聚酰亚胺膜的应用研究进展

Vol137No1926NEWCHEMICALMATERIALS37920099:(1985-),,,:(1964-),,,11111,21,23(11,430062;21,430062)(PI)PIPI,,ResearchprogressontheapplicationsofpolyimidemembranesYanShanyin1ChenWenqiu1YangXiaojin1ChenChuan1XuZushun1,2YiChangfeng1,2(11CollegeofMaterialsScienceandEngineering,HubeiUniversity,Wuhan430062;21Ministry2of2EducationKeyLaboratoryfortheSynthesisandApplicationofOrganicFunctionalMolecules,HubeiUniversity,Wuhan430062)AbstractTheapplicationsofpolyimide(PI)membranesinrecentyearswerereviewed.TheapplicationsofPImembranesasseparationmembraneandprotonexchangemembranewereemphaticallyintroduced.ThedevelopmentsofPImembranesinfuturewerealsoprospected.Keywordspolyimide,membrane,application(PI),,PIKaptonUplixApical[1],PI,PI1111,PI,1PI,PI,10%[1](FCCL),,FCCLFCCLFCCLFCCLPI()API[2]112PI[3]PI,PI,,Yang[4]PI,Suzuki[5]PI113PI[1]11311[1]PI,[628],11312PI[1][9210](PEI),/PEI,//9::011MPa,PEI/PVP32165914L/(m2h),7611%7813%,9110%9215%,9910%,Ren[11]BTDA2TDI/MDIPI,PI11313,,[12213](BAN)PI,PI,PI,,[14],BAN,BAN11314PI,[15]23,6PI,[16]6,,PI,[17]/PI/,:PI,,11411411(PEMFC)Nafion,,,,(SPI)[18221],()SPI[22],SPI,,[23],,(1),Lee[24]SPI,(2SO3H),(IEC)1SPI[23]PI,,Yolanda[25][26](NTDA),Zhang[27](BTDA)PEMFCSPI(2),:BTDASPINTDASPI,,2SPI[27]PI,Seo[28]SPI(PEGDA)(semi2IPN),SPINafion117,PEGDAsemi2IPNSPI11412(DMFC)PEMFC,,,,[29231],,SPI,DMFC[32]2PI/SiO2,:,,SiO2Munakata[33](113m200nm)(3DOM)PI,112105Scm-1,Nafion1,DMFC7237[34](SPEI)(PES)SPEI/PES,SPEI,,DMFC115LB,PI,LB,PILB[35]Kang[36]PILB,,LBPI,PI116,LaRCCP22(3)PI,,Kresten[37]LaRCCP22(SWNTs),SWNTs,SWNTsLaRCCP22,3LaRCCP22[37]117Stphanie[38],PIPIPI,,,118,PI,,[39]LBPI,,,PILB,PILB85%,35PILB98%[40]119PI[41][42][43][44][45][46][47][48]2PI,,PIPI,PI,,,,PI[1].[M].:,2006.[2],,.[J].,2006,39(3):27232.[3],,,.[J].,2006,9(37):149621499.[4]YangChin2Ping,etal.[J].Polymer,2006,47(20):702127033.[5]SuzukiYasuhiro,etal.[J].OpticalMaterials,2003,21(123):5212524.[6]XiaoShude,etal.[J].Polymer,2007,48(18):535525368.[7]MarthaL,etal.[J].JournalofMembraneScience,2007,293(122):53265.[8]YounKookKim,etal.[J].JournalofMembraneScience,2005,255(122):2652273.[9],ChungTS.[J].,2001,21(2):33236.[10],ChungTS.[J].,2001,21(3):29232.[11]RenJizhong,etal.[J].JournalofMembraneScience,2008,309(122):1962208.[12],,,.[J].,2005,18(2):1942197.[13],,,.[J].(),2006,32(6):6292634.[14]LiGuoMin,etal.[J].SeparationandPurificationTechnolo2gy,2008,60:3302334.[15],,,.[J].,2003,23(5):5210.[16],,,.[J].,2004,24(3):60262.[17],,,.[J].,2006,26(5):16220.[18]HeBai,etal.[J].JournalofMembraneScience,2008,313(122):75285.[19]LiWenmu,etal.