高级氧化技术在水处理的研究进展刘晶冰

。。、、。。AdvancedoxidationprocessesAOPs、、·OH2.80VF22.87V1。CO2H2O[1]。1FentonFenton23456。11.1FentonFenton1894FentonFe2+H2O2。FentonFenton[2]。1964FentonFenton[3]。FentonFe2+H2O2·OH[4]。·OH。Mandal[5]Fenton。H2O2/FeSO4。Fe-SO46mg·L-1H2O244.4mg·L-124hCOD60%H2O2277.7mg·L-1COD95%。Fenton。pHFe2+COD。、、FentonFe2+。Fenton。Fenton。1Tab.1CommonoxidantredoxpotentialF2·OHO3H2O2MnO2Cl2O22.872.802.071.771.681.361.231121211.1001242.101100)AOPs。FentonFenton、、、、、。·OHAOPs。、、AOPs。X703.1A1000-3770(2011)03-0011-0072010-05-19[2008][e-mail][e-mail]37320113TECHNOLOGYOFWATERTREATMENTVol.37No.3Mar.,201111DOI:10.16796/j.cnki.1000-3770.2011.03.003Tony[6]FentonUV。CODFenton42%Fenton/UV50%。Yang[7]Fenton。300W6minpH=4.42H2O2Fe2(SO4)1300mg·L-14900mg·L-1CODUV25457.53%55.06%BOD5/COD0.1650.470。FentonFe2+。Fe2+。Luo[8]Fe-AlFenton。Fenton。Chen[9]FeFe-MtX-GN。30℃140minpH=3.0H2O2Fe-Mt4.9mmol·L-10.6mg·L-198.6%TOC52.9%Fe-Mt1.26%。Fenton。、。Fenton。。Fenton、、Fenton。FentonFenton。1.2H2O2、ClO2、O3·OHCO2、H2O。、、、[10]。Rao[11]O3/UVUV3.52.5。UVTOC100minTOC15%。O3/UV100min80%。Ahmed[12]UV-H2O2。H2O2210mg·L-1UV254nm5h28℃pH=11.25CODTOC92%90%UVH2O2。UVH2O2·OH。。。。OH-H2O·OHO2·O2-·OH·O2-CO2、H2O[10]。TiO2、ZnO、WO3、CdS、ZnSSnO2[4]。TiO2、[10]。Wang[13]TiO2。TiO2800mg·L-1、25℃、pH=2、UV10min47.9%。TiO2。。TiO2。Wang[14]-TiO2。25℃TiO2100mg10min89.5%。25℃TiO2150mgpH=675.2%。TiO2TiO2。TiO2。TiO2[15]。Chen[16]-TiO2/AC。7g·L-17hCOD64.30%。TiO2。TiO2TiO2TiO2。Pan[17]AuTiO270minAuTiO23731294%TiO21.7。Zhou[18]N-ITiO2。N-ITiO22h96.3%。4hCOD41.7%。。。。1.3O3。O32.08V1O3、。·OH。·OH。O3·OH3O3/UV[19]。Somensi[20]。pH=3.04hCOD40.6%18.7%。pH=9.14hCOD67.5%25.5%。BOD/COD0.060.41。O3、O3。UV/O3、O3/H2O2、UV/O3/H2O2。。Rajeswari[21]O3、O3/UV、TiO2/UVTiO2/UV/O3。TiO2/UV/O3。pH=6O30.28g·h-1TiO21g·L-1CODTOC92%76.5%BOD5/COD0.38。Moussavi[22]。pH=820g·L-110min1150mg·L-1100mg·L-191%。COD2600mg·L-1600mg·L-177%。。。O3O3O3O3、、O3。1.4·O2、H2O2、·OH。。、、、[23]。Zhu[24]。20～60mA·cm-2pH=3～1120～60℃。TOCNH3-NSnO2PbO2。Radha[25]。pH=1.328mA·cm-2COD、、、TOC68%、49.2%、50.7%、96.8%。60min96%。Panizz[26]。pH=6.46min2mA·cm-2COD75%0.14kWh·m-3。10mA·cm-21.5hCOD97%12kWh·m-3。。Yang[27]TiSnO2、Sb2O3、Nb2O5PbO5。0.5g·L-120℃pH=7.020mA·cm-2120min78.6%。Chen[28]SbCeSnO2SnO2-Sb-CeSbSnO2-Sb。Ti/SnO2-Sb-Ce。135.4A·h-1·L-125℃Ti/SnO2-SbIICOD52%Ti/SnO2-Sb-CeCOD100%。。、、、。、、。。1.5WAO。125～320℃、0.5～20MPaO3、H2O2CO2H2O。WAOFJZimmerman19441958[4]。90WAO、、[29]。、。Katsoni[30]WAO。100%90%TOC70%。Suárez-Ojeda[31]WAO。15MPa180℃220℃TOC19%47%。、、70CWAO。WAO[4]。Ji[32]Pt/Al2O3CAWO。CWAOWAO44%～98%COD60%～79%CWAOWAO。CWAO、。[33]。。、。、[34]。ARodríguez[35]CuCu/CNFCWAO。