含重金属离子废水治理技术的研究进展

2008284IENVRONMEANTLPORCIETTOOCNFEHMICIIALN)USYTR·332·,,2,,(1.,300162.,300072;3.,300160)「〕、、、;;,、,,。〔〕;;;;;[〕T49t]A[]10061575(2005)032304ResearchProgressesinTreatmentTechnologiesforHeavyMetalIonContainingWastewaterWangaTo’,LiiXn、ang,,DuQiyun,(1.TheKeyLabofHollowFiberMembraneMaetiralsandMembranePoreessofMinistI’yofEdueation,TianjinPolyteehnieUniversity,iTanli300160,China;2.Nationa】EngineeirngReseacrhCenterofrDistillationTeehno]ogy,iTanjinUniversity,Tianjin300072,China;3.MotianEngineeirngandTeehnologyComPany,Tianjin300160,China)Abstraet:TheresearehanddeveloPmentoftreatmentProeessesforheavymetalioncontainingwastewaterarePresented,suchasPhysicalProcess,PhysicochemiealProcess,eonventionalchemiealPoreess,bioehemiealProeessandeleetroehemiea]Process.TheaPPlieationofbioelectroeouPledProeess15alsointroduced.CouPlingdiffeerntProeessesinordertoexerttheiresPecialadvantagesandavoidhteirinhibitinginteraetion15thedeveloPmentcuerrntinhteifeldofthewastewatertreatment.Keywords:heavymetalioncontainingwastewater;PhysicalProeess;eonventionalehemiealProcess;biochemiealProeess:eleetrochemiealProeess:eouPledPro55。、、、、、、、。、、、、、、、、、$lL,、。,,,,。,,。。l1.1〔2,’」、,。、、,。,,;_,。1.2〔4,5〕,[]20071216:[」20080315。〔](1974),,,,、。:022-24528104;:[e-mail][〕(07cJzDcJol400);(20070410765)。·324·ENIVORNMEANTLOPRTECOITNOFCEHM】CAILNDUSI,RY200828。、、,,“”,。,。,。,、。1.3。,,。Aroua16〕、,er,+(10mg/L),er,+100%。rella(DA)S4.47.6mg/LbPZ`’,Pb/DAS、Pb/,bP+299%。22.1〔8。。。,“”。:、,。,、、,。2.2,、,,,,,。,100,,。,,。,。sma[’O〕/bP,`,CuZ`,ZnZ`,cdZ`,。3,。、、,。Baraka〔MFDTPAC0+2,Cd+2,nz+2,cu+2,、pH、、、。〔’2」DTCR,,Hg+2,Cd+2,euZ·,Pb,·,Mn,·,NiZ`,zn,`,er,`,Cr6`,,,。,,,。4、、。30〔”〕。:,、、[’4,”〕,;,。〔’6,17〕。4.1。,zaik「’8〕,、cu+2cu+2,。zejh〔’9〕Pb+2。4.2,〔’()j。,;;;;、,、4.·235·〔”〕。,“”。[”」,1969BachkurstCooidrdge。,、、,,,。,,,。,。5,。,、、。[””」。〔’61,「’7〕;〔’8」;[29},、、、〔’。〕。「”〕,,。hAfuwiala〔”〕,、,、;,,,,。6,,,。,〔”〕,,。[’4〕,,mZ,3。,,,,[”{。[’“〕;,[’71〔’8〕cr6`Zn+2,Pb,+zn+2。iL〔’9〕0rC+bP+2,3.ov、17.7Wm、1.98m,,138%,erC+(50111L)bP+2(30mg/)L12h6h1mg/L,(GB/1T99232005《》)。7,,,。、,,,,,,。1,,..,1997,5(6):34432,..,2004,5(3):59623,,.,2003,25(2):1241264,..:,2000.1871955..:,2004.1681866ArouaMK,uZikFM,SuliamanNM.Removalofcllr。