导电聚苯胺共混物和复合物的合成及应用

(417~421)杨庆浩,井新利,王杨勇(,710049):,:;;;:TQ324.8:A:1009-0045(2002)06-0417-05,Cao[1-4],,,:(1),;(2),-;(3)-[1-3],Anand[4]:-,,;(),,16%,,,16%,,11.1:(1);(2);(3);(4);(5);(6);(7)Pinho[5](1)();Oh[6-7](4),10-5~10-2ScmCadenas[8]-PMMA-PVK,(,)5%,,-CuS40%(w)Ruckenstein[9](PS),,2%~10%()3~5Scm-PS,[3],:2002-03-25;:2002-08-14:(:59903005):(1977-),,,,206200211PetrochemicalTechnology&ApplicationVol.20No.6Nov.2002,Su[10](DBSA),PVADBSAFaez[11]DMF,-Hydrin-C,2%(w),9.1%,Haba[12]PAn-DBSAPMMA,,PAn-DBSA0.5%,10-6Scm(),-PMMA-PS[4],-,,Ikkala[13]DBSAPAn(DBSA)x(xDBSA)SBS190PAn(DBSA)xSEBS,:x=0.5,(,)10%,,20%~30%,10-6Scm;x=2.0,10%,10-4Scm;x1.52.0,xPAn(DBSA)x,PAn(DBSA)0.530%,,;,250%,PAn(DBSA)2.0,Nechtschein[14]3%()0.51.2,123(),,,1.2.1,AgAgCl+0.75~+0.8V[15],0.6V(SCE,),,,0.9V,,,0.65~0.8V1.2.2,Bi[16](,PPDTA),PPDTApH2pH[17],-PVA[HClO4]=0.75molL,0.18Scm1.2.3-Park[18],1!1,-0.2~1.0V,50mVs,60min10-1Scm,,Choi[19]∀418∀20Xie[20]2-SBS,7%,10%22.1,(10-3~10-1)(10-6~50Scm),,Cheguettine[21]-SSA:,[22](--)(P(BSH)),AnP(BSH)0.1!1.00.2!1.0,5#10-2Scm8Scm;An,,P(BSH),0.1!1.05.4MPa1.0!1.00.7MPa,658%70%;,,m[An]!m[(NH4)2S2O8]=1!2.5,,2.2,(100),61550%[23];200,600,Jang[24]N-(NMP)-,NMP300,,,,,,,2.3-:320nm635nm∃*∃*,,,635nm,2,430800nm,PMMA,425nm600nm-,,pH,,pH,,[17]-PVA1560cm-11482cm-12,C=C,;PVA2.4,,-2:0.13V0.68V(SCE)Gurunathan[25]-TiO20.1molL,20.14V0.63V(SCE),0.15V0.64V,,0.14V,;TiO2,,TiO20.63V,0.48V2.5,∀419∀6,,,,(),33.1,,,DHAWAN[26]DBSASBS-,10-5molL,103~1011,3.2,,[27]-;-WO3,,UNIX2~3V,,1s,106,31%~80%,%&3.3,,,106~107UNIX[28]13.37dB,26.7dB,0.7gcm3,10.34~1400GHzKoul[29]-ABS60dB,PVCPMMA40~75dB80-100dB,,,,[4-5,28]4,,,,,,,-,,:[1]CAOYong,SMITHP,HEEGERAJ.Counter-ioninducedprocessibilityofconductingpolyanilineandofconductingpolyblendsofpolyanilineinbulkpolymers[J].SyntheticMetals,1992,48(1):91-97.[2],,,.[J].,1996,30(4):447-451.[3]WESSLINGB.Polyanilineonthemetallicsideoftheinsulator-to-metaltransitionduetodispersion:thebasisforsuccessfulnano-technologyandindustrialapplicationsoforganicmetals[J].SyntheticMetals,1999,102(1-3):1396-1399.[4]ANANDJ,PALANIAPPANS,SATHYANARAYANADN.Conductingpolyanilineblendsandcomposites[J].ProgressinPolymerScience(Oxford),1998,23(6):993-1018.[5]PINHOMS,DEZOTTIM,CORELOVAMMElectroconductingcompositesbasedonpolyanilineandmonomer-swollenpolychloroprene[J].JournalofAppliedPolymerScience,1999,71(14):2329-2334.[6]OHKW,HONGKH,KIMSH.Electricallyconductivetextilesbyinsitupolymerizationofaniline[J].JournalofAppliedPolymerSci∀420∀20ence,1999,74(8):2094-2101.[7],,,.[J].(),2000,132(4):80-83.