臭氧氧化法深度处理养猪废水研究

1009-6094201406-0153-05*361021、pHCOD、UV2543DEEMDOM。1.13g/h、20℃、pH7.240minCOD、UV25450%、95%75%。、。。X703.1ADOI10.13637/j．issn．1009-6094.2014.06.03501GB18596—2001《》COD。2.07V2。、、、3。45C/N。、pHCOD、、UV254DOM。11.1、、1。DHX-SS-1G。750mL5.6∶1。20℃、、。-1。1.2COD、、SS、6pHHACHHQ40d18HachUSA7UV254DＲ5000HachUSA。1.3200～600nm1nmOrigin8.0。1.43DEEM3DEEMF-4600FLSpectrophotometerHitachi。Ex200～400nm5nmEm200～500nm5nm。10nm1200nm/min700V。Milli-Q。3DEEMsOrigin8.0。*[e-mail]。2012BAJ21B072011BAC09B043502z201100051Fig．1Schematicdiagramofozonationapparatus351146201412JournalofSafetyandEnvironmentVol．14No．6Dec．201422.12.1.11.13g/hpH7.220℃2。10minUV25410min20min。、8。UV2549。5UV254。0.85。10minCOD22%。。10minCOD·OH。COD10minCO2－3HCO－3CO2－3HCO－3·OH10。40minCODCOD65mg/L。40min。UV254、COD75%、95%50%。2.1.240minpH7.220℃0.50g/h、0.75g/h、1.13g/h、2.00g/h2.50g/h3。0.50g/h1.13g/hCOD41.54%47.90%UV25473.98%78.6%。·OH11。UV254COD。UV254COD1.13g/h。40min1Table1CharacteristicsofthewastewaterCOD/mg·L－1138～147456nm350～450SS/mg·L－118～30NH+4-N/mg·L－140～45NO－3-N/mg·L－1250～270pH7.0～7.3UV2541.34～1.36、UV254COD。3。2.1.340min、1.13g/hCOD50%1gCOD7.28g121gCOD0.86g。。。COD。2.2pHpH5、9pHpH=7.240min20℃1.13g/hpHpH=5、9、7.24。CODUV254pHpHCODUV25413。pH·OH·OH14。pH57.2UV254CODpH9pH9pH7.2。2Fig．2Effectofreactiontimeontheremovalrate3Fig．3Effectofozoneflowingrateontheremovalrate451Vol．14No．61462.32.3.15。200～600nm21220～240nm2280～310nm。1π－ππ－π*152、。2。2.3.26a43DEEM。A、BC3、16。17。ABC4pHFig．4EffectofpHvalueontheremovalrate。f450/50018。f450/500Ex370nmEm450nm500nmFI。2f450/5001.41.919。f450/5001.88。6b1.13g/h40min43DEEM。。Ex、EmFI2。25Fig．5UV－Visabsorptionspectraofswinewastewaterbeforeandafterozonation63DEEMFig．63DEEMofswinewastewaterbeforeandafterozonation551201412Dec．2014ExEmnm20-22。、FＲI3DEEM23。FＲIPFＲ。FＲI7。ⅡPFＲ11.69%1.34%PFＲ23.12%6.64%PFＲ18.16%10.26%。2Table2PositionandintensityoffluorescencepeaksofthewastewatersamplesbeforeandafterozonationAEx/nm/Em/nmFIBEx/nm/Em/nmFI325/4109226.6250/4359482.8295/400860.1235/435692.27FＲIFig．7FＲIdistributionofwastewaterbeforeandafterozonation340min、1.13g/h、20℃、pH7.2COD、UV25450%、95%75%。、COD。Ｒeferences1ANDＲEOTTOLAGBOＲTONEGTILCHEA．Experimentalvali-dationofasimulationanddesignmodelfornitrogenremovalinse-quencingbatchreactorsJ．WaterScienceandTechnology1997351113-120.2CHOIJSONGHKLEEWetal．ＲeductionofCODandcolorofacidandreactivedyestuffwastewaterusingozoneJ．KoreanJournalofChemicalEngineering2004212398-403.3HOUSHYAＲZKHOSHFETＲATABFATEHIFAＲE．Influenceofozonationprocessoncharacteristicsofpre-alkalizedtanneryefflu-entsJ．