含油废水处理技术综述徐根良

171;19912TECHNOLOGYOFWATERTREATMENTVol.17,No.1Feb.。IggJ()(),,,.,。:、,。、.J、(、),。,。,,。,。。5001000,[`1。。,19741976,nlz[。。,100%,164ls1。。10mg/Ll,1,5~20mg/L1’,.1。,,,。、(),,COD、BOD,,,,,。,(、),,。.90041DOI:10.16796/j.cnki.1000-3770.1991.01.0011711。.*、*,4.5dm32.8x10`;mm、2.010’m:1.1。1mg34mg。,,。,4,100,120t[]。。501。。。,20,40%【s]。.2.t..,(、)。、、,。。,、、、,vI,,1。3。,,,,。,。4...,。,,。,,。S。.,,`,,。、、1.1,,。`。.*、、,,,。,,。、」.`.`1。、、()、,、、,、50%sIJ。60%,19641974521,173【’。i。1978,35￡’`,1976318“TorreyCanyon”11.7t,1978“AmocoCad”22t,,71〔7,。,。,()、、。3~30%,0.3~o。4%,1020%,3%,,,10t/d,O。2~5%1zI。,1~2t/d,。.1~0.2%`’“]。,,。1985,2000d/,322ta/,IOoot,“tt`3]。、、、、、、。、、6800t,,400。2。(1),,,。(2)1m。,,(),。(3)1“m。“),,,。(5)。、,()1。,,。(1),,,、。SotkesNewtonI“]。,,。。(API),,(1o)(2)·,、、,:,。,1)。、、11API1011,`.J(mm/s)m)t(g/L)t(mg/L)150100030160100010~20API1/230~60100010PPI2/3、0.230~5100010CPI9/10CPICPI,【`7l(2),,、,。(3),,,I`](3)。flJJJJJ23,,。,,。(a12000)。2.l[2(4)[。11“”,、、、[,s0J。“”,、、、、、,、。()127),。)il}Ol4“”“”5~10m,1~2mI`。l。PWT`],,10mg/l。。,〔“1。,。lFowkes,Al.CFe,,,.CAIGFeoC“。,],,50mgl/。“”(5l)3,,10“m,5x1-0“~20xl0~。()。“”,,,。3。,,5,、、、,]。、1,as[’]。。,,30~100mg/L7。5~10mg/U10~20mg/L2~smg/L[4,1,25~75mg/L(smg/Ll“],50mg/L15~20mg/L〔`.1。,、,,,,。4。(RO)、(UF),()。,I’.,`71,()()148,`。]。()()1,3~1。m,~2。。pm,10“m171。。.1m,。.005m~。.01m,O。l~3m,,,,,。,,,,`“”“2J。,,`.J。,,“7],RO,,lsal。,25%,70%,99.5%,8x10’。」。,100~1000mg/L,10mg/L,sz[l。,。().1.,、。,(6),[`,,.0[1。30~55555】A()_2115B()C6.,2.,3.,4.,5.100%O。3~O。6MaP,(),,,,,80“m,。,。、。,。,,5mg/L]。2.,。,、、、,。5mg/L(1mg/L)[`21,、,。1,(,)[’zl。eI`],(、())1。,,10mg/L。(),,、,。pH,,,、、。1.,,,,。、、、、,,。,。pH,pH。()·,ppm1~3m,l。2.pH3~4,,,,pH7~9。(),,Fe。3。,、,,。,。。Ca、Mg、Al(2)。2s0I](mg/L)(mg/L)(%)(/t)86ōn..…,OnJ.,`O.0D6.``ùO..…U,`OOOOOO3200032000320003200032Q00CaCI:·KAI(50):NCIHsSO-HCI·NaOH.KAI(50`):CaCI:·KAI(50):604170071643.5144l103],,10mg/L。,、、,,【“`1。,1~20x10“。l,’」,,。,,,,,1,、。().(),,CO:、HO:、N:、CH`,。。。l。()(),,、、,(),,,(),N、P,BOD。,,。`)-`—-l,.I[。71。,,。BOD。,$1J50~100mg/L[681,30250mg/L,710xl0“,CoDsmg/L,BOD。10mg/U““]。,,,、、、。,.eIl,2。~30xl。。,1~3x10,1xl。“.。2。,。,,,。1871,],,,,、。60,,,,1973,Flocor200v0I]。,,I’l1。,。,。3。,。,。198,39。()1.v[’。。(Al),、,1。,,(3)7s[1。,,,。,,。MEF,Al,,,`MEF.ll](4)。3(mg/L)(mg/L)24802320604117000~35500134016000018270~3006017012003~5559~2144.85~200L/hlzooL/h1000L/h0.sm./d60m./dsm./d。2.1,,,,,,。,,,,。,。S(s)t(mg/L)COD(mg/L)25020026426432.125.428.08.01340820222。7222。7100.395.740.020。0nn.n“.,3。,,,。,1,,(pH=7~8),2.09l/,0.4~1。091/,1~5mg/L。(HGMS)(6ll).1。(DEMl).oj。,,01716t.................,.,..............(mg/L)(mg/L)(mg/L)AP!AFUHGMSI’()HGMS2.