1难降解染料废水处理方法的研究进展

14120023JOURNALOFJIANGSUINSTITUTEOFPETROCHEMICALTECHNOLOGYVol114No11Mar12002:1005-8893(2002)01-0061-04X1,1,,,(11,213016):,,(SCWO)(AOP),:;;:O21115:A,,,:pH,pHCODCrBOD5,PVA,,1111,,,,[1],[2]112701983Tinghuis[3]131982[4],95%98%,COD60%90%,95%[5],[6],,[7],,CAChen[8]AFT50,[9],,X:2002-01-04::(1964-),,,,95%99%Soma[10],,,,98%2211,,;212,,,W.Z.Tang/H2O2,,1g/LpH23H2O21mmol/L,;pH10,[11]213[12]TiO2,,TiO2[13],TiO2(2002000)mg/LTiO2,,,1000mg/L,[14]:,214,NaClNa2SO4,,O2Cl2,H2NaClOH2,,50%70%,CODCr,CODCr:215(ultrasound),[15],BOD5/COD01220128014401513311,,,BOD,,,,,,,[16],,,8313%,CODBOD90%,[17],,,COD20%30%90%,15%25%90%,312,262002:,;,;,,,,.,[18],,COD70%8616%,60%84%,[19],-,,,,,3,COD44%49%,90%Knapp[20],,,77%313-,,CODBOD,,,-,[21],,,:COD,-,,COD65%,70%80%4411(SCWO)(374)(2211MPa),,625,1s9919%MODEL[22]27133g/LSCWO,t=550,1min,99199%99197%,:,99199%;,;;(2%),,;,;,SCWO,,,(),,,,412(),,,104K;,,,,2BX-3B40s95%,,,,,,---,,[23]3615,,:[1],,1[J]1,1987,13(3):152-159.[2],1XBR[J]1,1998,32(9):126-129.[3]TingHuiLiu,Matsuurat,SourirajonS.EffectofMembraneMaterialSandAveragePoreSizesonReverseOsmosisSeparationofDyes[J].IndEngChemProdRosDev,1983,22:77-85.[4],1[J]1,1985,4(2):1-41[5],1[J]1,1981,7(4):19-211[6]1[J]1,1998,6():124-1271[7],1[J]1,1996,22(2):97-991[8]ChenGuohua,ChaiXijun,YuePo-Lock,etal.TreatmentofTextileDesizingWastewaterbyPilotScaleNanofiltrationMem2braneSeparation[J].JMembraneScience,1997,127(1):93-991[9],1[J]1,1997,17(5):7-101[10]SomacC,RumeauM,SergentC.UseofMineralMembranesintheTreatmentofTextileEffluentsPorc1stIntlConfInorganicMembranes[C].France:Montpellier,19891523-5261[11]TangWZ,ChenRZ.DecolorizationKineticSandMechanismsofCommercialDyesbyHydrogenPeroxide/IronPowderSystem[J].Chemosphere,1996,32(59):947-958.[12],1[J]1,1999,19(6):15-171[13],1TiO2[J]1,1999,15(3):58-601[14],1[J]1,1997,(3):17-211[15]1-SBR[J]1,1997,18(1):76-801[16]1[J]1,1997(9):11-121[17],,1[J]1,1998,24(4):37-391[18],,,1[J]1,1995,11(5):16-191[19],,,1[J]1,1996,16(1):64-671[20]KnsppJS,NewbyPS.TheMicrobiologicalDecolorizationofanIndustrialEffluentContainingDiazo-linkedchro-mophore[J].WaterResearch,1995,29(7):1807-18091[21],,,1[J]1,1995,51(1):57-631[22]ModelM.ProcessingMethodsfortheOxidationofOrganicsinSupercriticalWater[P].USPatent:4543190,1985-09-241[23]1[J]1,1998,24(5):259-2641ProgressintheApplicationofRefractoryDye-stuffWastewaterTreatmentProcessesFANHong-bo1,SUNXiao-juan1,WUWei-zhong,CHANGJie-yun,WANGJin(1.DepartmentofEnvironmentandSafetyEngineering,JiangsuInstituteofPetrochemicalTechnology,Changzhou213016,China)Abstract:Areviewofthetreatmentmethodsappliedtotreatingwastewatercontainingdyestuffanditsprogresswaspresented,andtherecentdevelopmentofadvancedtechniqueswasintroduced,suchasmembrane,ultrasonic,supercriticalwateroxidation,advancedchemicaloxidationprocesses,catalyzedphotochemicaldegra2dationandelectrochemicalprocesses.Recentachievementintraditionalbiochemicalprocessesandcoagulationprocesseswasalsopresentedandfuturedevelopmentprospectathomeandabroadareintroduced.Keywords:refractory;dye-stuffwastewater;wastewatertreatment462002