海藻糖强化厌氧氨氧化耦合反硝化工艺处理高盐废水的脱氮除碳效能杨振琳

3910201810ENVIＲONMENTALSCIENCEVol．39No．10Oct．2018*266071SBＲSAD．0.25mmol·L－1NH+4-N、NO－2-N、NO－3-NCODNH+4-N、NO－2-N50%、43%46%AＲＲNＲＲ81.25%75%．0.5mmol·L－1NH+4-NAＲE58.82%NH+4-N33.25mg·L－1．HaldaneAibaLuongSAD．NＲＲmax、KS、Smn0.954kg·m3·d－1、0mg·L－1、184.785mg·L－10.718．LogisticBoltzmanGompertzGompertz．X703.1A0250-3301201810-4612-09DOI10．13227/j．hjkx．2018032182018-03-302018-04-1151278258514782291992～[e-mail]*[e-mail]rbonＲemovalPerformanceofSimultaneousANAMMOXandDenitrificationSADwithTrehaloseAdditionTreatingSalineWastewaterYANGZhen-linYUDe-shuangLIJin*WANGXiao-xiaFENGLiSchoolofEnvironmentalScienceandEngineeringQingdaoUniversityQingdao266071ChinaAbstractEnhancednitrogenandcarbonremovalperformanceofsimultaneousANAMMOXanddenitrificationSADprocesswithtrehaloseadditiontreatingsalinewastewaterwasinvestigatedinasequencingbatchreactorSBＲ．Theoptimalnitrogenremovalwasachievedat0.25mmol·L－1trehaloseduringwhichNH+4-NNO－2-NNO－3-NandCODcouldbecompletelyremoved．ComparedtonoadditionoftrehaloseammoniumremovalefficiencyAＲEnitriteremovalefficiencyNＲEandtotalnitrogenremovalefficiencyTNＲEincreasedby50%43%and46%．AmmoniumremovalrateAＲＲandnitriteremovalrateNＲＲincreasedby81.25%and75%respectively．Withincreasingconcentrationoftrehaloseto0.5mmol·L－1AＲEwasonly58.82%andtheeffluentconcentrationofNH+4-Nwas33.25mg·L－1．ComparedtotheHaldanemodelandtheAibamodeltheLuongmodelwasthemostsuitabletosimulatethenitrogenremovalperformanceofSADwithtrehaloseadditiontreatingsalinewastewater．TheNＲＲmaxKSSmandnfittedfromLuongmodelwere0.954kg·m3·d－10mg·L－1184.785mg·L－1and0.718respectively．ComparedtothemodifiedLogisticmodelandthemodifiedBoltzmanmodelthemodifiedGompertzmodelwasthemostsuitabletodescribethedegradationofasubstrateinasinglecycle．KeywordssimultaneousANAMMOXanddenitrificationSADnitrogenremovalefficiencysalinewastewatertrehalosekineticsanaerobicammoniumoxidationANAMMOX、．ANAMMOX12．、CODANAMMOX．SAD3．．ANAMMOXAnAOBHDB．SAD4．5．、、6710．、89．“”10．1112．SAD．SADSAD．11.1SBＲ1．7L35±0.5℃．．0.5h6h0.5h0.5h．pH1mol·L－1NaOHHCl7.4±0.2．0～0.6mmol·L－1N210min．1．2．3．4．5．6．1Fig．1SchematicdiagramoftheSBＲconfiguration1.2．MLSSSV11.48g·L－1、11%．．32g·L－1NH+4-N、NO－2-NCODNH4Cl、NaNO280、160214mg·L－1．g·L－1KH2PO40.029、CaCl2·2H2O0.136、KHCO31.4、MgSO4·7H2O0.06Ⅰ1mL·L－1EDTA5g·L－1FeSO4·7H2O5g·L－1Ⅱ1mL·L－1EDTA15g·L－1H3BO30.014g·L－1MnCl2·4H2O0.99g·L－1CuSO4·5H2O0.25g·L－1ZnSO4·7H2O0.43g·L－1NiCl2·6H2O0.19g·L－1Na2MoO4·2H2O0.22g·L－1CoCl2·6H2O0.24g·L－1NaSeO4·10H2O0.21g·L－1．1.3NH+4-N、NO－2-N、NO－3-NCOD13．SVISV．3．