河流重金属污染底泥的修复技术研究进展

1674-9669201201-0067-05：2011-12-04：(51174239)；（10JJ3001）；（20090461028、201003526）：（1987-），，，，E-mail：[e-mail].：（1975-），，，，、，E-mail：[e-mail].a，a，a,b，b(,a.，410083；b.，410083）：，，.，、，，.：；；；：X522：ARemediationtechnologyforriversedimentpollutedbyheavymetalsLIMing-minga,GANMina,ZHUJian-yua,b,CHAILi-yuanb（a.SchoolofMineralsProcessingandBioengineering;b.SchoolofMetallurgicalScienceandEngineering,CentralSouthUniversity,Changsha410083,China）Abstract:ThispaperreviewsthesedimentremediationtechnologypollutedbyheavymetalsonthebasisofthecurrentsituationofheavymetalpollutioninChina.Thebioremediationmethodofheavymetalremovalisdescribed.Bioremediationmethodisselectedasapromisingmethodwhichprovidestheoreticalbasisfordealingwiththeheavymetalinsedimentconsideringtheremovalefficiency,processingcostandenvironmentsafety.Keywords：sediment;heavymetalpollution;remediationtechnology;bioleaching0.，[1-2].[3].，.，，[4]，，，、，，、，，.[5-6]，，，、、[7-9].，，、，.3120122Vol.3No.1Feb.2012NonferrousMetalsScienceandEngineering.1，，，.，：Cu，Pb，Zn，70～90cm，CuRI[10].，Zn，ZnCuPb[11].，Cd，Zn，Pb，Cd，，Zn[12].()，Cu，Pb，Zn，CrMn[13].，，Pb、Zn，，As、Cr，，Hg、Pb、Cd[14].，Cu，Zn，CdPb，PI2.23~18.11，Cu，Zn，CdPb13.82，50.83，0.103，2.91mg/mL[15].，Cd，Pb，AsCu，Hg，CrZn，，Hg，CrZn，[16].2010，As，Cr，Cd，Pb，Hg[17].，.Pb，Pb1827.6mg/kg，《》（GB3838-2002）[18].Hankanson，PbAs，，，[19].，，.，，.22.1，..、[20].，，.、、；，，400m3[21].[22]、[23].，，，.，，.，、.，，[24].，.，，.，，.2.2、2012268，：，，，EDTA、、、、，，...，[25]，42%2%Cd，Cr，Pb，Zn，Ni90%.，，.、，，.，，，，[26].，，，，，.2.3（、）.、-.2.3.1、、，、.3，、.、、，.，，、、3Cd，，、．Cd3[27].，，，，，.，.，.2.3.2.，、、.、（Pb2+、Cu2+、Cr2+）[28].，，，，，，，.2.3.3.、.，.，，、、、、，Fe3+，Mn2+，Ni2+，Zn2+，Cu2+40，8，10，4，4mg／L，95.3％，93.1％，98.2％，89.9％，95.6%[29].H2S，，，..，，，(Trichodermalhd)28℃pH112h，Cr(VI)99％[30].，.，、、3169、，（、）.、，[31-32].，(Thiobacillus)、(Sulfobacillus)、(Acidianus)、(Leptospirillumferrooxi-das)、(Acidiphilium).，：，，.，，，，，Zn、Cd、Cu、Hg、As，Zn、Cd、Cu95.3%，84.4%，90.1%，As、Hg、Pb，（F4）（F5），[33].，.、、，，，pH，O2CO2，，[34].，，、.2.3.4-，，.，，，，、，，[35].，..-，.，，.3.，，.，，，.，，，，，，，，.，，，，.，，，，，，，.：[1]H.Akcay,A.Oguz,C.Karapire.Studyofheavymetalpollutionandspeciationinbuyakmenderesandgedizriversediments[J].WaterRes.2003,37:813-822.[2]O.R.Susana,D.L.Daniel,L.Lazaro,etal.AssessmentofheavymetallevelsinAlmendaresRiversediments-HavanaCityCuba[J].WaterRes,2005,39:3945-3953.[3]M.Legret,V.Colandini.Effectsofaporouspavementwithreservoirstructureonrunoffwater:waterqualityandfateofheavymetals[J].WaterScienceandTechnology,1999,39(2):111-117.