140℃0.87MPa180minTOC97%74.1%。Ersoz[36]-Co3O4/CeO2。150℃400kPa2h0.5g·L-135.15%。34.94%Co3O4/CeO2。、。1.6SWOModell[37]。374.3℃22.05MPa。、O2、N2、。99%CO2H2O[19]。Cui[38]SCWO。703K25MPa427%10minCOD92%。Gong[39]H2O2SC-WO。28MPa723K34.3sCOD99%。SCWO。SCWO。。Cr、Mn、Fe、Co、Ni、CuPt[19]。。Angeles-hernández[40]MnO2/CuO。673K23MPa0.3mmol·L-1TOC99%98%。¨37314MnO2/CuOTOC40%25%。Kim[41]Ce0.65Zr0.35O2。150℃3h64%TOC22%。Ce0.65Zr0.35O2TOC46%40%。CuOxCe0.65Zr0.35O245min。MnOxCe0.65Zr0.35O2TOC3h94%。CuOxMnOxCe0.65Zr0.35O2TOC80%。。20。SCWO。SCWO。2AOPs、。AOPs、。AOPs。、AOPs、、、AOPs。AOPS。AOPs。。1。·OH·OH。2、。H2O2、O3、ClO2。3。、、、。、、。4。。、、。5。、、、AOPs。UV/H2O2/O3AOPs。6。、。[1]PoyatosJM,AlmecijaMC,TorresJC,etal.Advancedoxidationprocessesforwastewatertreatment:ttateoftheart[J].WaterAirSoilPollut.,2010,205(1-4):187-204.[2],,.Fenton[J].,2009,35(2):13-19.[3].Fenton[J].,2009,24(2):30-34.[4],.[M].:,2002.[5]MandalT,MaityS,DasguptaD,etal.Advancedoxidationprocessandbiotreatment:theirrolesincombinedindustrialwastewatertreatment[J].Desalination,2010,250(1):87-94.[6]TonyMA,PurcellPJ,ZhaoYQ,etal.Photo-catalyticdegradationofanoil-wateremulsionusingthephoto-Fentontreatmentprocess:effectsandstatisticaloptimization[J].JournalofEnvironmentSci-enceandHealth,PartA,2009,44(2):179-187.[7]YangYu,WangPeng,ShiShujie,etal.MicrowaveenhancedFen-ton-likeprocessforthetreatmentofhighconcentrationpharmaceu-ticalwastewater[J].JournalofHazardousMaterials,2009,168(1):15238-245.[8]LuoMingliang,BowdenD,BrimblecombeP.CatalyticpropertyofFe-AlpillaredclayforFentonoxidationofphenolbyH2O2[J].Ap-pliedCatalyticB:Environmental,2009,85(3-4):201-206.[9]ChenQiuqiang,WuPingxiao,LiYuanyuan,etal.Heterogeneousphoto-FentonphotodegradationofreactivebrilliantorangeX-GNoveriron-pillaredmontmorilloniteundervisibleirradiation[J].JournalofHazardousMaterials,2009,168(2-3):901-908.[10],,.[J].,2008,34(2):5-8.[11]RaoYF,ChuW.Anewapproachtoquantifythedegradationki-neticsoflinuronwithUV,ozonationandUV/O3processes[J].Chemosphere,2009,74(11):1444-1449.[12]AhmedB,MohamedH,LimemE,etal.Degradationandmineral-izationoforganicpollutantscontainedinactualpulpandpapermillwastewatersbyaUV/H2O2Process[J].IndEngChemRes.,2009,48(7):3370-3379.[13]WangShuqin,JiaoKunling,ZhangJinghong,etal.Researchonthechloridetreatmentfromdesulphurizationwastewaterbynano-TiO2[C].BioinformaticsandBiomedicalEngineering,Beijing:2009:1-4.[14]WangShuqin,ZhangXiaojie,ZhangJinghong,etal.ResearchontheTreatmentfordesulphurizationwastewaterbynano-titaniumdioxide[C].BioinformaticsandBiomedicalEngineering,Shanghai