Fenton试剂MBR工艺处理环氧增塑剂化工废水的研究游文婷

WATERPURIFICATIONTECHNOLOGYVol.28,No.3,2009June25th,2009[]2008-09-26[](1985-)，，，。[]，：021-64253061；E-mail:[e-mail]。，Fenton，，。Fenton,，、，[1-3]。MBR，，（），，，，，，[4-9]。，（SBR）[10-11]。SBRCOD，COD，COD，，。H2O2，Fenton-MBR，Fe2+，；，MBR。11.1，：1、：++→；2、：、、、。、、、、、、、。，CODCr4500mg/L，H2O2Fenton-MBR，，，（，200237）H2O2，Fenton-(MBR)。Fe2+Fenton，(HRT)CODMBR。，FentonFe2+1.1g/L、3h、MBRHRT30hMLSS7000～8000mg/L。CODCr150～250mg/L，COD94%。Fenton：TQ028.8：A：1009-0177（2009）03-0061-04StudyofUsingFentonReagent-MembraneBioreactorontheEpoxyPlasticizersWastewaterTreatmentYOUWen-ting,FONGFei,XUZhen-liang,WULi(MembraneScienceandEngineeringR&DLab,ChemicalEngineeringResearchCenter,EastChinaUniversityofScienceandTechnology,Shanghai200237,China)AbstractUsingfentonreagentandmembranebioreactor(MBR)forthetreatmentoftheepoxyplasticizerswastewaterwhichcontainsH2O2.TheeffectofFentonreagenttreatmentwasstudiedbydifferentdosageofFe2+andreactiontime.Meanwhile,theefficiencyofMBRtreatmentwasdiscussedbyregulatingdifferenthydraulicretentiontime(HRT)andinfluentCODconcentration.Theexperimentalresultsindicatedthattheconditionsof1.1g/LFe2+,3hreactiontime,30hHRTand7000～8000mg/LMLSSweretheoptimumoperationconditions.TheeffluentCODCrreached150～250mg/Landtotalremovalratecouldreach94%.KeywordsFentonreagentmembranebioreactorepoxyplasticizerschemicalwastewateroperationparameters2009，28（3）：61-64WaterPurificationTechnology61--DOI:10.15890/j.cnki.jsjs.2009.03.010Vol.28,No.3,2009，，，.Fenton-MBR0.5%，pH3.5。1.2，；，。MBR：，，，，，SVI80mL/gMLSS，MLSS7000～8000mg/L[12]；（SRT）60d；MBR，1.5L/min。PVDF，352cm2，0.1μm，；MBR7.2L，MBR。1.3FentonpH3.5，FeSO4·7H2O，，，，，pH7～8，，，，COD。1.4MBRFenton，，MBRFenton，。MBRCOD。1.5、COD，《》[13]。22.1Fe2+FentonH2O2，Fe2+，FeSO4·7H2O。1，0.5%H2O2，2h，pH=3.5，Fe2+，COD。Fe2+1.1g/L，FeSO4·7H2O5.45g/L，COD。FeSO4·7H2O，1.1g/L（FeSO4·7H2O5.45g/L）Fe2+。2.2FentonCOD，FeSO4·7H2O，0.5h，pH，COD。2，0.5%H2O2FeSO4·7H2O5.45g/L，pH=3.5，，COD。3h，，COD，3h，COD。，FeSO4·7H2O，3h，COD50.71%。2.3CODMBR，FentonMBR。FeSO4·7H2O，FentonCOD，MBR，MBRCOD。MBR，，1CODMBR。3，，COD。，CODCr500mg/L。32.84kgCOD/（m3·d），MBRCODCr601mg/L，。1Fe2+CODFig.1TheeffectofCODreductionwithdifferentdosageofFe2+2CODFig.2TheeffectofCODreductionwithreactiontime62--WATERPURIFICATIONTECHNOLOGYVol.28,No.3,2009June25th,2009MBR2.34kgCOD/m3·dMBR。4MBR。MBRCOD。，2.34kgCOD/（m3·d），MBRCODCr500mg/L。MBR2.34kgCOD/（m3·d）。1，Fe2+0.82g/L，FentonMBRHRT30h，CODCr500mg/L。2.4HRTMBRHRTMBR，MBR，MBR。1.78kgCOD/（m3·d），HRT30h，25h20h，MBR，5。5，HRT，MBRCOD。HRT20h25h，COD，HRT20h，COD470mg/L。，，。HRT30h，COD，COD184～270mg/L，94%。，30h。2.5MBR，。2.94L/（m2·h），34kPa。