ChemicalEngineeringJournal201219159-65.4CHENJianpingWANGShuWANGDaohanetal．OnaimprovedtreatmentofpapermakingsewagecooperatedwithozoneadvancedoxidationJ．JournalofSafetyandEnvironment201212172-75.5ZHENGKeZHOUShaoqiYEXiuyaetal．DegradationofconcentratedleachateofreverseosmosisbyozonationJ．ChineseJournalofEnvironmentalEngineering201262467-470.6StateEnvironmentalProtectionAdministrationofChina．MethodofwaterandwastewaterinspectionandanalysisM．4thed．BeijingChinaEnviron-mentalSciencePress2002.7CJ/T3028.2—94Themeasuresofozoneconcentrationoutputandspecificeneryconsumptionforozonegenerator、、S．8MOＲAESSGDFＲEIＲEＲSDUＲáNN．Degradationandtoxic-ityreductionoftextileeffluentbycombinedphotocatalyticandozo-nationprocessesJ．Chemosphere2000404369-373.9LIAOＲihongSHENYingjieZHANNanetal．ＲesearchontheeffectsofozonationondissolvedorganicmatterinthepollutedsurfacewaterJ．Water＆WastewaterEngi-neering2011373127-132.10HOIGNEJBADEＲH．TheroleofhydroxylradicalreactionsinozonationprocessesinaqueoussolutionsJ．WaterＲesearch1976105377-386.11VALDéSHZAＲOＲCA．Heterogeneousandhomogeneouscata-lyticozonationofbenzothiazolepromotedbyactivatedcarbonki-neticapproachJ．Chemosphere20066571131-1136.12MAJingMAIWenningWANGJuan．Experimentalresearchontheadvancedtreatmentoffiberboardpro-ductionwastewaterbyozonationprocessJ．EnvironmentalPollu-tion＆Control201032955-57.13SEVIMLIMFSAＲIKAYAHZ．Ozonetreatmentoftextileefflu-entsanddyeseffectofappliedozonedosepHanddyeconcen-trationJ．JournalofChemicalTechnologyandBiotechnology2002777842-850.14PＲEETHIVPAＲAMAKALYANIKSLYAPPANKetal．OzonationoftanneryeffluentforremovalofcodandcolorJ．JournalofHazardousMaterials20091661150-154.15TANGHuitong．SpectroscopicidentificationoforganiccompoundM．BeijingPekingUni-versityPress1992195.16WANGZWWUZCTANGSJ．Characterizationofdissolvedorganicmatterinasubmergedmembranebioreactorbyusingthree-dimensionalexcitationandemissionmatrixfluorescencespectrosco-pyJ．WaterＲesearch20094361533-1540.17ZHUZhaolianSUNMinWANGHailingetal．PretreatmentoflandfillleachatebyFentonprocessJ．EcologyandEnvironmentalSciences201019102484-2488.18WOLFEAPKAUSHALSSＲOBINJetal．Spectrofluores-cenceofsedimenthumicsubstancesandhistoricalchangesofla-custrineorganicmatterprovenanceinresponsetoatmosphericnu-trientenrichmentJ．EnvironmentalScience＆Technology200236153217-3223.19WANGLishaHUHongyingKOICHIFujie．CharacterizationofthechangeinDOMduringwastewaterchlorineandchlorinedioxidedisinfectionsby3DEEMJ．EnvironmentalScience20072871524-1528.20S＇WIETLIKJDABＲOWSKAAＲACZYK-STANISLAWIAKU651Vol．14No．6146etal．Ｒeactivityofnatu