(+)HGMS.3(+)190~24053~1212319~235~20142~20442~445~73~51~181500~4100970~372016001663260,、,(7)。7,}},,(,m):1}t,、,,21、、60,·160、10~203}.、10、10~20、601。1010101010、10、10、、115!l、10161},10,,,,100mg/L,,、,,,,,t,、、,,,,,,,,,、,,,,,,,、t、,、()、、,、。、、、,75%,、,t,,70℃,,,,,t,,.OtóOēU`1.J.....,,,,,「,,,,,,,,。、、,—()—,,(API、PPI、CPI)—()—()“”17111,、,,,BP,*、、*,。,。,,,、。,,、。,、、。*,。,。“”,,,(),13.26mg/L6.74mg/L,COD162.o6mg/L97.20mg/L,1.45mg/Lo.zsmg/Ll.`]。17,,1984,(1)15pushkarevvv。t。l,Teratment。f。11-eontainingwastewater,NewYork,lle-1Sleeter,Thomas,MethodsforlndentifyirtonPre,Ine,1,83ngthoSoureeofSpilled.011,Hareadr,29~215657。。,56537,.,561762,Env!roeementalLawReview,1977,(5):22~2`56`0215,5112953,527152651425WMLononetal,EnvironmentalSel-2,,1085,(7):enee&Teehnology,1972,`(10):。053,,1985,6(3)26DowChemCo,ALiteratureSearehand4,,1935CriliealAnlysisofBologiealTrlekling5,,,iFlterstuides,1972198827,,6JKWalter,,AWnt,IndustrealEffluPPM(),198。(12):37entTreatment,l,WaterandSoildWast25,,z”s5(1):27e,50,ApPlledSeiencePublisllersLTD,2。,,*London,198119847,,1955,6(5)30,,1956,(12):138,,1982,1(10)31,,1982.(5):169,PPM(),1050,(6):1732LloyDA,Ind&EngChem,1910,62(10),10,,1982,1(10)1011JNButler,OeeanIndustryOet,107533,,1978(4):2212,,“,,1986(s),41198535(),13,()36,,(),,1985197814,,(),37,(),1982,23(4):18,197938514434615,,59~i5`6352,53`250,535`276,198442,,1988,10(2)9,,,198043(),r12;171”lteday,Protses.akhNeftePerearbinNe-ftekhemleBaku,1983,313(Russ),,(),1984;(2),,19851(5):3,,198(3),,197(3):27,,1982,(,):52REMekinney,JWPCF,1,67,39(3):3`6GAGagnon,JWPCF,1977,,(5):832,,1051(xo).32,,1979,,198(2):24,,1985,5(l):5,,1981,(3):27,(),1986,(4):69,,1986,25(10):36,,197(2).27T,,191,(3).613M3HKHHA,,,1983,(2):28,,197(3):12,,197(3):9S,,1978,7(1):22,,1956,6(`):`5563“65“67“69707172”7’76”78On.,,8ù100“,,,1980,(6).145,,19806AYasuda,eSPaartlonofoilandwaterbyPolymermembranes,ChemEng,Inthe.eleemanklnd,Paris,eSPetmber,197247PCaPa,AdanceineeParationseienee-197848~,(1978)78,17749LNodr,BKarlbe,AnalChemAeta,1980,(2).11860,,1953,(6).151511009775,,1952,(3):s,53~55511259153`7370.5011518656PlantandPoreess,(),1985,27(8).3.57PlantandProeess,(),1985,27(11).43585110097759MlddlebrooksEJoe,Watereruse,AnnArbor,AnnSeienee,198260,,1986(2):19,(3):2361GanevaJF,SeleetlonofoPtimaleondi-tlonfortatingwastewaterwithbento-RVIEWOFTHETECHNOLOGYOFOILCONTAININGWASIWAI.ERTRATMENTXuGenlingZeilgJIgDWegDJiaing(DeparfeotofChe,`calE。`。eeri。,Zhejia。Uoioers`t,)AbstraetThehazardof011eontainiwastewatertotheenvironment,theform-ationofitadntheaPPearaneeof011inthewa3tewateraredeseribed-T