[4]N.Caille,C.Tiffreau,C.Leyval,etal.Solubilityofmetalsinananoxicsedimentduringprolongedaeration[J].TheScienceoftheTotalEnvironment,2003,301(1-3):239-250.[5]T.A.DelValls,J.Blasco,M.C.Sarasquete,etal.Evaluationofheavymetalsedimenttoxicityinlittoralecosystemsusingjuvenilesofthefishsparusaurata[J].EcotoxicologyandEnvironmentalSafety,1998,41(2):157-167.[6]J.Widada.Recentdevelopmentsinmoleculartechniquesforidentificationandmonitoringofxenobiotic-degradingbacteriaandtheircatabolicgenesinbioremediation[J].Appl.Microbiol.Biotechnol,2002,60(1):45-59.[7]EveRiser-Roberts.Remediationofpetroeamcontaminatedsite,2012270Bilolgical,physicalandchemicalprocesses[M].NewYork:LewisPublishers，1998：277-291.[8]LiTaiping,YuanSonghu,ZhongJin.Hydroxypropyl-7-cyclodextrinenhancedelectrokineticremediationofsediment.contaminatedwithHCBandheavymetals[J].JournalofHazardousMaterials，2010,176：306-312.[9]P.Kelderman,A.A.Osman.Effectofredoxpotentialonheavymetalbindingformsinpollutedcanalsedimentsindelft[J].WaterResearch,2007,41:4251-4261.[10],,,.[J].,2010,27(2):180.[11],.[J].，2006,29(11):2.[12],,.[J].,2004,23(3):321-324.[13],,,.()[J].,2004,39(6):105.[14].[D].：,2009.[15],,,.[J].,2005,18(3):5-10.[16],,,.[J].,2005,24(1):106-107.[17]L.Y.Chai,Z.X.Wang,Y.Y.Wang,etal.IngestionrisksofmetalsingroundwaterbasedonTINmodelanddose-responseassessment-acasestudyintheXiangjiangwatershed,central-southChina[J].ScienceoftheTotalEnvironment,2010,408(16):3118-3124.[18],,.[J].,2009,34(6):34-36.[19],,,.[J].,2009,5(4):45-52.[20].[D].：,2010.[21],,.[J].,2010,28(12):23.[22].[J].,2008,28(4):138-139．[23].,,.[J].，2008，24(2):6-11.[24],.[J].，1997,181:65-69.[25],,,.[J].,2002,25(2):43-46.[26],,,．[J].，2010,4(1):8．[27],,，.Cd[J].,2005,8(3):325-327.[28],,.[J].,2006,35(9):536.[29],.[J].,2005,25(9):1-3.[30],,,.[J].,2010,19(3):353-356.[31]R.D.Tyagi,T.R.Sreekrishnan,J.F.Blais,etal.Effectofdissolvedoxygenonsludgeacidi-ficationduringtheSSDML-process[J].WaterAirSoilPollution,1998,102(1-2):139-155.[32]Shen-yiChen,LinJih-gaw.Bioleachingofheavymetalsfromcontaminatedsedimentbyindigenoussulfur-oxidizingbacteriainanair-liftbioreactor:effectsofsulfurconcentration[J].WaterResearch,2004,38:3205-3214.[33]J.Y.Zhu,J.X.Zhang,L.Y.Chai,etal.Bioleachingofheavymetalsfromcontaminatedalkalinesedimentbyauto-andheterotrophicbacteriainastirredtankreactor[C]//Proceedingsofthe19thInternationalBiohydrometallurgySymposium,2011,Changsha：1122-1127.[34].、、[D].：，2008.[35]，，，.[J].，2007，30（2）:104.，：3171