高盐废水处理技术研究进展陈浩

4522201711GuangzhouChemicalIndustryVol.45No.22Nov.2017430010。。、、。。X703A1001－9677201722－0017－03StudyonTreatmentofWastewaterwithHighSalinityCHENHaoZHANGFengWANGZhong－zhengZhouJun－boXIONGGuang－chengChangjiangInstituteofSurveyPlanningDesignandＲesearchHubeiWuhan430010ChinaAbstractWiththerapiddevelopmentofeconomyinChinawastewaterwithhighsalinityproducedfrommanyfieldshasabadinfluenceonhumanlivingenvironment.Thedefinitionandsourceofhigh－salinitywastewaterwasbrieflyintroducedparticularlyforthequalityinpetroleumrefiningprocess.Thetreatmenttechnologyofhigh－salinitywastewaterwereintroducedsuchasconventionaltreatmentprocessconcentrationprocessandzeroemissionprocesstheadvantagesanddisadvantagesofvarioustreatmenttechnologieswereanalyzedaswell.Thedevelopmentorientationoftreatinghigh－salinitywastewaterinthefuturewaspresented.Keywordswastewaterwithhighsalinityconcentrationprocesszeroemission1989－。、、、、1。2。。11.13.5%TDS3。Cl－、SO2－4、Na+、Ca2+。4。、、、、、、。1.2201326810/351000/150m3/h1m31。。5COD、TDS800mg/L、500mg/L34823mg/L。。22.12.1.1、COD。6CODBODTPTN。2.1.218201711、、。。7CrCr1540mg/L0.5mg/L。2.1.3、。。8、、。2.1.4、、。、、。99.3%CODCr1738mg/L216hCODCr98%。2.2。。。2.2.1、。MFUFNFＲO。。、、。60%10。2.2.2。。。118%。2.3。。。。、。100%12。2.41。。1Table1Comparisonofhigh－salinitywastewatertreatmentprocessesCOD3、、、、Cl－、SO2－4、Na+、Ca2+。、、。。。。1．J．20052521－4．2．J．199925335－38．3WoolardCＲIrvineＲL．Treatmentofhyper－salinewastewaterinthesequencingbatchreactorJ．WaterＲesearch19952941159－1168．4．J．2011393119387－19389．314522311∶1114.5g93%。1HNMＲ400MHzCDCl3δ7.896～7.9172Hm27－H7.206～7.2602Hm45－H7.592～7.6322Hm36－H4.8494HsJ=4.00Hz2OCH2CO4.2584HqJ=4.00Hz2OCH2CH31.2766HtJ=6.02Hz2OCH2CH313CNMＲ400MHzCDCl3δ183.58182.16168.69157.93134.96133.95125.0567.1861.6314.28。1.220.2g110mL15mL12h－1∶132。2a25%。1HNMＲ400MHzCDCl3δ8.5582HsJ=1.88HzＲCONHＲ7.260～8.5586HmAr－H4.6634HsJ=3.99Hz2OCH2CO3.6432HdJ=4.07HzNHCH213CNMＲ400MHzCDCl3δ185.22182.91167.57157.89135.59135.02125.0170.4738.70。2b50%。1HNMＲ400MHzCDCl3δ8.4502HsJ=1.96Hz2ＲCONHＲ7.260～7.9696HmAr－H4.6694HsJ=4.00Hz2OCH2CO3.5804HdJ=4.02Hz2NHCH2CH2NH2.8514HdJ=3.92Hz2NHCH2CH2NH13CNMＲ400MHzCDCl3δ183.30183.16167.38157.31135.10122.81120.5667.83OCH2CO49.6239.45。2c20%。1HNMＲ400MHzCDCl3δ7.9472HsJ=1.75HzＲCONHＲ7.255～7.94510HmAr－H4.9044HsJ=4.00Hz2OCH2CO4.6934HdJ=2.13HzNHCH2Ar13CNMＲ400MHzCDCl3δ183.10183.12166.95118.93～138.5067.9242.78。21Duck7DMFNaH82%。DMFNaH。18－。。93%。。1。。3。。1PedersenCJ.CyclicpolyethersandtheircomplexeswithmetalsaltsJ．JAmChemSoc.1967897017.2BeletskayaIPAverinADBessmertnykhAGetal.SynthesisofdiazacrownethersbasedonanthraceneandanthraquinonebyPd－catalyzedaminationreactionsJ.TetrahedronLett200132424987－4989.3KadarkaraisamyMSykesAG.LuminescencedetectionoftransitionandheavymetalsbyinversionofexcitedstatesSynthesisspectroscopyandX－raycrystallographyofCaMnPbandZncomplexesof18－anthraquinone－18－crown－5J.InorgChem.2006452779.4GouloumisALawsonＲCVázquezPetal.Synthesisandelectrochemicalswitchingofadianthraquinonecryptandandrelatedanthraquinone－diazacrownetheroligomersJ.Tetrahedron2002585961－966.5KimSHChoiHSKimJetal.Noveloptical/electrochemicalselective123－triazolering－appendedchemosensorfortheAl3+ionJ.OrgLett201012560.6ＲanyukEDouaihyCMBessmertnykhAetal.Diaminoanthraquinone－linkedpolyazamacrocyclesefficientandsimplecolorimetricsensorforleadioninaqueoussolutionJ.OrgLett200911987.7ParkDHKangSOLeeHJetal.SynthesisandElectrochemistryofDiester－AnthraquinoneasLithium－IonSelectiveＲeceptorBullJ.KoreanChemSoc.2001226638.檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵檵185．J．201131722－26．6．J．200114251－53．7．CrVIJ．200736122－25．8．、J．200832370－7179．9．J．2007224117－121．10．J．20091060－61．11．J．2001103201－208．12．J．200926225－27．