沉积物中重金属形态分析方法研究进展

1111113(1.,250100;2.,250013;3.,277101),,TessierForstnerBCR,,,,2050,,2070,[1],AsBeCdCrCuPbHgNiTi[2],,,,,,,,,[3],Cr(III),Cr(VI),Cr(III)100;As(III)As(V);,,,1,,,,4[4]:,,,,,,,,,,,,,2090,,[5],,(SQC),,,,2,,()(),0.45m,()()2.1,:2006205220272006,15,4,(l)A.M.Ure[6],(),,,4(2),,,,,,,:Tessier1979[7],Tessier;Forst2ner1986[8],Forstner;(CommunityBureauofReference,BCR,theStandards,MeasurementsandTestingProgramme,M&T)19924[9],BCRTessier:,Forstner:(Mn)BCR4:,BCR,,BCRFessierForstnerBCR34[10],TessierForstnerForstnerTessierTessierForstnerBCR3Tessier4,BCRTessierBCRTessier,[11],BCRTessierBCR[12],,BCR,,,,;;;;,2.2,,,,,,,,,,[13]2.2.1(1)(GC)GC,,GC(2)(LC),,,,(HPLC)(3)2.2.2(1)(AAS)AASAASGC-AASHPLC-AASIC-AASAAS-MS(2)(AES)AES(DCP)(ICP)(MIP),3,DCP,ICP,MIP3,37,:(3)(AFS)AFS2.2.3ICP/MS,HPLC,(FPD),,GCDCPGCFPD/DCP,3,,,,TessierForstnerBCR,,1,..:,1992.2,,..:,1995.3KotA,NamiesikJ.Theroleofspeciationinanalyticalchemistry.TrendsinAnalysisChemistry,2000,19(2+3):694..:,1992.5QuevauvillerP.Requirementsforproductionanduseofcertifiedrefer2encematerialsforspeciationanalysis:AEuropeancommissionper2spective.SpectrochimicaActaPartB,1998,53:12616UreAM.Singleextractionschemesforsoilanalysisandrelatedappli2cations.TheScienceoftheTotalEnvironment,1996,178:37TessierA,CampbellPGC,BissonM,etal.Sequentialextractionpro2cedureforthespeciationofparticulatetracemetals.AnalyticalChem2istry,1979,51(7):8448ForstnerU.Metalpollutioninaquaticenvironment.SecondEdition,1981.9DavidsonCM,ThomasRP,McveySE,etal.Evaluationofase2quentialextractionprocedureforthespeciationofheavymetalsinsediments.AnalyticaChimicaActa,1994,291:27710UseroJ,GameroM,MorilloJ,etal.Comparativestudyofthreese2quentialextractionproceduresformetalsinmarinesediments.Envi2ronmentInternational,1998,24(4):48711,,,..,2005,24(8):72812ArunachalamJ,EmonsH,KrasnodebskaB.Sequentialextractionstudiesonhomogenizedforestsoilsample.SequentialTotalEnviron2ment,1996,181:14713,..:,2003,39(7):434STUDYONSPECIATIONANALYSISMETHODOFHEAVYMETALINSEDIMENTSFengSuping1,JuLi1,ShenYong1,QiuNa1,LiXin1,ZhuPeiming2,WangWei3(1.SchoolofEnvironment,ShandongUniversity,Jinan250100,China;2.ShandongGeologicalScientificExperimentResearchInstitute,Jinan250013,China;3.ZaozhuangEnvionmentalMonitoringStation,Zaozhuang277101,China)ABSTRACTGeneralsituationofheavymetalstudyinginsedimentsandrecentadvancesofheavymetalseparationmethodsandspeciationanalysismethodswerebrieflyintroduced.Speciationanalysisextractmethods,suchasTessiermethod,ForstnermethodandBCRmethodwerealsodescribedandcompared.KEYWORDSsediment,heavymetal,speciationanalysis,(UPOV)35,6DUS,19994UPOV,UPOV,,,UPOV,,,,14,;,62;80,DNA,,DUS,1000,180020066,3378,810()472006,15,4