沸石在氨氮废水处理中的应用进展尚会建95672b10bdd126fff705cc17552707

Jan．2013331ModernChemicalIndustry2013112222222*(1．天津大学化工学院，天津300192;2．河北科技大学化学与制药工程学院，河北石家庄050018)。、。X703A0253－4320201301－0026－04ApplicationprogressofzeoliteinremovalofammoniafromwastewaterSHANGHui-jian12ZHOUYan-li2ZHAOYan2ZHAODan2ZHANGShao-hong2ZHANGGao2ZHENGXue-ming2*1．CollegeofChemicalTianjinUniversityTianjin300192China2．CollegeofChemicalandPharmaceuticalEngineeringHebeiUniversityofScienceandTechnologyShijiazhuang050018ChinaAbstractBio-zeolitetechnologyiscapableofbufferingshockloadswell．Itcanbeusedinadvancedwastwatertreatmentincombinationwithotherprocesstoremovevariouskindsofnitrogeninthewastewatereffectivelyandcanberecycled．Theprincipleofammonia-nitrogenremovalbyzeoliteanditsregenerationmechanismarebrieflyintroduced．Theapplicationsofnaturalzeolitemodifiedzeoliteandbio-zeoliteinremovalofammoniafromwastewaterbothinChinaandabroadaresummarized．Thepotentialvalueofzeoliteintreatmentofammonia-nitrogenwastwaterisprospected．Keywordsnaturalzeolitemodifiedzeolitebio-zeolitewastewatertreatmen[e-mail][e-mail]。。1。。5mg/LDB32/1072—2007。。。、。1756CronstedAF、、、、、。。“”NH3－N。、Cs+＞Rb+＞K+＞NH+4＞Sr2+＞Na+＞Ca2+＞Fe3+＞Al3+＞Mg2+＞Li+2。NH+4。。10.4nmNH+40.286nm3。Zn－·Mn++nNH+←→4Zn－·nNH+4+Mn+Zn－Mn+n。·62·DOI:10.16606/j.cnki.issn0253-4320.2013.01.031201313。1H2SO4、HCl、HNO3、NaOH、NaClNH+4Z－+X→－X+Z－+NH+4ZXNaH。2300～600℃。3。NH+4。。22.1NH+44Ca2+、Mg2+5。Sarioglu6。1、Gholamreza7Langmuir8.29mg/g。85mg/L。Weatherley980mg/L。、、、10。11－13。。2.214－15。、、。、、、櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆(上接第25页)13FengLLiSLiHetal．Super-hydrophobicsurfaceofalignedpoly-acrylonitrilenanofibersJ．AngewandteChemie200214471269－1271．14FengLSongYZhaiJetal．Creationofasuperhydrophobicsur-facefromanamphiphilicpolymerJ．AngewandteChemie20031157824－826．15．J．2008661145－148．16NakajimaAAbeKHashimotoKetal．Preparationofhardsuper-hy-drophobicfilmswithvisiblelighttransmissionJ．ThinSolidFilms20003761/2140－143．17XieQDXuJFengLetal．Facilecreationofasuper-amphipho-biccoatingsurfacewithbionicmicrostructureJ．AdvancedMate-rials2004164302－305．18OnerDMcTJ．UltrahydrophobicsurfacesEffectsoftopographylengthscalesonwettabilityJ．Langmuir200016207777－7782．19KietzigAMHatzikiriakosSGEnglezosP．Patternedsuperhydro-phobicmetallicsurfacesJ．Langmuir20092584821－4827．20PengYTLoKFJuangYJ．Constructingasuperhydrophobicsur-faceonpolydimethylsiloxaneviaspincoatingandvapor-liquidsol-gelprocessJ．Langmuir20102675167－5171．21．/J．200634755－62．22LauKKSBicoJTeoKBKetal．SuperhydrophobiccarbonnanotubeforestsJ．NanoLetters20033121701－1705．23LiuHFengLZhaiJetal．Reversiblewettabilityofachemicalva-pordepositionpreparedZnOfilmbetweensuperhydrophobicityandsuperhydrophilicityJ．Langmiur200420145659－5661．24MaMMaoYGuptaMetal．SuperhydrophobicfabricsproducedbyelectrospinningandchemicalvapordepositionJ．Macromole-cules200538239742－9748．25IslamMSAkterNKarimMR．PreparationofsuperhydrophobicmembranesbyelectrospinningoffluorinatedsilanefunctionalizedpullulanJ．ColloidsandsurfacesAPhysicochemicalandEngi-neeringAspects20103621/2/3117－120．26LimJMYiGRMoonJHetal．Superhydrophobicfilmsofelec-trospunfiberswithmultiple-scalesurfacemorphologyJ．Lang-muir200723157981－7989．27MingWWuDBenthemRVetal．Surperhydrophobicfilmsfromraspberry-likeparticlesJ．NanoLetters20055112298－2301．28ShangHMWangYLimmerSJetal．Opticallytransparentsuper-hydrophobicsilica-basedfilmsJ．ThinSolidFilms20054721/237－43．29XuBCaiZSWangWMetal．PreparationofsuperhydrophobiccottonfabricsbasedonSiO2nanoparticlesandZnOnanorodarrayswithsubsequenthydrophobicmodificationJ．SurfaceandCoatingsTechnology20102049/101556－1561．30ZhangYAYuXQZhouQHetal．Fabricationofsuperhydropho-biccoppersurfacewithultra-lowwaterrollangleJ．AppliedSur-faceScience201025661883－1887．■·72·331、。14HCl、H2SO4HNO3。16pHHNO3、H2SO4、H3PO4。pH。pHH2SO4HNO3。H3PO4pH。172.51mg/L1g/L70.8%。14NaOH1mol/L0.65mg/g2.82。14NaClKClCaCl2。NaCl3～4NaCl150g/L18h0.88mg/g3.84。18、NaCl0.8mol/LNaClNH+40.84mg/g。19。20NaCl、。NaClNaClNaCl+NaOH89W4minNaCl10%。21300℃24h。3.47mg/g91.55%。。。2.3Tsuno1994“”。。。、。22。、、、、。2324。Miladinovic25。26－－SBRSBBR2NH+4－N、COD、NO3－NTNGB5749—2006。27PVCNH+4－N。NH+4－N2mg/L90%。28－29。。。·82·20131。3。1/5。、。。。、。1．D．2009．2．J．20062689－12．3．J．20092965－9．4WangShaobinPengYuelian．Naturalzeolitesaseffectiveadsor-bentsinwaterandwastewatertreatmentJ．ChemicalEngineeringJournal2010156111－24．5RahelehMalekianJahangirAbedi-KoupaiSayedSaeidEslamianetal．Ion-exchangeprocessforammoniumremovalandreleaseu-singnaturalIranianzeoliteJ．AppliedClayScience2011513323－329．6SariogluM．RemovalofammoniumfrommunicipalwastewaterusingnaturalTurkishDogantepezeoliteJ．SeparationandPurifica-tionTechnology20054111－11．7GholamrezaMoussaviSadeghTalebiMehrdadFarrokhietal．Theinvestigationofmechanismkineticandisothermofammoniaandhumicacidco-adsorptionontonaturalzeoliteJ．ChemicalEngi-neeringJournal201117131159－1169．8．J．201041147－49．9WeatherleyLRMiladinovicND．ComparisonoftheionexchangeuptakeofammoniumionontoNewZealandclinoptiloliteandmorde-niteJ．WaterResearch200438204305－4312．10．J．20103312206－209．11SprynskyyMLebe