臭氧催化氧化技术在废水处理中的研究进展

4612201712AppliedChemicalIndustryVol．46No．12Dec．20172017-05-312017-06-2615272615D1989－。[e-mail]。[e-mail]1121．0500182．050018。pH、、。。。TQ085+．4X703．1A1671－3206201712－2455－04ＲesearchprogressofozonecatalyticoxidationtechnologyinwastewatertreatmentGAOZi-xing1YANGWen-ling121．SchoolofChemicalandPharmaceuticalEngineeringHebeiUniversityofScienceandTechnologyShijiazhuang050018China2．HebeiKeyLaboratoryofMolecularChemistryforDrugShijiazhuang050018ChinaAbstractThemajorcategoriesofcatalyticozonationhavebeenintroducedtheapplicationandmecha-nismofhomogeneousozonecatalyticoxidationandheterogeneousozonecatalyticoxidationinwastewatertreatmentwasdescribedrespectively．TheeffectsofpHvalueozonedosagedosingmethodreactorcata-lystandreactiontemperatureonthecatalyticoxidationsystemofozonewereanalyzed．Accordingtotheproblemsinthetreatmentofwastewaterbycatalystsincatalyticozonationprocessthesuggestionofimpro-vingthepreparationofthecatalystispointedout．Specialcatalystswerepreparedaccordingtodifferentindustrialwastewaterandtheircombinationwithhighefficiencyreactorswillbethefuturedevelopmentdi-rectionofheterogeneouscatalyticozonationtechnology．Keywordsozonecatalyticoxidationcatalystwastewaterdegradation1-2。3-6。·OH7-9。10-12。。。1。Fe2+Mn2+Cu2+Co2+Ag+Ni2+Zn2+。131DOI:10.16581/j.cnki.issn1671-3206.20170928.01946。Tong14TiⅣH2O2/O3TiⅣH2O2Ti2O52+1～4Ti2O52++O3→O－31O3－+H3O－→H3O－+H2O2H3O·→O2+·OH3·OH+CH3COOH→……→CO2+H2O42。。Fe2+/H2O2/O3Fe2+H2O2O3、H2O2O3H2O2/O3、Fe2+/O3H2O2。215。。Zhao16LewisLewis。Legube17。。3。18。。Liu19Fe2O3CuOFe-Cu-OBCOD60%55%70%。。。、。20Fe“”。。33．1pHpH。O3H2O2/O3pHpHpHOH－OH－·OH。pH·OH。pH·OH5～6MeOH+OH－MeO－+H2OpH＞pHzpc5MeOH+H+Me2OH2+pH＜pHzpc6·OHpH。pHOH－·OHpHOH－654212·OH。Chen21FeOx/ACpHzpc=7．35pH=7COD。pH。pH。3．2、、。22Ni-Cu-Mn-K/AC6∶3∶1COD9%19%。。23。Zheng24--COD、NH3-NUV25425%9%35%。25-COD100%。BAF。3．3、、、。。Al2O3Al2O3γ-Al2O3θ-Al2O3α-Al2O326。。、27。11Al2O3。。。28CuO/ACCuO-CeO2/ACCODCrCuO/ACCu2+。。3．4729-30。。Zhuang3125℃COD。Chen32MnOx/AC/O30204060℃40℃COD52．1%。。。K=K0·expEa/ＲT74。1-。7542462。3。。1．CN102626629AP．2012-08-08．2．CN105080523AP．2015-11-25．3．J．201021001-1008．4ZhuangHFHanHJMaWCetal．AdvancedtreatmentofbiologicallypretreatedcoalgasificationwastewaterbyanovelheterogeneousFentonoxidationprocessJ．JournalofEnvironmentalScience20153312-20．5XuPHanHJZhuangHFetal．AdvancedtreatmentofbiologicallypretreatedcoalgasificationwastewaterbyanovelintegrationofheterogeneousFentonoxidationandbiologicalprocessJ．BioresourceTechnology2015182389-392．6LiangHZhouSChenYTetal．DiatomitecoatedwithFe2O3asanefficientheterogeneouscatalystfordegrada-tionoforganicpollutantJ．JournalofTaiwanInstituteofChemicalEngineers201549105-112．7．J．20143341010-1014．8．J．2014324176-180．9WangJLBaiZY．Fe-basedcatalystsforheterogeneouscatalyticozonationofemergingcontaminantsinwaterandwastewaterJ．ChemicalEngineeringJournal201731279-98．10．J．201446650-54．11．CN105289610AP．2016-02-03．12．CN105536813AP．2016-05-04．13．J．2016351263-268．14TongSPLiWWZhaoSQetalTitaniumⅣ-im-provedH2O2/O3processforaceticaciddegradationunderandacidconditionJ．OzoneScience＆Engineering2011336441-448．15HuELWuXBShangSMetal．Catalyticozonationofsimulatedtextiledyeingwastewaterusingmesoporouscar-bonaerogelsupportedcopperoxidecatalystJ．JournalofCleanerProduction20161124710-4718．16ZhaoLSunZMaJ．Novelrelationshipbetweenhydroxylradicalinitiationandsurfacegroupofceramichoneycombsupportedmetalsforthecatalyticozonationofnitroben-zeneinaqueoussolutionJ．EnvironmentalScience＆Technology200943114157-4163．17LegubeBKarpelVelLeitnerN．Catalyticozonationapromisingadvancedoxidationtechnologyforwatertreat-mentJ．CatalysisToday19995361-72．18．J．2017363944-950．19LiuXYZhouZMJingGHetal．CatalyticozonationofAcidBinaqueoussolutionoveraFe-Cu-OcatalystJ．SeparationandPurificationTechnology2013115129-135．20．J．2017681313-319．21ChenCMChenHSGuoXetal．Advancedozonetreat-mentofheavyoilrefiningwastewaterbyactivatedcarbonsupportedironoxideJ．JournalofIndustrialandEngi-neeringChemistry2014202782-2791．22．J．201121647-50．23．--J．2014853-58．24ZhengTLWangQHZhangTetal．Microbubbleen-hancedozonationprocessforadvancedtreatmentofwastewaterproducedinacrylicfibermanufacturingindustryJ．JournalofHazardousMaterials2015287412-420．25．-J．201781-9．26．Al2O3J．2006649889-893．27．J．20133212105-109．24628542463．GAPGAPJ．199419-16．4．D．2015．5WagnerＲIWilsonEＲGrantLＲetal．GlycidylazidepolymerandmethodofpreparationUS4937361P．1990-06-26．6．D．2015．7．GAPJ．20075516-23．8FlanaganJEWilsonEＲ．GlycidylazidepolymerestersUS4938812P．1990-07-03．9．GAPJ．20142177-181．10．THF/GAPD．2015．11．J．2013304374-377．12ByoungSunMin．CharacterizationoftheplasticizedGAP/PEGandGAP/PCLblockcopolyurethanebindermatricesanditspropellantsJ．PropellantsExplosivesPyrotech-nics2008332131-138．13SureshMManuSKVargheseTL．Thermomechanicalandmorphologicalcharacteristicsofcross-linkedGAPandGAP-HTPBnetworkswithdifferentdiisocyanatesJ．Pro-pellantsExplosivesPyrotechnics2010332146-152．14．GAP/HTPBJ．2010182167-173．15．GAPJ．2015467-70．16．GAPD．2011．17．、D．2013．18．J．2007154425-430．19．J．201512-4．20．J．19965281-283．21．GAPJ．2008165614-617．22．D．200