过氧化氢处理含染料废水研究新进展胡长诚

ChemicalPropellants&PolymericMaterials·6·(471000)FentonUV/FentonUV/H2O2/H2O2O3/H2O2TOCFentonUVO3TOCTQ123.6A16722191(2009)0300060620090209(1928)[e-mail][1][2][3][4][5]50mg/LFeO.Fe2O324h92%~99%(COD)500mg/L3h(TOC)88.77%89.54%81.44%PtCo49350COD6545mg/L10%H2O2UV120h99.5%COD84.4%COD13851586mg/L658722pH6.06.4COD62mg/L78mg/L95.5%95.1%242896.4%96.1%COD632.5mg/L74.2%98.5%COD966.2mg/L78.1%99.3%169()()242C36H23N5Na2O6S2()GR10BF4B(MO.Fe2O3,M=Fe,Co,Cu,Mn)H2O2pH=2~10FeO.Fe2O3FeFe2O3CeO2/Al2O3H2O2(CWPO)4UV/H2O2H2O2,CODpH2.0~3.5FentonH2O2pH8~10H2O2pH2.0~3.5,pH7.0~7.5CuO/Al2O3H2O2Al2O3··7·39()PVMS5B()5(2)()()5()COD5720mg/LPtCo49350TS6545mg/LSS275mg/LpH=2.850%20%10%C.I.24H2O2pH=4702h(FeOOH)H2O2NaClNa2SO4NaNO3KClFe()/H2O2TOCUVH2O2TiO2UVTiO2pH=330%H2O23mL/L100mL/min1hUV/H2O22Cu()chitosan()(Cu23.6%)H2O2pH=7.0/H2O2/0.05g/50mmol/4105molCu2pHH2O22UV/H2O2UVH2O2UVCOD(ZVI)UV/H2O2()TOC(30%)Cu2pH7.0~7.5Cu2FeOOHH2O2Fe4NaClNa2SO4NaNO3KClNaClKClTOC100200500mg/L91%86.8%26.4%H2O2UV(DOC)90%DOCH2O2180min85%20min91.5%10%180minCOD98.1%92.3%50%420minCOD49.1%20.0%UV/H2O2TOC5%270min(ZVI)30min56.7%TOC30%[6][7][8][9][10][11][12]ChemicalPropellants&PolymericMaterials·8·G()()()C.I.7(2)()C.I.4()UV/H2O23.77~4.0UV//H2O2H2O2K2C2O4Fe2(SO4)3.7H2OpHFe3C2H223Fe(C2H4)33(hydroxyl-Fepillaredbentonitecatalyst)UV/H2O2FeH2O2pH0.074mm30pH3.050mg/L1.0g/LH2O210mmol/LUVH2O2(UVH2O2pH)UV/H2O2UVUV0.3~4.6cmUV/H2O2Fenton/H2O2FentonTOCUVUV//H2O216min96.52%UV/H2O250mg/L120min98%TOC65%Fe0.6%Fe1mg/kgUV/FentonpH3.09.0pHUVH2O2pH(10min)0.3cm3min95%4.6cm15min90%UVUVH2O2H2O2H2O2UV/H2O2Fenton/H2O2ClSO42HPO42HPO42Fenton/H2O2UV/H2O20.1mmol/L1.0mmol/LH2O210mmol/L([13][14][15][16][17][18]··9·(C16H11N2NaO4S)B(C23H25N2Cl)X3B()TOCFeFenton/H2O2Fe(2m)H2O21234hTOCFeFe()Fe26.2%H2O2Al2O34503hFentonFe2H2O2Fenton(US)/Fe3/H2O2H2O2Fe3pHH2O2(Fe)H2O2CODH2O2H2O2()O3/H2O2pHO3/H2O2O3O3H2O2H2O2)35minTOC()80%100%4h100%TOC65%(0.66%~5%)H2O2(57~68)(43mg/L)(35~45)(118mg/L)4h99%TOC90%Fe4%702hCOD825mg/L299.6mg/L66.5%99.2%200mg/L(pH=3/30%H2O2/500mL/2mL/0.2g20~252h)99%COD90%Fe3/H2O2pH=3=500WFe3H2O230mg/L150mg/L30mg/L120min99.5%H2O24060minCOD97.5%98.8%100100pH10~11O3/H2O2195%[19][20][21][22][23][24]ChemicalPropellants&PolymericMaterials·10·(C.I.52)(remazol)(S)C.I.7(C16H11N2NaO4S)()procionMRprocionH8GprocionMG(7)()C.I.27()()Fenton(BAF)FentonBAFUV/H2O2()UV/H2O2H2O2(TOC)/TiO2/H2O2H2O2TiO2pHTiO2Fe(FeTAML)H2O2pH=9~11UVUV/H2O22000COD140~160mg/L20COD20mg/LUV10024%H2O256min65min93%100%17.5mg/LH2O2525mg/L3.75W/LUV100minTOC90%3120mg/L1h99%10TiO2TiO2TiO2COCO2FeTAMLH2O22H2O2UV/H2O2UV373[25][26][27][28][29][30]TOCH2O2(Fenton)(UVUSO3TiO2)100%TOCH2O2H2O2()H2O2H2O2··11·H2O2[1]PetrBaldrian,VeraMerhautova,JiriGabriel,etal.Deco-lorizationofsyntheticdyesbyhydrogenperoxidewithheterogeneouscatalyticbymixedironoxides[J].AppliedCatalysisB:Environmental,2006,66:258264.