedia:waterspray,watermist,foam,drychemicalpowder,CO2Unsuitableextinguishingmedia:noneknownSpecialexposurehazards:Emitstoxicfumesunderfireconditions.Hazardousdecomposition:carbonmonoxide(CO),sulphurdioxide(SO2),nitrousgases(NOx).Protectiveequipment:Wearselfcontainedbreathingapparatus.Otherinformation:Donotallowrun-offfromfirefightingtoenterdrainsorwatercourses.6.ACCIDENTALRELEASEMEASURESPersonalprecautions:ForpersonalprotectionseeSection8.Environmentalprecautions:Avoiddischargeintotheenvironment.Methodsforcleaningup:Collectasmuchaspossibleinacleancontainerfor(preferable)reuseordisposal.7.HANDLINGANDSTORAGEHandling:Avoidcontactwithskin.Avoiddustgeneration.Fireandexplosionprevention:Takeprecautionarymeasuresagainststaticdischarges.Storagerequirements:Storeinadryandcoolplace.8.EXPOSURECONTROLS/PERSONALPROTECTIONEngineeringcontrols:Nospecificrecommendations.Exposurelimits:Nodustformationtobeexpectedundernormalconditionsofhandling.Intheunlikelycaseofdustformation:Noexposurelimitshavebeenestablishedforthismaterial.Thefollowingexposurelimit(s)applyfor.NameN-Cyclohexylbenzothiazole-2-sulf:WEL(TWA):4mg/m³(respirabledust).enamideOES-TWA10.0mg/m³inhalabledustOES-TWA4.0mg/m³respirabledustPersonalprotectionRespiratory:Nospecificrecommendations.Hand:Wearsuitablegloves.Eye:Wearsafetygoggles.Skinandbody:Wearsuitableprotectiveclothing.9.PHYSICALANDCHEMICALPROPERTIESAppearance:GreyishwhitepowderorgranuleOdour:odourlessBoilingpoint/range:notrelevantMeltingpoint/range:Activecomponent:99°C.Flashpoint:Activecomponent:177°C.Flammability:notdeterminedAutoignitiontemperature:notdeterminedExplosiveproperties:notdeterminedExplosionlimits:notdeterminedOxidisingproperties:notapplicableVapourpressure:notrelevantSolubilityinwaterActivecomponent:0.00032kg/m³(pH7,21°C)Solubilityinothersolvents:Activecomponent:inmostorganicsolvents.pHvalue:notdeterminedPartitioncoefficient:Activecomponent:4.93.n-octanol/waterRelativevapourdensity(air=1):notapplicableViscosity:notdetermined10.STABILITYANDREACTIVITYStability:Stableunderrecommendedstorageandhandlingconditions(seesection7).Conditionstoavoid:Heating100°C:Maycatchfire.Materialstoavoid:Nospecificrecommendations.Hazardousdecompositionproducts:Thermaldecompositionproducts:carbonmonoxide(CO),nitrousgases(NOx),Sulfuroxides(SOx).11.TOXICOLOGICALINFORMATIONName:N-Cyclohexylbenzothiazole-2-sulfenamideAcutetoxicityOralLD50rat:5300mg/kg.DermalLD50rabbit:7940mg/kg.IrritationSkinSlightlyirritatingtoskinbutnotsufficientforclassification.EyeSlightlyirritatingtoeyesbutnotsufficientforclassification.SensitizationPatchtesting(Humanexperience):Maycausesensitizationinsusceptibleindividuals.12.ECOLOGICALINFORMATIONName:N-Cyclohexylbenzothiazole-2-sulfenamideEcotoxicityfish96h-LC50(Lepomismacrochirus):7.9mg/l.96h-LC50(Oncorhynchusmykiss):5.4mg/l.96h-LC50(Pimephalespromelas):1000mg/l.daphnia48h-EC50(Daphniamagna):18mg/l.algae96h-IC50(Selenastrumcapricornutum):1.1mg/l.FateDegradationBioticNotreadilybiodegradable.