，[14]，，。，5%（）（）（），→→，。，5HRTMBRCODFig.5TheeffectofeffluentCODinMBRwithdifferentHRT1CODMBRTab.1ThesituationofMBRwithdifferentCODvolumeloadFe2+/(g·L-1)FentonCODCr/(mg·L-1)MBRHRT/h/(L·m-2h-1)MBR/(KgCOD·m-3·d-1)MBRCODCr/(mg·L-1)1.651658305.81.331041.102228305.81.782480.822926305.82.344040.663553305.82.846014MBRCODFig.4ThevarietyofeffluentCODreductionwiththevarietyoftimeindifferentvolumeload3MBRCODFig.3TheeffectofCODreductionwithMBRvolumeload63--Vol.28,No.3,2009（51）[3]H.Parab,S.Joshi,N.Shenoy,etal.DeterminationofkineticandequilibriumparametersofthebatchadsorptionofCo(II),Cr3+andNi(II)ontocoirpith[J].ProcessBiochemistry.2006,41(3):609-615.[4]C.Namasivayam,R.T.Yamuna.Studiesonchromium(III)removalfromaqueoussolutionbyadsorptionontobiogasresidualslurryanditsapplicationtotannerywastewatertreatment[J].Water,Air,andSoilPollution.1999,113(1-4):371-384.[5]K.H.Chu,M.A.Hashim,Adsorptioncharacteristicsoftrivalentchromiumonpalmoilfuelash[J].CleanTechnologiesandEnvironmentalPolicy.2002,4(1):8-15.[6]J.P.Ibá觡ez,Y.Umetru.Uptakeoftrivalentchromiumfromaqueoussolutionsusingprotonateddryalginatebeads[J].Hydrometallurgy2004,72(3-4):327-334.[7]V.J.Inglezakis,M.D.Loizidou,H.P.Grigoropoulou.EquilibriumandkineticionexchangestudiesofPb2+,Cr3+,Fe3+andCu2+onnaturalclinoptilolite[J].WaterResearch.2002,36(11):2784-2792.[8]WuD.Y.，SuiY.M.，HeS.B.,etal．Removaloftrivalentchromiumfromaqueoussolutionbyzeolitesynthesizedfromcoal覱yash[J].JournalofHazardousMaterials,2008,155(3)415-423.[9]Sui,Y.M.,Wu,D.Y.,ZhangD.L,etal.Factorsaffectingthesorptionoftrivalentchromiumbyzeolitesynthesizedfromflyash[J].JournalofColloidandInterfaceScience.2008,322(1)13-21.[10]D.Y.Wu,B.H.Zhang,L.Yan,etal.Effectofsomeadditivesontheformationofzeolitefromcoalflyash,Int[J].JournalofMineralProccessing.2006,80(2-4)266-272.5.8L/（m2·h），20kPa。，5.8L/（m2·h），。，，。，。Fenton，Ca2+Fe(OH)3。，。，Fenton，，，。5～10mg/L，，。3（1）Fe2+，FentonCOD，1.1g/L，COD。1.1g/LFe2+（FeSO4·7H2O5.45g/L），COD50%。（2）Fenton，3h。（3）Fenton，MBR，HRT30h，Fe2+0.82g/L。（4）FentonFe2+1.1g/L，3h，MBRHRT30h，MLSS7000～8000mg/L，COD94%。[1]，．(Fenton)[J]．，2005，46(5)：319-320.[2]，，，./[J]．，2005，(5)：31-34.[3]，，，.Fenton[J]．，2006，29(6)：28-33.[4]．[M]．：，2001.[5]．[J]．，1991，17(5)：318-323.[6]ChiemcliaisriC，WongYK,UraseT,etal．Organicstabilizationandnitrogenremovalinmembraneseparationbioreactorfordo-mesticwastewatertreatment．WaterScienceTechechnology，1992，25(10)：231-240.[7]SuwaY，SuzukiT，ToyoharaH.,etal．Single-stage,single-sludgenitrogenremovalbyanactivatedsludgeprocesswithcross-flowfiltration．WaterResearch，1992，26(9):11