-nllllmionsfromaqueoussolutionsbyPolymerenhaneed·236·ENVRINOMNETALPRTOTECIONOFHCEM】CALINDUTRSY200828ultralfitratino.JHazradMatre,2007,147:7527587eFerllaF,irPseiaIKlaroM,ehelisID.eRmovalofhevaymetalsbysurfaetantenhaneedultrItrationfromwasetwaetrs.Desalination,2007,207:1251338,,.cr6.,2004,22(l):33349,,..,2002,27(13):6910SmaraA,DelimiR,ChianetE,etal.Removalofheavymetalsfromdilutedmixturesbyahybirdionsexehange/eleetrodialysisProeess.SePPuirfTeehnol,2007,57:10311011BarakaA,HallPJ,HesloPMJ.PreParationandeharac-teirzationofmelaminefomraldehydeDTPAehelatingresinanditsuseasanadsorbentforheavymetiasremovalftomwastewaterReaetFunetPo]ym,2007,67(3):58560012,,..,2003,23(3):17717913ArnsotrngRD,ToddM.SeleetiveeleetrodePosiitonofmetalsformsimulatedwastesolutions.JAPPIEleetro-ehem,1996,26(4):37938414,..,2000,26(3):13013515LiYanhui,DingJun,LuanZhaokun,etal.ComPetitiveadstsonofPbZ+,euZ`andedZ+sonsomaqueoussolutionsbymulitwalledcarbonnanotubes.Carbon,2003,41(10):2787279216NaumezykJ,SzyPkrowiezL,21110GF.lEectorehemiealtreatmentoftextilewastewaetr.WaterSeiTechnol,1996,33(7):30631517,,..,2001,21(l):111518ZakiMM,Nidroshl,SedallnledGH.MasstransferehaareteirstiesofereiPocraitngseerenstackeleetoreheim-ealreactorinrelationtoheavymetalsremovalftomdilutesolutions.ChemEngJ,2007,126(2):677719zejliH,eTmsarnKR.Eleetocrhemicalimcorexactr-itonoflead(11)atahydroxylaPiatte.modiifedPlantinumeleetrode.lEeetorehemCommun,2006,8(9):1544-154820,,..,1998,16(l):5821VuoirrlehtoK,TamminenA,Ylasaan5.Eleeotreheealremovalofdissolvedoxygenfromwater.JAPPIElectro-ehem,1995,25(10):97397722,,`.,2001,23(2):12512823MoralFMN.PirneiPlesofAquaticChemistry.NewYork:WileynIterseienee,1983.300309FordTE.Thecrobialeeologyofwaterdisitrbutionandourfallsystems.In:FOrdTE,ed.qAuaitceorbiology,nAEeologiealAPProach.Boston:Blackwell,1993.455-482..,1998,6(5):919,,.-.,2000,12(3):2830GlimourCC,HenryEA.MercurymethylaitoninaquatiesystemsaffeetedbyaeiddePosiiton.EnvironPollut,1991,71(24):131137ComPeanGC,BarthaR.Sulafteredueingbacteira:irPn-eiPalmehtylatorsofmecruryanoxiesediments.APPIEnviornMicorbiol,1985,50(2):498502oDyleRJ.oHweellwallsofgrampositivebacterlainetacrtiwhtmetali.hi:BeveirdgeTJ,yleRJ,eds.MetalIonsandBacteria.NewYork:Wiley,1989.275293BlaekJP,FodrTE,MitehellR.hTeroleofbacterialPolymersinmetalre!easeintowaetr.In:CullimoerR,InternationalSymPosiumonBioofuledAquifers:Preven-tionandRestoration.Bethesda,1986.3742iFnlaysonJC.hTerelationshiPbetweenthestruetureofactivatedsludgeflocsandhtesorptionofhydroPhobiePol-lutants.WaterSeiTeehnol,1998,37(45):353357Ahluwalia55,GoyalD.eorbialandPlantsdeirvedbiomassforermovalofheavymetalsfromwastewater-BioersourTeehnol,2007,98(9):22432257eFlekeZ,SakaikbaraY.AbioeleetrochemicalreaetoreouPledwihtadsorberofrtheremovalofnitrateandihnib-itoryPesticide.WaterRes,2002,36(7):30923102,,..:..:,2000.231235,,.0+6znZ.,2006,32(11):5457.:〔〕.:,2003.:〔〕.:,2003.:〔〕.:,2003LiXingga