[J].JournalofMembraneScience,2008,315(122):1722179.[20]LiNanwen,etal.[J].Polymer,2007,48(25):725527263.[21]HoBumPark,etal.[J].JournalofMembraneScience,2006,285(122):4322443.[22],,,.[J].,2006,27(3):5862588.[23],,,.[J].,2007,28(7):140821410.[24]ChangHyunLee,etal.[J].JournalofMembraneScience,2008,313(122):1992206.[25]YolandaAlvarez2Gallego,etal.[J].Polymer,2008,49(18):829:387523883.[26],,,.[J].,2007,28(1):1732176.[27]FengZhang,etal.[J].JournalofMembraneScience,2008,314(122):24232.[28]SeoJongchul,etal.[J].PolymerDegradationandStability,2008,93(1):2982304.[29],,,.[J].,2004,55():2302233.[30],,,.[J].,2005,56(12):244022443.[31],,,.[J].,2006,27(6):115321156.[32],,.[J].,2005,12(36):192321927.[33]HirokazuMunakata,etal.[J].JournalofPowerSources,2008,178(2):5962602.[34],,,.[J].,2008,24(5):8552860.[35],,,.[J].,1998,11(2):2792292.[36]YunJiKang,etal.[J].ColloidsandSurf2acesA:PhysicochemEngAspects,2008,3132314:5852589.[37]KrestenLCNielsen,etal.[J].PolymerDegradationandSta2bility,2008,93(1):1692175.[38]StphaniePLacour,etal.[J].SensorsandActuatorsA:phys2ical,2008,147,4562463.[39],.[J].,2001,34(6):12217.[40],,,.[J].,1998,10(5):2552258.[41].[J].,2004,32(10):44245.[42],.[J].,2006,6:8332837.[43],.[J].,2005,25(4):50253.[44],.[J].,2008,4:3942398.[45],,,.[J].,2006,28(1):18221.[46],.[J].,1994,2:25237.[47],,,.[J].,2007,31(10):9292932.[48],,.[J].,2007,22(5):5242528.:2008211203:2008211220(20)[10],,,.LiNi1/3Co1/3Mn1/3O2[J].,2005,21(7):99921003.[11]KimJH,ParkCW,SunYK.SynthesisandelectrochemicalbehaviorofLi[Li0.1Ni0.35-x/2CoxMn0.55-x/2]O2cathodemateri2als[J].SolidStateIonics,2003,(164):43249.[12]ChangZhaorong,ChenZhongjun,WuFeng,etal.Synthesisandcharacterizationofhigh2densitynon2sphericalLi[Ni1/3Mn1/3Co1/3]O2cathodematerialforlithiumionbatteriesbytwo2stepdryingmethod[J].ElectrochimicaActa,2008,53:592725933.[13]JianGuo,LiFangJiao,HuaTangYuan,etal.Effectofsyn2thesisconditiononthestructuralandelectrochemicalpropertiesofLi[Ni1/3Mn1/3Co1/3]O2preparedbythemetalacetatesde2compositionmethod[J].ElectrochimicaActa,2006,51:373123735.[14],.LiNi1/3Co1/3Mn1/3O2[J].,2006,139(3):1832186.[15],,,.LiNi1/3Co1/3Mn1/3O2Si/F[J].,2007,23(3):4652472.[16],,,.Ti,FLiNi1/3Co1/3Mn1/3O2[J].,2007,28(10):183921841.[17],,,.Li(Mn1/3Ni1/3Co1/3)1-yMyO2(M=Al,Mg,Ti)[J].,2006,16(8):147421479.[18]LinBin,WenZhaoyin,GuZhonghua.Preparationandelectro2chemicalpropertiesofLi[Ni1/3Co1/3Mn1-x/3Zrx/3]O2cathodematerialsforLi2ionbatteries[J].JournalofPowerSources,2007,174:5442547.[19]JianGuo,LiFangJiao,HuaTangYuan.Effectofstructuralandelectr