[8]CADENASJL,HUH.Chemicallystableconductingpolyanilinecompositecoatings[J].SolarEnergyMaterialsandSolarCells,1998,55(1-2):105-112.[9]RUCKENSTEIUE,YANGShiyong.Emulsionpathwaytoelectricallyconductivepolyaniline-polystyrenecomposites[J].SyntheticMetals,1993,53(3):283-292.[10]SUShiJian,KURAMOTO,NORIYUKI.Synthesisofprocessablepolyanilinecomplexedwithanionicsurfactantanditsconductingblendsinaqueousandorganicsystem[J].SyntheticMetals2000,108(2):121-126.[11]FAEZR,GAZOTTIWA,DEP,etal.Marco-A.Elastomericconductorbasedonpolyanilinepreparedbymechanicalmixing[J].Polymer,1999,40(20):5497-5503.[12]HABAY,SEGALE,NARKISM,etal.Polyaniline-DBSApolymerblendspreparedviaaqueousdispersions[J].SyntheticMetals,2000,110(3):189-193.[13]IKKALAO,TIITUM,TANNERJ.Blendsofthermoreversiblegelsofpolyanilinewiththermoplasticelastomers:Co-continuousmeltprocessiblepolymerstructures[J].SyntheticMetals,1999,102(1-3):1248-1249.[14]NECHTSCHEINM,RANNOUP,PRONA,etal.Preparationoflowdensitypolyethylene-basedpolyanilineconductingpolymercompositeswithlowpercolationthresholdviaextrusion[J].SyntheticMetals,1998,93(3):169-173.[15],,.PAn[J].,1998,10(2):133-137.[16]BIXiantong,XUEZhejian.Electricallyconductivecompositeofpolyanilineandpoly(p-phenylenediphenylether-terephthalamide)[J].PolymerInternational,1991,26(3):10-14.[17],,.[J].,2000,21(1):53-55.[18]PARKYH,PARKCR.Preparationofconductingpolyacrylonitrilepolyanilinecompositefilmsbyelectrochemicalsynthesisandtheirelectroactivity[J].SyntheticMetals,2001,118(1-3):187-192.[19]CHOIHJ,LeeYH,KIMCA,etal.Microencapsulatedpolyanilineparticlesforelectrorheologicalmaterials[J].JournalofMaterialsScienceLetters,2000,19(6):533-535.[20]XieHongquan,MaYongmei,GuoJunshi.Conductivepolyaniline-SBScompositesfrominsituemulsionpolymerization[J].Polymer,1999,40(1):261-265.[21]CHEGUETTINEY,BANKAE,PLANSJ.Transportmechanismsinpolyaniline(phenylphosphonicacid)celluloseacetateblends[J].SyntheticMetals,1999,101(3):787-788.[22],,,.()[J]..1999,16(1):92-94.[23]DINGL,WANGX,GREGORYRV.Thermalpropertiesofchemicallysynthesizedpolyaniline(EB)powder[J].SyntheticMetals,1999,104(2):73-78.[24]JANGSH,HANMG,IMSS.Preparationandcharacterizationofconductivepolyanilinesilicahybridcompositespreparedbysolgelprocess[J].SyntheticMetals,2000,110(1):17-23.[25]GURUNATHANKaruppasamy,TRIVEDIDineshChandra.StudiesonpolyanilineandcolloidalTiO2composites[J].MaterialsLetters,2000,45(5):262-268.[26]DHAWANSK,KUMARD,RAMMK,etal.Applicationofconductingpolyanilineassensormaterialforammonia[J].SensorsandActuatorsB:Chemical,1997,B40(2-3):99-103.[27],.∋∋∋[J].,2000,14(1)