[2],.CWPOFe2O3CeO2/Al2O3[J].,2006,57(10):23032308.[3]ShuHungyee,HsiehWenpin.Treatmentofdyemanu-facturingplanteffluentusinganannularUV/H2O2reactorwithmulti-UVlamps[J].SeparationandPurificationTechnology,2006,51:379386.[4],,,.[P].CN:1899986,2007.[5]QiuZumin,HeYunbing,LiuXiaocheng,etal.Catalyticoxidationofthedyewastewaterwithhydrogenperoxide[J].ChemicalEngineeringandProcessing,2005,44:10131017.[6]ManickavachagamMuruganandham,YangJingshen,WuJerryJ.EffectofultrasonicirradiationoncatalyticactivityandstabilityofgoethitecatalystinthepresenceofH2O2atacidicmedium[J].IndEngChemRes,2007,46:691698.[7]DongYongchun,ChenJiali,LiChunhui,etal.DecolorationofthreeazodyesinwaterbyphotocatalysisofFe()-oxalatecomplexes/H2O2inthepresenceofinorganicsalts[J].DyesandPigments,2007,73:261268.[8],,.[J].,2007,33(2):7072.[9],,./[J].,2006,38(12):21882190.[10]RomanaSulakova,RadimHrdina,GracaMBSoares.OxidationofazotextilesolubledyeswithhydrogenperoxideinthepresenceofCu()-chitosanheterogeneouscatalysts[J].DyesandPigments,2007,73:1924.[11]ShuHung-Yee,ChangMing-Chin,HsiehWen-Pin.RemedyofdyemanufacturingprocesseffluentbyUV/H2O2process[J].JournalofHazardousMaterials,2006,128(1):6066.[12]ChangMing-Chin,ShuHung-Yee,YuHsin-Hung.Anintegratedtechniqueusingzero-valentironandUV/H2O2sequentialprocessforcompletedecolorizationandmineralizationofC.I.AcidBlack24wastewater[J].JournalofHazardousMaterials,2006,138(3):574581.[13],.UV/[J].,2008(6):2730.[14]ChenJianxin,ZhuLizhong.HeterogeneousUV-Fentoncatalyticdegradationofdyestuffinwaterwithhydroxyl-Fepillaredbentonite[J].CatalysisToday,2007,126:463470.[15]EstherRodriguez,RoberPeche,JoseMiguelMerino,etal.DecoloringofaqueoussolutionsofindigocarminedyeinanacidmediumbyH2O2/UVadvancedoxidation[J].EnvironmentalEngineeringScience,2007,24(3):363371.[16]AleboyehAzam,AleboyehHamid.EffectofgapsizeandUVdosageondecolorizationofC.I.AcidOrange7byUV/H2O2process[J].JournalofHazardousMaterials,2006,133(13):167171.[17]FatemaAAlshamsi,AmnaSAlbadwawi,MaithaMAlnuaimi,etal.ComparativeefficienciesofthedegradationofcrystalvioletusingUV/hydrogenperoxideandFenton'sreagent[J].DyesandPigments,2007,74:283287.[18]PatriciaACarneiro,RaquelFPupoNogueira,MariaValniceBZanoni.Homogeneousphotodegradationo