SYHB200602013

2006292　　　　　　　　　ENVIRONMENTALPROTECTIONINPETROCHEMICALINDUSTRY39　　　宋　丹(中国石化工程建设公司,北京　100101)　:。,,,、。,,,,。:;;;　。,0.5%～1%。,。(16×108t/a),、,“”,。,、、、、、、、。、、、。,、,。,,,、,、、,。,、、。,,。25%5%,70%。,98%。。,、,,,。、、,。,,,。1　,:、、、、。、,;、,,4197%,;,,,;,,;、,。,、,。:2006-01-10:,,。2005(),。:010-8487870140　　　　　　　　　　　　200629　　:—、、(、)。2　2.1　—,。:,、,;,,。。10%,;4%,。,,、。,。、、,。1。2.2　,,()。,、、4,,。2.2.1　90,,299℃399℃,,1　,。[1],。2.2.2　,、、、、,。。,。:。,。(),。,,370℃,。,;,。,,。,,2　.41　　　,、、、。2.3　,、、。,,、、。C∶N∶P100∶10∶1,[2]。,、。2.3.1　,。,C、N、P,pH,。,,。,,()。2.3.2　,。,;(、)、,[3]。。:、、。,2。,。。、、、、pH,,,。:,。,。,、。2.4　,,、、,。,,,:、、。,;,,;、,;,,。,。、、CO2[4]。,-:、(2～4)、、;,,。、(HNO3),,。200～375℃、0.1MPa,,CO2H2O,。,,,。--。,,--,,,,。,,,、,42　　　　　　　　　　　　200629;,,。。,。,,。,,,,:、,;,,,,,。,0.25%(),。,,;;,。2.5　2.5.1　,、。,。,。,、、、、,[5]。、。,。,,,NaCl、CaCl2。2.5.2　。。、,、、、、,CO2、,。,、、、pH、、。。。,,。2.5.3　,,,,。,。:、、、。。,,(60℃),(PAC),、,。,、,,800～850℃,30min,。,,,,。3　,,、。(下转第45页)2.45　　　5　mg/LFX25101511.53.84.36.8,%89.497.296.093.716.716.317.315.3,%89.689.288.589.85,FX5mg/L,100mg/L,FX,。2.5　MAX-2,FXMAX-2,。6　mg/LMAX-2+FX1235.0+5.07.5+2.52.5+7.55.48.46.12.85.04.36,FXMAX-2,10mg/L,5mg/L,《》10mg/L。3　(1)MAX-2,50℃,pH=7.5,5mg/L,,。(2)FX5mg/L,,。(3)FXMAX-2,10mg/L。1　.[M]..:,1989.2　.[M].:,1996.1～2.3　..[J],2000,10(1):26～284　..[J],1996,16(6):285　.PAFCS.[J],1996,16(4):29～30(上接第42页),、(),。,、、。,;,。,。,。,,。1　KuriakoseAP,etal.Bituminouspaintsfromrefinerysludge.SurfaceandCoatingsTechnology,2001,145(3):132～1382　CharlesU,etal.Noveltechniqueforrenderingoilysludgeenvirionmentallyacceptable.JournalofHazardousMate-rials,2002,92:51～623　.“”.,2003,21(2):121～1244　.CO2.,1993,(3):82～855　..,2001,27(104):7～8ABSTRACTSENVIRONMENTALPROTECTIONINPETROCHEMICALINDUSTRYStartedPublicationin1978,Quarterly.10June.2006Vol.29No.2Total114th　forwardsuggestionforfutureimprovemen.tKeywords:IndustryResidueLandfillPlace,Situa-tionofEnvironment,AnalysisSTUDYONTHETREATMENTTECHNOLO-GYOFOILYSLUDGESongDan.SEI,Beijing,100101Abstract:Theoilysludgeisoneofthemainpollu-tionofpetroleumandchemicalindustry.Itisinlargevolumeandveryhardtodealwith,whichisaseriousproblemtotheenvironmentpollutionofoilfieldandrefiningenterprise.Today,therearemanywaystosolvethisproblemindoorandoutdoor,buttheeffectisnotinevidence.Inordertodealwiththisproblemandprotecttheenvironment,wehavetoseekforaneconomicalandsimplewaytotreattheoilysludge.Keywords:OilySludge,Pollution,EnvironmentProtection,DealingWithTHEOPTIMIZATIONOFCOMPOUNDFOR-MULATIONFORTREATEDOIL-BEARINGSEWAGEREFILLEDINTOGROUNDLiMeirong,TianLiming,MaJifei,LouLaiyong.DepartmentofChemicalEngineering,UniversityofPetroleum,Dongying,Shandong,257062.ZhuWei.ShengliEngineeringandResearchInstituteofShengliOilField,Dongying,Shandong,257068Abstract:Astheconcentrationofoilandsuspendsolidsinoil-bearingsewageofHao-yistationareoff-spec,theresultingsewagecan′tberefilledintotheground.Theeffectofthreekindsofflocculantshasbeencompared.ThebestflocculantsisMAX-2with50℃,pH7.0.Thesuitableexperimentalcon-ditionsfordoffingtheoilandsuspendsolidsfromthesewage,theaddingamountis10mg/L.Thecomposi-tionoftreatedwaterisfollowing:oilcontent10mg/L,suspendsolids5mg/L.Theobtainedwa-termeetsthemaintechnicalparametersofreuseddemandsofoil-bearingsewage.Keywords:Oil-BearingSewage,Flocculants,OilContent,SuspendSolidsIONCHROMATOGRAPHYAPPLIEDINANALYSISOFWASTEWATEROFPETRO-CHEMICALINDUSTRYXiaoHuiying.SINOPECJiujiangBranch,Jiujiang,Jiangxi,332004Abstract:ByuseofIC-6ion-chromatographicanalyzerstudiesthemeasurementtechnologyofanioninpetrochemicalindustrywastewater,andfirstde-velopameasurementmethodforanioncontentof(F-,Cl-,NO-2,PO3-4,NO-3,SO2-4)inwastedrainoutwaterfromoil-refiningunitsandchemicalfertilizerplants.Take0.0054mol/Lofbicarbonatesodiumand0.0050mol/Lofsodiumcarbonateasrinseliquid,undertheconditionofcurrent70mA,1.5mL/minofcurrentvelocityand0～42MPapumppressure,measuresthecorrelationcoefficientofeachanionislargerthan0.995andtherelativestandarddeviation(RSD)is5.00%,addtomarkrecoveryrateis95%-116%.Keywords:IonChromatographic,PetrochemicalIndustryWasteWater,Analysis,ApplicationSTUDYONDETECTIONMETHODFORTRACEFE(III)INENVIRONMENTWATERSAMPLEGuoFang.OilCompanyofPingdingshanCity,Pingdingshan,Henan,467000.ChenXin.TheCityDesignandResearchInstituteofPingdingshan,Pingdingshan,Henan,467000Abstract:At5.0pH,aternaryassociationcomplexsystemwhichwasformedby,Fe(III)and717strongalkalescenceanionexchangeresin,hasthelargestabsorbanceatthewavelengthof490nm.Withthethreeassociationcomplexsystem,thesen-sitivitywas48timeslargerthanthatinwatersolu-tion,basedontheincreaseofabsorbancesectionalsurfaceandthepelectronfreespaceoftheFecom-plexintheresinphase.TheRSDoftheoverallmethodwas2.7%(n=6)for6.0μg/mL.Thede-velopedmethodwasappliedinthedeterminationoftraceFe(III)surfacewater,thelinearrangeof0-10μg/25mLanddetectionlimitof0.12μmolL-1wereachieved.Keywords:TernaryAssociationComplexSystem,ThinLayerResinPhase-Spectrophotometry,Fe(III)