高级氧化与生物联用技术处理制药废水的研究申晓辉

*122223141110024100823410200。。、。InvestigationonAdvancedOxidation－BiologicalProcessesinPharmaceuticalWastewaterTreatment*SHENXiao－hui1SHENTing－ting2LIXiao－ming2YUEXiu2LIUXian2TANGYu－fang31PharmacyDepartmentXiangtanCentricHospitalHunanXiangtan4111002CollegeofEnvironmentalScienceandEngineeringHunanUniversityHunanChangsha4100823BureauofEnvironmentalProtectionofWangchengDistrictHunanChangsha410200ChinaAbstractPharmaceuticalindustrialwastewatercontainedhighconcentrationoforganicmattersandwascharacterizedbyextremelypoorbiodegradabilityandtoxicity．AlthoughadvancedoxidationprocessesAOPsusedinthepharmaceuti-calwastewatertreatmentwasgenerallyatthebatchexperimentstageyetithadbrightapplicationprospectincombiningwithbiologicaltreatment．Theelaborationoftheprincipleandcharacteristicsofvariousadvancedoxidationprocessesaswellasthepresentsituationwerefocusedonandtheexistingproblemsandfuturedevelopmentdirectionofadvancedoxi-dation－biologicalprocessesinpharmaceuticalwastewatertreatmentwerediscussed．Keywordspharmaceuticalwastewateradvancedoxidationprocessesbiologicaltreatmentapplication*No51078128。1978－。1966－。、、。、、CODBOD5/CODNH3－N1－4。、、。AdvancedOxidationProcessesAOPs、、、5－6。。1、1．1Fenton/FentonFenton、、7－9。FentonFe2+H2O2pH·OH·OH。FentonFentonFentonUV/Fenton、Fe3+/H2O2、UV/H2O2/Fenton。1．1．1Fenton/FentonMohamed10COD13023mg/L4100mg/L。·1·20113918COD51%56%TOC48%36%FentonCOD92．07%99%。11－FentonFentonFenton。FentonFe3+Fe2+Fe2+H2O2－FentonCODFenton。COD70%BOD5/COD00．41。12“Fenton+”FentonCOD87%CODBOD5132mg/L52mg/L。3．0～3．5/t。13SBRCOD7300mg/L120minCOD65．3%BOD5/COD0．140．22。FentonSBRCOD500mg/L。1．1．2Fenton/Fenton14++Fenton+BOD5/COD0．38～0．42“+”COD16800～24300mg/L1000mg/LBOD5100mg/LCOD94%BOD5/COD0．1Fenton+COD73%COD、BOD5267mg/L30mg/L。Fenton。JosianiBerto15FentonCODBOD5。16FentonCOD89．5%COD66mg/L。FentonpHpH。Fe2+。Fenton。17Fe3+FentonpH。Fe3+EDTACOD86．0%78．0%BOD5/COD00．48。18Fenton。1．1．3Fenton/FentonFentonUV/Fenton。UV/FentonUV/H2O2H2O2/Fe2+Fe2+H2O2Fe2+H2O2H2O2Fe2+H2O2。C．Sirtori19－Fenton+IBR－FentonIBRDOC35mg/L。DOC95%－Fenton33%IBR62%。FentonPPGpH3、Fe2+1．5mmol/L、H2O225mmol/L30minCOD44%TOC35%BOD5/COD0．10．24COD56%TOC42%BOD5/COD0．10．45。UV/FentonPPG20。Puangrat21UV/FentonBOD5/COD0．30．52CODBOD5TOC。1．2TiO2TiO2－。。·OH。22COD。COD90%100%。。、23。24+A/O++、、SDM、SASPCOD14000mg/LBOD55500mg/L。A/OBOD5/COD0．05BOD5/COD。BOD5/CODCOD。25ABRCOD823mg/L200L/h、70L/h、90minCOD93．1%、COD56．8mg/L。1．326－29。O3、。O3H2O2/O3UV/O328。O3·OH3·OH·OH·OH。ArslanAlaton30H2O2/O3COD830mg/LO3COD30%H2O2/O320mmolH2O2COD83%。O340mg/L/minBOD5/COD0．45。