pHWTWpH/Oxi340iTNＲＲHＲT12．TNＲＲ=cinf－c()eff×241000·HＲT1TNＲE=cinf－ceffceff×100%2HＲTHＲT=6ht=0.5hcinfmg·L－1ceffmg·L－1．34Pana=1.32NH+4rem÷NO－2inf+NO－3inf+0.26NH+4rem－NO－2eff－NO－3eff×100%3Pden=100%－Pana%4ana、den、rem、inf、eff、、、．NH+4、NO－2NO－3Nmg·L－114．1.4Haldane15．Ewards16．Aiba17．Luong18．HaldaneAibaANAMMOX1920．4SAD316439．1HaldaneNＲＲ=NＲＲmaxSKS+S+S2/KIH5NＲＲmaxkg·m3·d－1Smg·L－1KSmg·L－1KIHHaldanemg·L－1．2EwardsNＲＲ=NＲＲmaxexp－SK()IE－exp－SK()[]S6KIEEwardsmg·L－1．3AibaNＲＲ=NＲＲmaxSKS+Sexp－SK()IA7KIALuongmg·L－1．4LuongNＲＲ=NＲＲmaxSKs+S1－SS()mn8Smmg·L－1nLuongmg·L－1．．Logistic、BoltzmanGompertzSBＲANAMMOX．5LogisticNＲE=NＲEmax1+exp4Ｒmaxλ－t/NＲEmax+[]2992ceff=cinf1－0.01×NＲEmax1+exp4Ｒmλ－tNＲEmax[]+210NＲE%NＲEmax%Ｒmax%·h－1λhth．6BoltzmanNＲE=NＲEmax+NＲEmin－NＲEmax1+expt－tc/td11112ceff=cinf1－0.01×NＲEmax+NＲEmin－NＲEmax1+expt－tct()d12NＲEmin%tc1/2NＲEmaxhtdh．7GompertzNＲE=NＲEmaxexp－expＲmaxeNＲEmaxλ－t+()[]113132ceff=c[inf1－0.01NＲEmin·exp－expＲm·eNＲEmax·λ－t+()()]11422.1SADNH+4-N、NO－2-NNO－3-N2a．≤0.25mmol·L－1NH+4-NNO－2-N0mg·L－1NH+4-NNO－2-N100%．NH+4-N、NO－2-N50%、43%46%．0.05、0.1、0.15、0.20.25mmol·L－1COD56.87%、68.03%、75.57%、87.00%95.95%．0.25mmol·L－1SAD．Vyrides21K+．0.5mmol·L－1NH+4-N33.25mg·L－1NH+4-N58.82%NH+4-N50.38%8.44%．0.5mmol·L－1ANAMMOX．22NaCl10g·L－11mmol·L－1NH+4-NNO－2-N．ANAMMOX．ANAMMOX2b．0～0.15mmol·L－1ANAMMOX50%53.01%ANAMMOX46.99%．COD64%．ANAMMOX416410．0.3mmol·L－1ANAMMOX．aNH+4-N、NO－2-NNO－3-NbcNH+4-N、NO－2-NCODd2SADFig．2PerformanceofthesimultaneousanammoxanddenitrificationSADoveralong-termtestof248cycles0.5mmol·L－157.94%～66.58%ANAMMOX51643933.42%～42.46%．23ANAMMOXHDB．OLＲAnAOBHDB24～26．3Fig．3NitrogenremovalinatypicalSBＲcyclewithvariousinfluenttrehaloseconcentrationsNH+4-NAＲＲ、NO－2-NNＲＲ、CODOＲＲ2c．AＲＲ0.25mmol·L－1AＲＲ0.29kg·m3·d－10.25mmol·L－10.5mmol·L－1AＲＲ0.19kg·m3·d－1AＲＲ0.16kg·m3·d－10.25mmol·L－1AＲＲ81.25%0.5mmol·L－1ANAMMOX．NＲＲ0.25mmol·L－10.63kg·m3·d－1．OＲＲ．NＲＲ75%．Liu281mmol·L－1ANAMMOXNＲＲANAMMOX28．Cyplik271mmol·L－1．ANAMMOX．ΔNO－2-N/ΔNH+4-NＲaΔNO－3-N/ΔNH+4-NＲb2d．ＲbＲa．1ANAMMOXΔNO－2-N/ΔNH+4-NΔNO－3-N/ΔNH+4-N1.320.26．ＲaＲb．29．2.2SADCOD3．0.05mmol·L－1NH+4-N、NO－2-N616410CODNO－3-N0mg·L－1．NO－2-NCOD．AnAOBHDB．pH7.448.03．0.25mmol·L－1NH+4-NNO－2-NCOD5h．0.25mmol·L－1SAD．pH7.327.86．0.4mmol·L－1NO－2-NCOD4hNH+4-N6hNH+4-N22.95mg·L－1．pH7.388.067.7．0.5mmol·L－1NO－2-NCOD3.5hNH+4-N3.5h32.12mg·L－137.77mg·L－1．pH7.328.027.55．4SADFig．4CurveofthewholeprocessofSADkineticmodelwithtrehaloseaddition0.4mmol·L－10.5mmol·L－1pH3.5h．NO－2-NpHNO－2-NANAMMOXpHNH+4FAOH－pH．FAANAMMOX2530pH．ANAMMOXNO－2-NNH+4-N．SBＲ．31AnAOBVFANO－2-NNH+4-NDNＲA．ANAMMOXDNＲAANAMMOXNH+4-N．ΔpHCODΔpH