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0,2011,7t。,,。[1]、,[2]。、、、、、、、,,。1,,,,。1.1[3]-FentonJZ9-3,50%H2SO4pH4.0,,4.0cm,3.0A,15min,30%H2O21.0mL,,,99.2%。[4],:pH,,pH;1A、10mm,500mg/L,pH7.220min,89.6%。[5],,,(,113001):,,。,、、、、、、,,。:;;;;;;;:X7:A:1674-4829(2013)02-0071-04:2013-01-18:(2012019).:(1977-),,,,,:.ResearchProgressinPhysic-chemicalTreatmentMethodsofOilExtractionWastewaterYANGShuang-chun,SUNXi-bo,LILei,PANYi(LingningShihuaUniversity,Fushun113001,China)Abstract:Oilextractionwastewaterisofcomplexcomponentandisdifficulttobiodegrade.Oilextractionwastewaterinmostdomesticoildepositsaredeposedbycombinatingphysicochemicalandbiochemicaltechnology.Inthispaper,thesetreatmentmethodswerereviewedsuchaselectrochemicalprocessing,adsorptionmethodtreatment,ozonemethod,flocculationtreatment,catalyticmethod,ultrasonicprocessing,microwavemethod,andsoon.Somesuggestionsofthefutureresearchweremadeaftertheevaluationandcomparisonofthesemethods.Keywords:Oilextractionwastewater;Physicochemicalmethod;Refractory;Electrochemical;Adsorption;Ozone;Flocculation;Catalyticoxidation26220134EnvironmentalScienceandTechnologyVol.26No.2Apr.201320134,,:pHm(Fe)/m(C);:pH=5,m(Fe)/m(C)7∶1,50min。m(Fe)/m(C),COD170mg/L,COD95.6mg/L,43.85%。[6]COD,,50mL,COD720mg/L,:10mm,6.4mA/cm2,4.2V,150min。CODCr120mg/L。1.2[7](GAC)。,35℃,100r/min,pH8.0~9.0,GAC2hCOD50%;35℃,pH8.0~9.0,1~5m/h、19.2~96min,COD60mg/L。GAC,80%。[8],,,(90%),10000mL,(10.1mg/g),COD13%~35%,90%。[9]GAC,--GAC,200mL301-3,:pH1.5,40g,1.5h,COD90%,,H2O2/Fe2+,CODGB8978—1996。[10]GAC/O3/UV,350μmGAC。3g/mLGAC1200mg/LCOD,220r/min90min,COD1120.6mg/L。1.3(O3)[11]O3GAC。:O3GAC,CODTOC77%49%;-,CODTOC80%74%,GB21/1627—2008《》。[12]-COD,3:A1,A2,A3。:O380mg/L、1000mg/L、pH10.850min。,,A3/O3,COD118.450mg/L,COD79.40%,O3,A1/O3,A2/O33COD33.00%,14.00%18.10%。[13]4(2000m),O3/Fenton,:O3pH11,50min,FentonpH3,3h,H2O2600mg/LFeSO4400mg/L,CODCr94.14mg/L,98.3%。,。[14]-(UV/O3),pH、COD,O3,:,pH3.0:O3810mg/h,60min,COD647mg/L96mg/L,UV/O3COD。1.4[15],Jeffamine-T4O3CS2DTC(T4O3)。DTC(T4O3)Fe2+,DTC(T4O3)25mg/L,10mg/L。[16],PAC,PFS,PAC-PFS,,:,PAM20~25mg/L,PAM55%,4“”PAC,80%。[17]“9-1”,,、722629991mg/L,21.1mg/L13mg/L,pH7.36。PFSS,PFSS50,100200mg/L,2.6%,3.1%4.7%,20%,25%32%,38%,54%62%。[18]FX,FX3mg/L,SS88%,-,1mg/L,99%;SS3mg/L,95%。-SY/T5329—94《》。1.5[19]TiO2,XRD,SEM,,,350μm,,,。TiO2,CODGB8978—1996《》,COD61%。[20]COD,-。:,pH4,400mg/L,45min,-COD97.4%;-,ρ(COD)100mg/L,。[21]-,,:pH4,m(H2O2):m(Fe2+)9∶1,ω(H2O2)=30%3mL/L,600mg/L,1.5h,pH7~8,、COD。[22]“”,:,TiO2TiO244.9,44.8544.85nm。1.6[23](+),:,23.67%,97.38%,TDS98.12%,CODSS88%;+,。[24]、、,、、,,。[25]--,,8.1~67.0mg/L、35~120NTU,10454~11354mg/L,/0.8mg/L、0.5NTU、(SDI)3,950mg/L,。[26],,5000mg/L,:、0.5mg/L,95%,200L/h,50L/h,3.47/m3,。1.7[27],:,PAC()20%,PAM()30%,1/4。60sTGB(),FEB(),SRB()99%,,20%。1.8。[28]-,、pH、、、-。,:pH。2.0g/L,pH2,870L/h,300W75min,97.28%。2,,90%,7320134!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!6%~9%,2826t,51%,。,:①、、;②、,;③。[][1],,,.[J].,2010,23(2):64-67.[2],,,.[J].,2010,23(6):18-20.[3],,,.-Fenton[J].,2011,42(5):20-22,31.[4],.[J].,2009,25(7):83-85,89.[5],,,.[J].,2012,6(1):242-245.[6],,,.[J].,2009,28(S2):117-120.[7],,,.[J].,2010,33(12):56-61,65.[8].[J].,2011(3):75-76.[9],,,.[J].,2009,38(1):81-84.[10],,,.O3/UV[J].,2011,34(12):311-314.[11],,,.O3-GAC[J].,2010,28(S1):4-6,21.[12],,,.[J].,2012,38(2):79-83.[13],,,.O3/Fenton[J].(),2010,32(5):146-149.[14],,.UV/O3[J].,2009,29(2):29-32.[15],,,.[J].,2010,31(10):2349-2353.[16],.[J].,2011(3):73-74.[17],,,.-[J].,2012,6(5):1531-1535.[18],,.-[J].,2010,30(2):156-158.[19],,,.TiO2[J].,2011,37(2):39-41.[20],,,.[J].,2009,29(4):64-67,138.[21],,,.-[J].,2009,26(6):33-36,94.[22],,,.[J].,2011,11(19):4529-4532.[23],,,.[J].,2010,36(1):86-90.[24],.[J].,2011,31(3):15-19.[25],,,.[J].,2009,38(1):78-84.[26].[J].,2009,35(5):182-185.[27],,,.[J].,2012,22(3):44-46,81.[28],,,.[J].,2010,36(10):32-34,40.()74
本文标题:采油废水物化处理法研究进展
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