O3COD81%·2·20113918100mg/LH2O2/O3。31H2O2/O3H2O2/O3、、OUR00．578mg/g·min。UV/O3、2080、、、。UV/O35、5β－、4、2、、15mg/LO318minLC/MS/MS32。1．4。·H·OH·OH2O2。·OH。、。100W60s80．9%Fenton92%、33－34。35+。COD13%～16%COD70%COD96%COD200～300mg/L。COD。1．5－COD5603mg/L36COD43%COD13%COD81%。37－SBRBOD5/COD0．170．51COD37%～47%SBRCOD80%～86%。23839。。。、、、。1．J．200121101－5．2HebererT．OccurrencefateandremovalofpharmaceuticalresiduesintheaquaticenvironmentareviewofrecentresearchdataJ．Toxicol-ogyLetters20021315－17．3SarithaPAparnaCHimabinduVetal．Comparisonofvariousad-vancedoxidationprocessesforthedegradationof4－chloro－2nitro-phenolJ．JournalofHazardousMaterials20071493609－614．4AzharNYonarTKestiogluK．Comparisonofvariousadvancedoxida-tionprocessesandchemicaltreatmentmethodsforCODandcolorre-movalfromapolyesterandacetatefiberdyeingeffluentJ．Chemo-sphere200455135－43．5．J．200626813－18．6KlavariotiMMantzavinosDKassinosD．Removalofresidualpharma-ceuticalsfromaqueoussystemsbyadvancedoxidationprocessesJ．EnvironmentInternational2008791－16．7NeyensEBaeyensJ．AreviewofclassicFenton’speroxidationasanadvancedoxidationtechniqueJ．JournalofHazardousMaterials2003981－333－50．8BadawyMIAliMEM．Fenton’speroxidationandcoagulationprocessesforthetreatmentofcombinedindustrialanddomesticwastewaterJ．JournalofHazardousMaterials20061363961－966．9MericSSelcukHBelgiornoV．AcutetoxicityremovalintextilenishingwastewaterbyFenton’soxidationozoneandcoagulationocculationprocessesJ．WaterResearch2005391147－1153．10MohamedIBadawyRifaatAetal．Fenton－biologicaltreatmentprocessesfortheremovalofsomepharmaceuticalsfromindustrialwastewaterJ．JournalofHazardousMaterials20091671－3567－574．11．－FentonJ．20112751－5．12．J．200536349－51．13．Fenton/SBRJ20103041－6．14．．J．200530755－57．15BretoJRochenbachGCBarreirosMAetal．Physico－chemicalmicrobiologicalandecotoxicologicalevaluationofaseptictank/FentonreactioncombinationforthetreatmentofhospitalwastewatersJ．Eco-toxicologyandEnvironmentalSafety20091221－6．16．FentonJ．200839368－71．17Ting－TingShenXiao－MingLiYu－FangTangetal．EDTAandelectricitysynergeticcatalyzedFe3+/H2O2processforamoxicillinoxi-dationJ．WaterScienceandTechnology2009603761－770．18FengJYHuXJYuePL．DiscolorationandmineralizationoforangeIIbyusingabentoniteclay－basedFenanocompositefilmasahetero-geneousphoto－FentoncatalystJ．WaterResearch200539189－96．19SirtoriCZapataAOllerIetal．Decontaminationindustrialpharma-ceuticalwastewaterbycombiningsolarphoto－FentonandbiologicaltreatmentJ．WaterResearch2009433661－668．．20Arslan－AlatonIGursesF．Photo－Fenton－likeandphoto－Fenton－likeoxidationofProcainePenicillinGformulatione