高级氧化技术在废水处理中的研究进展

FentonAbstract:AdvancedOxidationProcessisapopularresearchtopicinthefieldwatertreatment.Inthispaper,AdvancedOxidationProcess,suchaschemicaloxidation,photochemicaloxidationwetoxidation,supercriticalwateroxidationsweresummarizedindetail,andthereresearchandapplicationaspectsinthefieldwatertreatmentwerealsoillustrated.KeyWords:watertreatmentadvancedoxidationprocessAdvancedOxidationProcess,AOPsGlazeW.H.1987AdvancedOxidationProcessesAOPs,AdvancedOxidationTechnologies,AOTs[1],(OH),1Fenton1.1O?ClO295%COD90%85%pH=10NaClO18,30,30,100%[2]1.2FentonFentonH2O2-OHFentonFentonFentonFenton1.2.1FentonFe2+,,Fe2+HOPH3Fe(OH)?1.2.2FentonFentonFe2+HOFentonO2HO?HOFe2+OHFe3+Fe3+Fe2+FeFe2+FentonFentonFentonFenton4-4-50mg/LPH4.515.38A/m24-85.70%[3]1.2.3FentonFentonFentonFentonFe2+H2O2Fe2+H2O2UV/Fe(C2O4)33-/H2O2UV10min99%[4]1.31.3.11.3.2Cl-ComninellisTi/IrO2,NaClCo3+/Co2+,Fe3+/Fe2+,Ag2+/Ag+1.4UV/H2O2UV/O2UV/H2O2/O2[5]UV/O2[6]2hCCl490%[7]UV/O?[8]Fe2+Fe3+H2O2OH[8]1.5[9]70CWAO[10-11]1.6SCWOSCWOSCWOSWCO[12-13]1.7Mason[14]??Young-PHDO-Astrid[15]CCl4[16-17]Rkidak[18]O3USUVO3USUV/USO3UV/USO3USUVVSdez[19]NareshKazuhiko1.8NathalieEricko310?mol-1?s-1kOH109?mol-1?s-1[20]BassamKunpingMarcoH2O21.9PDP[21]2[1][J]..2001613-15.[2]..[J].200524425-27.[3][4].UV/Fe(C?O?)?/H?O?[D].:.1999:55.[5]StevenT,Summerfelt.OzonationandUVIrradiationanIntroductionandExamplesofCurrentApplications[J],AquacuralEngineering,2003,28:2136.[6][M].2001.1278.[7].UVO?CCl?[J].19971425456.[8][J].200031719.[9]LaurentBromet[J].2005.196551556[10].[J].20053057980[11][J].2004243326331.[12].[J].20052513336.[13].[J]2003424143.[14].[J].2008207/8:1187-1195.[15]AstridReborek,MichaelTauber,GeorgGubitz.Applicationofpowerultrasoundforazodyedegradation[J].UltrasonicsSonochemistry,2004,11(3-4):177-182.[16].[M].2006,5-7:162-165.[17].[J].2006,71051-54.[18]RKidak,NHInce.Catalysisofadvancedoxidationreactionsbyultrasound:Acasestudywithphenol[J].ournalofHazardousMaterials,2007,146(3):630-635.[19]VSdezMDEsclapezPBoneteetal.Sonochemicaldegradationofperchloroethylenetheinfluenceofultrasonicvariablesandtheidentificationofproducts[J].UltrasonicsSonochemistry,2011,18(1):104-113[20].[J].2009,35318-22.[21]DanielGerrityBenjaminDStandfordRebeccaATrenholmetal.Anevaluationofapilot-scalenonthermalplasmaadvancedoxidationprocessfortraceorganiccompounddegradation[J].WaterResearch,2010,44(2):493-504.